• Title/Summary/Keyword: Advanced Oxidation

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A Study on Improvement of Durability for Run-out Table Roller with Hot Rolling by Porous Self-fluxing Alloy Coating (다공질 자용성 합금 피복에 의한 열간 압연용 런-아웃 테이블 롤러의 내구성 향상에 관한 연구)

  • Bae, Myung-Whan;Park, Byoung-Ho;Jung, Hwa
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.2
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    • pp.276-285
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    • 2012
  • The objective of this research is to develop the coating technique by a porous self-fluxing alloy for improving the mechanical properties of run-out table roller surface with the hot rolling. To enhance the durability of run-out table roller with the hot rolling, the high hardness of roller surface should be maintained at high temperatures, and the improvement of wear resistance, corrosion resistance, heat resistance, burn resistance and adhesion resistance should be maintained. In order to be able to transport reliably a hot rolled steel sheet, also, the appropriate friction coefficient on the roller surface should be maintained and the slip between roller and steel should not occur. In this study, the wear resistance of roller increases after the self-fluxing alloy is changed to a cermet by adding the tungsten carbide(WC), and the coefficient of friction increases and the ability of grip is improved because the porosities are made by coating with fine iron powder on the roller surface. As a result, it is found that the ability of grip between the steel and the roller coated by a porous self-fluxing alloy contained to 5 ~ 10 wt% of Fe in the coating layer is improved compared to the roller coated by Ni-Cr. This is because the porosities are made after Fe contained in the roller is partially alloyed by heating with a furnace in the fusing process and the rest is eliminated by oxidation and dissolution.

A Study on the Comparison of Advanced Oxidation Reactions Including UV, $Fe^{2+}$, and $H_2O_2$ for the Degradation of Pentachlorophenol (UV와 $Fe^{2+}$, 그리고 $H_2O_2$를 조합한 고급산화 공정에서의 Pentachlorophenol의 분해 속도 연구)

  • Son, Hyun-Seok;Kim, Moon-Kyung;Zoh, Kyung-Duk
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.7
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    • pp.846-851
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    • 2007
  • This study was performed to compare and to examine the degradation efficiencies and degradation mechanism of pentachlorophenol(PCP) by UV, $UV/H_2O_2$, $Fe^{2+}$, $Fe^{2+}/H_2O_2$, and $UV/Fe^{2+}/H_2O_2$ processes. The pseudo-first order rate constant was compared in each process. The addition of $H_2O_2$ increased the rate constant by 13 times compared to the reaction with UV alone. The reaction rate in $Fe^{2+}$ reaction with PCP increased 4 times and 7.25 times by adding 180 mM $H_2O_2$ and 16 mM $H_2O_2$, respectively. Compared to that with $Fe^{2+}/H_2O_2$, the rate constant of the reaction with UV alone reaction increased 3.1 times. These results indicates the enhancement of reaction rate is closely related to the generation of OH radical. The degree of the iron sludge production observed in $Fe^{2+}/H_2O_2$ reaction was significantly reduced by irradiating UV in this process.

Analysis of Articles Published in the Korean Journal of Oriental Medical Prescription (대한한의학방제학회지에 게재된 논문 동향 분석)

  • Kim, An-Na;Song, Mi-Young;Bae, Sun-Hee;Kim, Chul;Kim, Ha-Young;Kim, Young-Sik;Park, Kyoung-Bum;Kim, Hong-Jun
    • Herbal Formula Science
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    • v.18 no.1
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    • pp.57-77
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    • 2010
  • Objective : This study reviews the recent trend of oriental medical prescription research. The data examined are the articles published in the Korean Journal of Oriental Medical Prescription from 1990 to 2009. Method : The data are retrieved through the internet database Oriental Medicine Advanced Searching Integrated System (OASIS) and the collection of the Korean Journal of Oriental Medical Prescription. The number of articles examined is 385, published in 25 volumes of the journal. This study examines the nature of the articles, research methods, subjects, and author information. Research subjects are sorted out by the OASIS key words for the articles published before 1999, and by key word indexes cited in the abstracts for the articles published sinceafter. Results : Among the 385 articles collected, 206 are research articles, 143 philological articles, 35 case studies, and 1 special contribution. A majority of research articles are experimental studies (199 articles or 96.6%), while clinical reports (5 articles or 2.43%), and others studies (2 articles) occupy a small portion. Most of experimental studies (183 articles or 91%) examine the effectiveness of certain prescriptions or treatments. Among the effectiveness studies, 114 articles (62.3%) employ in vivo experiment design, 52 articles (28.42%) in vitro experiments, and 17 articles (9.29%) both in vivo and in vitro experiments. In terms of research subject, the most frequently indexed key words are hepatotoxicity among diseases (9 articles), Bojungikgitang (Bu-Zhong-Yi-Qi-Tang) among prescriptions (10 articles), Buja (Acontii Tuber) among meteria medica (4 articles), immunity and anti-oxidation among efficacy terminology (6 articles each), and Donguibogam(東醫寶鑑) among references in the key words (25 articles). Universities are the main affiliation of authors (76.42%), followed by university hospitals (6.71%), non-academic research institutes (5.55%), local clinics (4.67), academic research institutes (2.81%), hospitals (2.38%), and others (1.44%). The most affiliated institute of the first and correspondent authors is Wonkwang University. In terms of authorship, co-authorship outnumbers sole-authorship by 82.08% to 17.92%. The proportion of authors of a single article is 63.54% which is near the author productivity distribution described by Lotka's law.

