• Title/Summary/Keyword: Aerosol Particle

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Synthesis of Polymer-Carbon Nanotubes Composite Nanoparticles and Their Applications into Forming Hybrid Composite Thin Films (폴리머-탄소나노튜브 복합체 에어로졸 입자의 생성 및 이를 이용한 하이브리드 복합체 박막 제조)

  • Kim, Whi-Dong;Ahn, Ji-Young;Kim, Soo Hyung
    • Particle and aerosol research
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    • v.6 no.2
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    • pp.61-67
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    • 2010
  • In this paper, we describe a new method to form polymer thin films, in which carbon nanotubes (CNTs) are homogeneously distributed so that they can strengthen the mechanical property of resulting polymer film. To do so, we first homogeneously mixed CNTs with polymer in a DMF solvent. With the assistance of ultrasonic nebulizer, the polymer/CNT solution was then aerosolized into micro-sized droplets and finally turned into solidified polymer/CNT composite particles by gas-phase drying process. As the results of SEM and TEM analysis, CNTs were found to be homogeneously immobilized in the polymer matrix particles due to rapid drying process in the gas phase. For comparison purpose, (i) the polymer/CNTs composite particles prepared by aerosol processing method and (ii) polymer/CNTs sheets prepared by simple solution-evaporation method were employed to form polymer/CNTs composite thin films using a hot press. As the result, the aerosol processing of composite particles was found to be a much more effective method to form homogeneously distributed-CNTs in the polymer matrix thin film.

Improvement of a High-volume Aerosol Particle Sampler for Collecting Submicron Particles through the Combined Use of a Cyclone with a Smoothened Inner Wall and a Circular Cone Attachment

  • Okuda, Tomoaki;Isobe, Ryoma
    • Asian Journal of Atmospheric Environment
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    • v.11 no.2
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    • pp.131-137
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    • 2017
  • A cyclone is an effective tool to facilitate the collection of aerosol particles without using filters, and in cell exposure studies is able to collect a sufficient amount of aerosol particles to evaluate their adverse health effect. In this study, we examined two different methods to improve the aerosol particle collection efficiency of a cyclone. The individual and combined effects of reducing the surface roughness of the inner wall of the cyclone and of using a circular cone attachment were tested. The collection efficiency of particles of diameter $0.2{\mu}m$ was improved by approximately 10% when using a cyclone with a smoothened inner wall (average roughness $Ra=0.08{\mu}m$) compared with the original cyclone ($Ra=5.1{\mu}m$). A circular cone attachment placed between the bottom section of the cyclone and the top section of a collection bottle, resulted in improved collection of smaller particles without the attachment. The 50% cutoff diameter of the modified cyclone (combined use of smoothened inner wall and attachment) was $0.23{\mu}m$ compared to $0.28{\mu}m$ in the original model. The combined use of these two techniques resulted in improved collection efficiency of aerosol particles.

Synthesis of Porous Graphene Balls by the Activation and Aerosol Process for Supercapacitors Application (활성화 및 에어로졸 공정에 의한 다공성 그래핀 볼 제조 및 슈퍼커패시터 응용)

  • Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.15 no.4
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    • pp.183-190
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    • 2019
  • Here, we introduce porous graphene balls (PGB) showing superior electrochemical properties as supercapacitor electrode materials. PGB was fabricated via activation of graphene oxides (GO) by H2O2 and aerosol spray drying in series. Effect of activation on the morphology, specific surface area, pore volume, and electrochemical properties were investigated. As-prepared PGB showed spherical morphology containing pores, which lead to the effective prevention of restacking in graphene sheets. It also exhibited a large surface area, unique porous structures, and high electrical conductivity. The electrochemical properties of the PGB as electrode materials of supercapacitor are investigated by using aqueous KOH under symmetric two-electrode system. The highest specific capacitance of PGB was 279 F/g at 0.1 A/g. In addition, the high rate capability (93.8% retention) and long-term cycling stability (92.2%) of the PGB were found due to the facilitated ion mobility between the porous graphene layers.

