• Journal of Korean Society of Water and Wastewater
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• 제17권4호
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• pp.542-549
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• 2003

In the present study, the feasibility of $UV/H_2O_2$ systems was investigated using low and medium-pressure lamps on biologically treated wastewater effluents for secondary effluent reclamation. Two types of UV lamps were used as the light sources (a 39-W low-pressure mercury lamp and a 350-W medium-pressure mercury lamp). The results from these UV systems showed that the removal of organic compounds could be achieved in the contact time of longer than 30min (i.e., low UV doses). Efficiencies of color removal and disinfection were far better than those of organic matters measured as TOC, DOC and $TCOD_{cr}$. In the low-pressure lamp UV system, it has been found that DOC and color removals were 60.9 and 86.2% with 50mg/L of $H_2O_2$ and contact times of 30 minute, respectively. Whereas, with the medium-pressure lamp UV system, TOC, DOC and color removal were 27.1, 5.6 and 95% with 14.3mg/L of $H_2O_2$ and 14 minute of contact times, respectively. Both systems could be applied for the reclamation of secondary effluent treated with biological treatment processes.

• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.190.1-190.1
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• 2016

One of the most serious problems faced by billions of people today is the availability of fresh water. According to statistics, 15% of the world's total output of dye products is discharged into the environment as dye wastewater, which seriously pollutes groundwater resources. For the treatment of chemically and biologically contaminated water the advanced oxidation processes (AOPs) shows the promising action. The main advantage with AOPs is the ability to degrade the organic pollutants to $CO_2$ and $H_2O$. For this degradation process the AOPs generation of powerful and non-selective radicals that may oxidize majority of the organic pollutants present in the water body. To generate the various reactive chemical species such as radicals (${\bullet}OH$, ${\bullet}H$, ${\bullet}O$, ${\bullet}HO_2$) and molecular species ($H_2O_2$, $H_2$, $O_2$) in large amount in water, we have used the atmospheric pressure plasma. Among the reactive and non-reactive species, the hydroxyl radical (${\bullet}OH$) plays important role due to its higher oxidation potential (E0: 2.8 V). Therefore, in this work we have checked the degradation of various dyes such as methyl orange, methylene blue and congo red using different type of atmospheric pressure plasma sources (Indirect jet and direct jet). To check the degradation we have used the UV-visible spectroscopy, HPLC and LC-MS spectroscopy. Further, to estimate role of ${\bullet}OH$ on the degradation of dyes we have studied the molecular dynamic simulation.

• Journal of Korean Society of Environmental Engineers
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• 제27권1호
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• pp.115-119
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• 2005

As the regulations on DBPs are tightened, many water treatment plants (WTPs) in Korea have already introduced or will introduce enhanced coagulation, alternative disinfectants and advanced treatments such as ozonization and granular activated carbon to improve drinking water qualify. After a phenol leakage accident at the Nakdong-River in 1991, 26 WIPs in Korea introduced carbon dioxide generators, but there has been no accumulation of significant operating data. This research summarizes things that should be considered for the introduction of carbon dioxide disinfection process to WTPs based on one year operation data from A WTP that has had high concentration of DBP during a specific period in the summer. The removal efficiency of DBP was $30{\sim}40%$, but those of 2-MIB, Geosmin were less than 10%. The generation rate of $ClO_2$ by-products such as chlorite and chlorate were $70{\sim}100%$ of input dosage, but the ratios increased over time. At the same time, strong chlorine odors may be produced in the distribution system when $ClO_2$ was used with $Cl_2$ as a result of reaction between the chlorite and residual chlorine.