The Method of Exposure Determination for Digital Infrared Photography in Forensic Field (법과학 분야에서 디지털 적외선 사진을 위한 노출 결정 방법)

  • Kim, Sang-Ki;Kim, Yoo-Jin
    • The Journal of the Korea Contents Association
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    • v.14 no.2
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    • pp.181-191
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    • 2014
  • In the past, making IR photography needed somewhat complicated process, so its application fields were limited. However, it has become easy to make IR photography with advanced digital technology, so it is expected that the fields of IR photography and existing limit due to difficult making process will be expanded. Therefore, in this study, it is decided that the need of IR standard chart which allows us to manage exposure and tone of IR photography for scientific purpose will increase. Two methods were used to make IR standard chart. First method is to use aluminum. When aluminum has oxide coating through anodic oxidation, it has high durability, corrosion resistance and heat resistance. Also, IR reflectance of aluminum can be controlled in some degree depending on the thickness of oxide coating. Second method is to use pigments. Yellow 10P150 pigment is used for the brightest patch. This pigment is appropriate in this study due to high heat resistance and IR reflectance. Carbon black is used for the darkest patch. Carbon black absorbs much IR, and its color is not faded by any source of light. IR reflectance is adjusted elaborately by mixing two pigments. Finally, 6 patches are selected with consideration for actual IR reflectance of patches. As a result, IR reflectance of random subjects can be known approximately and IR photographs can have appropriate contrast with the IR standard chart.

A Study OH the Character and Activity of $TiO_2$ Photocatalysts Prepared With Various Condition (다양한 조건에서 제조된 $TiO_2$ 광촉매 특성 및 활성에 관한 연구)

  • Kim, Seung-Min;Youn, Tae-Kawun;Hong, Dae-Il;Kim, Sung-Kuk;Park, Sang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.932-938
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    • 2005
  • [ $TiO_2$ ] nanoparticles were prepared from the precipitation in $TiCl_4$ and the sol-gel profess in $Ti(OC_3H_7)_4$ as starting materials with various synthetic conditions. The samples were characterized by XRD, SEM, and TEM testing techniques. The photocatalytic degradation of congo red has been investigated in $TiO_2/UV$ process to evaluate photocatalytic activities for the samples. $TiO_2$ nanoparticles calcined at $400^{\circ}C$ had the best photocatalytic activity with the rate constant of the degradation of congo red as $0.0319\;min^{-1}$. The rate constant of $TiO_2$ photocatalysts was increased with the calcination temperature under $400^{\circ}C$ and decreased with the calcination temperature upper $400^{\circ}C$. In the case of $TiO_2$ photocatalysts, the photocatalytic activity wasn't greatly affected by the frequencies of usage. In the similar synthesis condition, the degradation efficiency of the $TiO_2$ particle prepared by $TiCl_4$ was increased to 8.8%, when the rate was compared with the sample prepared by $Ti(OC_3H_7)_4$. The photocatalytic activities of $TiO_2$ photocatalysts synthesized by $Ti(OC_3H_7)_4$ with various conditions were also discussed.