Eco-Friendly Synthesis of Rod-Like Potassium Hexatitanate Particles (친환경 공정에 의한 봉상형 육티탄산칼륨 입자의 제조)

  • Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.13 no.4
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    • pp.183-189
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    • 2017
  • Potassium hexatitanate ($K_2Ti_6O_{13}$) with high thermal insulating capacity, good mechanical properties, and excellent chemical stability are promising functional materials in the field of reinforcing material, heat insulating paints and automotive brake linings. In this study, we successfully synthesized rod-shaped potassium hexatitanate ($K_2Ti_6O_{13}$) by aerosol spray drying and post heat treatment as an eco-friendly process. The $KHCO_3-TiO_2$ porous particles were firstly synthesized from a colloidal mixture of $K_2CO_3$ and $TiO_2$ via aerosol spray drying. Size of $KHCO_3-TiO_2$ porous particles was ranged from $1{\mu}m$ to $5{\mu}m$. The porous particles were then heated to fabricate rod-type $K_2Ti_6O_{13}$. The length and width of rod-type composites were affected by temperature and heating time. The length and width of $K_2Ti_6O_{13}$ were increased by 830 nm and 500 nm, respectively, as the reaction temperature and time increased.

Preparation of V2O5-Graphene Composites using Aerosol Process for Supercapacitors Application (에어로졸 공정을 이용한 오산화바나듐(V2O5)-그래핀 복합체 제조 및 슈퍼커패시터 응용)

  • Lee, Chongmin;Jang, Hee Dong
    • Particle and aerosol research
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    • v.16 no.4
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    • pp.95-105
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    • 2020
  • Vanadium Pentoxide (V2O5) has been emerged as alternative electrode materials for supercapacitors due to their low cost, natural abundance, and environmental friendliness. Graphene (GR) loaded with V2O5 can exhibit enhanced specific capacitance. In this study, we present three-dimensional (3D) crumpled graphene (CGR) decorated with V2O5. The V2O5-graphene composites were synthesized from a colloidal mixture of graphene oxide (GO) and Ammonium metavanadate (NH4VO3), via aerosol spray drying and post heat treatment process. The average size of composite was ranged from 1.82 to 4.6 ㎛. Morphology of the composite changed from a crumpled paper ball to spherical ball having relatively smooth surface as the content of V2O5 increased in the composites. The electrochemical performance of the V2O5-graphene composites was examined. The V2O5-graphene composite electrode showed the specific capacitance of 312 F/g. In addition, the device possessed acceptable cyclic stability, with 84% after 2000 cycles at 2 A/g. These outstanding properties are expected to make the composites prepared in this study as promising electrode materials for supercapacitor applications.

FIELD EXPERIENCE OF PORTABLE SMPS+C NANO PARTICLE SIZER

  • Gerhart, Ch.;Grimm, H.J.;Heim, M.
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.47-48
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    • 2003
  • This new family of portable real time SEQUENTIAL MOBILITY PARTICLE COUNTER and SIZER (SMPS+C) is designed for mobility and easy field use. An integrated battery assures hours of operation, a data logger system storage of all optioned results and a user friendly powerful software easy operation. This technology not only simplifies the SMPS operation, but it permits new on site application monitoring up to a remote wireless telephone operation. (omitted)

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Variations of Aerosol Size Distribution on Ambient Air (대기중 에어로졸 입경분포의 변화)

  • 김신도;안기석;김종호;김태식
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.83-84
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    • 1999
  • 시정악화나 광화학 스모그를 비롯하여 지구 온난화에 부유 입자상 물질이 미치는 영향 등을 파악하기 위해선 중량농도, 화학적 성분분석 등과 함께 그 입경별 크기 분포도 반드시 고려되어야만 한다. 입경분포 측정을 위하여 다단식 임팩터(Cascade Impactor)나 광학입자계수기(OPC, Optical Particle Counter), Aerosizer, SMPS (Scanning Mobility Particle Sizer), EAA(Electrical Aerosol Analyzer) 등 이주로 사용되고 있다.(중략)