• Applied Chemistry for Engineering
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• 제7권2호
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• pp.371-378
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• 1996

A prototype of expert system which can support the operation for the municipal waste water treatment plant located at Kyoung-Ki Do, Kwang-ju Kun was developed and tested. This system provides (i) tracking the cause of the problem, (ii) analysis, and (iii) solution Knowledge-base consists of about 100 production-rules for the biological wastewater process, such as bio-reactor and final clarifier. Rules were obtained from the analysis of the problems such as sludge bulking. The system provides stable process control and management and effectively helps inexperienced operators with advanced and standard technologies. Future works will focus to develop a statistical process control model and associate with expert system. The control model can process the operation data statistically; analyze the relationship between affecting factors and control variables; and provide optimum operation parameters.

• Journal of Korean Society on Water Environment
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• 제35권6호
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• pp.459-469
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• 2019

The ozonation of sulfamethoxazole (SMX) was performed at 20℃ using a pilot scale countercurrent bubble column reactor. Ozonation systems were combined with UV irradiation and TiO₂ addition. As the oxidation reaction proceeded in each treatment system, the pH of the sample decreased and in the O₃/UV/TiO₂ system, the pH change was the largest from 4.54 to 2.02. Under these experimental conditions, the scavenger impact of carbonate is negligible. The highest COD and TOC removal rate was observed in the O₃/UV/TiO₂ system due to the UV irradiation and the photocatalytic effect of TiO₂. Also, the highest mineralization ratio(ε) value is 0.2 in the O₃/UV/TiO₂ system, which means theoxidation capacity of the systems. The highest SMX degradation rate constants calculated by COD and TOC values (COD and TOC) were 2.15 × 10^-4 sec^-1 and 1.00 × 10^-4 sec^-1 in the O₃/UV/TiO₂ system, respectively. The activation energy (E_a) of ozone treatment follows the Arrhenius law. It was calculated based on _COD and _TOC. Each activation energy decreased in order of single O₃> O₃/TiO₂> O₃/UV > O₃/UV/TiO₂ system. The result showed that ΔH^≠ is more effective than ΔS^≠ in each SMX ozontaionsystem, that is characteristic of the common oxidation reaction.

• Journal of Korean Society on Water Environment
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• 제22권6호
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• pp.991-995
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• 2006

The layered double hydroxide with the insertion of chloride ions (LDH-Cl), which was synthesized by the co-precipitation method, was applied to investigate the fundamental aspects of the absorptive agent for phosphate removal from wastewater. The adsorption capacity was best described by the Langmuir-FreundIich isotherm, and the estimated isotherm parameters indicate that the LDH-CI capacity for the phosphate removal is much higher than that observed using a natural adsorbent material such iron oxide tailing. The kinetic experiment also showed that the LDH-Cl adsorption reaction rapidly at the adsorptive rate of 0.55 mg-P/g-LDH/min, implying that this adsorbent can be of use in the full-scale applications. The pH had a minimal effect on the LDH adsorption capacity in the range of 5 to 11, although the capacity dropped at the low pHs because of the change in LDH surface properties. Furthermore, other anions such as $Cl^-$ and $NO_3{^-}$ commonly found in the wastewater streams insignificantly affected the phosphate removal efficiencies, while $HCO_3{^-}$ ions had a negative effect on the LDH adsorption capacity due to its high selectivity. The phosphate removal experiment using the actual secondary effluent from a wastewater treatment plant showed the similar decrease in adsorption capacity, indicating that the bicarbonate ions in the wastewater were competing with phosphate for the adsorptive site in the surface of the LDH-Cl. Overall, the synthetic adsorbent material, LDH-Cl, can be a feasible alternative over other conventional chemical agents, since the LDH-Cl exhibits the high phosphate removal capacity with the low sensitivity to other environmental conditions.