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Numerical analysis of particle transport in low-pressure, low-temperature plasma environment

  • Kim, Heon Chang
    • Particle and aerosol research
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    • v.5 no.3
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    • pp.123-131
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    • 2009
  • This paper presents simulation results of particle transport in low-pressure, low-temperature plasma environment. The size dependent transport of particles in the plasma is investigated with a two-dimensional simulation tool developed in-house for plasma chamber analysis and design. The plasma model consists of the first two and three moments of the Boltzmann equation for ion and electron fluids respectively, coupled to Poisson's equation for the self-consistent electric field. The particle transport model takes into account all important factors, such as gravitational, electrostatic, ion drag, neutral drag and Brownian forces, affecting the motion of particles in the plasma environment. The particle transport model coupled with both neutral fluid and plasma models is simulated through a Lagrangian approach tracking the individual trajectory of each particle by taking a force balance on the particle. The size dependant trap locations of particles ranging from a few nm to a few ${\mu}m$ are identified in both electropositive and electronegative plasmas. The simulation results show that particles are trapped at locations where the forces acting on them balance. While fine particles tend to be trapped in the bulk, large particles accumulate near bottom sheath boundaries and around material interfaces, such as wafer and electrode edges where a sudden change in electric field occurs. Overall, small particles form a "dome" shape around the center of the plasma reactor and are also trapped in a "ring" near the radial sheath boundaries, while larger particles accumulate only in the "ring". These simulation results are qualitatively in good agreement with experimental observation.

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Development of Simple Bimodal Model for Charged Particle Coagulation (Bimodal 방법을 이용한 하전입자 응집 모델링)

  • Kim, Sang Bok;Song, Dong Keun;Hong, Won Seok;Shin, Wanho
    • Particle and aerosol research
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    • v.10 no.1
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    • pp.27-31
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    • 2014
  • A simple bimodal model has been developed to analyze charged particle coagulation by modifying previously suggested bimdal model for evolution of particle generation and growth. In the present model, two monodisperse modes are used and 40 charge nodes are assigned to each mode to account both change of the particle size and charge distribution. In addition, we also implemented the effect of electrostatic dispersion loss in the present model. Based on the developed model, we analyzed coagulation of asymmetric bipolar charged particles by computing evolutions of particle number concentration, geometric mean diameter of particles, charge asymmetric ratio and geometric standard deviation of particle size distribution for various initial charge asymmetric ratios. The number concentration of asymmetric bipolar charged particles decreases faster than that of neutral particles but that does not give faster growth of particles since the electrostatic dispersion loss overwhelms particle growth by coagulation.

Numerical study of particle dispersion from a power plant chimney (발전소 굴뚝에서의 입자 분산에 대한 수치해석)

  • Shim, Jeongbo;You, Donghyun
    • Particle and aerosol research
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    • v.13 no.4
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    • pp.173-182
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    • 2017
  • An Eulerian-Lagrangin approach is used to compute particle dispersion from a power plant chimney. For air flow, three-dimensional incompressible filtered Navier-Stokes equations are solved with a subgrid-scale model by integrating the Newton's equation, while the dispersed phase is solved in a Lagrangian framework. The velocity ratios between crossflow and a jet of 0.455 and 0.727 are considered. Flow fields and particle distribution of both cases are evaluated and compared. When the velocity ratio is 0.455, it demonstrates a Kelvin-Helmholtz vortex structure above the chimney caused by the interaction between crossflow and a jet, whereas the other case shows flow structures at the top of the chimney collapsed by fast crossflow. Also, complex wake structures cause different particle distributions behind the chimney. The case with the velocity ratio of 0.727 demonstrates strong particle concentration at the vortical region, whereas the case with the velocity ratio of 0.455 shows more dispersive particle distribution. The simulation result shows similar tendency to the experimental result.