• Journal of Korean Society on Water Environment
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• 제27권4호
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• pp.461-466
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• 2011

The feasibility of utilizing food waste leachate as an external carbon source was tested to enhance biological nutrient removal from an industrial wastewater with an average flow rate of $164,800m^3/d$ and a low carbon/nitrogen ratio of 2.8. A considerable improvement in the removal of nitrogen and phosphorus was observed when a certain amount of the leachate, ranging from 70 to $142m^3/d$, was supplemented to the biological industrial wastewater treatment process. The addition of the leachate led to an increase in the BOD/N ratio (4.5) and the removal efficiency of nutritents from 29.7% to 71.7% for nitrogen and from 34.8% to 65.6% for phosphorus. However, an excessive dose of the leachate that significantly exceeded $120m^3/d$ caused serious operational problems, like oil-layer formation in the grit chamber and scum layer in the primary clarifier. Thus, an supplement of food waste leachate at a dose acceptable to an existing facilities can be a practical and effective means to enhance the nutrient removal from industrial wastewater and to dispose of the food waste leachate.

• Journal of the Korea Organic Resources Recycling Association
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• 제30권4호
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• pp.15-25
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• 2022

In this study, the efficiency of treatment of moisture and organic matter in food waste was analyzed according to the air blast volume and preheating using the bio-drying method. Te mount of air blast volume and preheating were determined by the evaluation of temperature and CO2 during food waste treatment using the bio-drying method. As a results, the increase in the air blast volume increased the moisture removal efficiency and removal rate, but, lowered the temperature inside the bio-drying by the decease in microbial activity. In order to maintain the activity of microorganisms, it was estimated that it was necessary to inject an appropriate air blast rate according th the properties of the food waste. In this study, the injection of air blast volume at 15L/min was optimal. It was evaluated that the organic matter and water removal rates according to the presence or absence of air preheating, the organic matter removal rate and water removal rate increased by 3-5% when air preheating was not performed. Also, there was no internal aggregation caused by the generation of condensate inside the bio-drying. Therefore, for effective bio-drying of food waste, it is necessary to maintain an appropriate air blast volume to maintain microbial activity, and it is considered that injection through preheating of air is required.

• Journal of the Korean Society for Environmental Technology
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• 제19권6호
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• pp.556-562
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• 2018

Due to the enforcement of effluent water regulation the advance sewage treatment system is needed to retrofit and remodelling. In this case the most important issue is the effluent concentrations of TP and there are a lot of system to reduce its concentration. But biological treatment processes have many restrictions to enhance the removal efficiency of TP. In this study the efficient ECO operating condition to improve and retrofit biological sewage wastewater treatment system is as follow; 1) The treatment efficiency of BOD, TN and TP at the current density of $15mA/cm^2$ was higher than the treatment efficiency at $5mA/cm^2$ in the electrodes arranged with Al-SUS(Stainless Steel) regardless of the reaction time, The TP concentration was 0.1 mg/L or less. Especially, when the reaction time was maintained at 10 min, the TP concentration was 0.06 mg/L or less irrespective of the current density. 2) The change of TP concentration is not influenced by the change of current density and rather the concentration of treated water changes according to the reaction time. In the case of electro coagulation reaction, a few seconds to several minutes are required. However, the reaction time of electro coagulation and oxidation was studied to be more than 10 minutes. 3) As a result, it has been studied that the economical current density of the electro coagulation oxidation process for TN and TP treatment of domestic wastewater is $15mA/cm^2$ or less and the reaction time is 10 minutes.

• Microbiology and Biotechnology Letters
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• 제31권3호
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• pp.264-270
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• 2003

A quantitative survey of the protozoa microfauna at bioreactor of advanced sewage treatment plant was carried out during a period of 11 months. In this study, 32 genera were identified, including 17 ciliates. The abundance of the important protozoa were compared with the operating parameters and water quality of the effluent of the plant using statistical procedure. Statistical analysis revealed a relationship between the abundance of some genera and removal rate. In particular, correlation analysis on the quality of effluent and protozoa indicated that Lepadella may be used as the bioindicator of TP removal and Trochilia, Entosiphon, Colepus may be used as the bioindicator of TN removal when water temperature was below $20^{\circ}C$.