Distribution and Risk Assessment of Bisphenol-A in Tap Water from Rehabilitated Indoor Water Service Pipe (갱생 옥내급수관 수돗물에서 비스페놀-A 분포 및 위해성 평가)

  • Jeong, Gwanjo;Son, Boyoung;Lee, Inja;Ahn, Chihwa;Kim, Junil;Moon, Boram;Lee, Suwon;Ahn, Jaechan;Kim, Bogsoon;Chung, Deukmo
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.7
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    • pp.371-376
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    • 2016
  • In this study, the survey of bisphenol-A in indoor water service pipes rehabilitated with epoxy resin was conducted and the risk assessment was done to investigate the effect on the human health to drink tap water. Bisphenol-A in raw water was detected in a range of 50~118 ng/L in all samples, where the limit of quantification was 10 ng/L. This is caused by inflow of the sewage effluent or the tributaries of the surrounding area containing bisphenol-A. Bisphenol-A was not detected in finished water after the advanced water treatment process. It was achieved by its removal from the processes of flocculation-precipitation and oxidation of ozone and chlorine and by being changed to other by-product materials. For the indoor water service pipe, bisphenol-A was not detected in all cases which was not coated with epoxy resin. However, when epoxy resin is lined within the indoor water service pipe, bisphenol-A was identified at maximum level of 521 ng/L and was detected above the limit of quantitation at 68 percentages of all samples. The Hazard Quotient (HQ) at the maximum level (521 ng/L) of the detected bisphenol-A is 0.004, which is less than the reference value of 0.1 for the tap water intake. Therefore, it is considered that the detected levels of bisphenol-A in this study would be safe to drink tap water.

Bilolgical Activities of Conjugated Linoleic Acid (CLA) and Animal Products (Conjugated Linoleic Acid (CLA)의 생리활성과 축산식품)

  • Hur, S.J.;Lee, J.I.;Ha, Y.L.;Park, G.B.;Joo, S.T.
    • Journal of Animal Science and Technology
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    • v.44 no.4
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    • pp.427-442
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    • 2002
  • Conjugated linoleic acid(CLA) is a collective term for a group of positional (c8, c10; c9, c11; c10, c12, and c11, c13) and geometric(cis,cis; cis,trans; trans,cis; and trans,trans) isomers of octadecadienoic acid (linoleic acid) with conjugated double bond system. CLA has been shown to have a variety of biological effects. Major effects of CLA on health, such as anti-cancer, anti-oxidation, anti-atherosclerosis and improving immuno-responses, might be derived or partially derived from the alternated lipid metabolism after CLA feeding. Most of studies on the effect of CLA on fat metabolism are concentrated on rats, mice, pigs and other mammals. The CLA inhibited carcinogen-induced neoplasia in several animal models and inhibited the proliferation of human malignant melanoma, colorectal and breast cancer cells and CLA reduced the atherosclerosis. Several studies have determined the antioxidant property of CLA; however, the property still remains controversial. Some of the studies have shown that CLA acted as an antioxidant, whereas some other studies have demonstrated that CLA might be a prooxidant. Several studies suggested that CLA could reduce fat accumulation in mammals. CLA was suggested to promote muscle growth and reduce fat deposition in mouse, and improve feed efficiency in rats. CLA has been shown to inhibit the activity of stearoyl-CoA reductase. CLA also reduced the content of arachidonic acid. Since arachidonic acid, and eicosapentaenoic acid (EPA) and docosahexenoic acid (DHA) are synthesized by different pathways, reducing the synthesis of arachidonic acid may not mean reducing that of EPA and DHA. Many sutdies have been shown biological effects of CLA. Therefore, further research is needed to answer the following questions: 1) how to synthesize the new CLA by new methods, 2) why CLA has shown biological effects, 3) how to increase CLA effects in animal products.

A Study on the Characteristics of Livestock Manure Treatment Facility in Korea (국내 가축분뇨 처리시설 형태별 특성조사 분석)

  • Jeong, Kwang-Hwa;Kim, Jung-Kon;Khan, Modabber Ahmed;Han, Duk-Woo;Kwag, Jung-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.4
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    • pp.28-44
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    • 2014
  • Due to development of the national economy growth, livestock goods consumption has rapidly increased over the past 30 years. It has led livestock breeders to increase their livestock numbers. An increased number of livestock have consequently resulted in an increasing animal feces generation. According to the agricultural statistics provided by the Bureau of Statistics, livestock manure amounts to 47,235 thousand tons in 2013. To treat livestock manure, various types of treatment facilities like composting, liquid fertilization, purification, and anaerobic digestion facilities are being applied. In composting facility, there are four kinds of agitation system: escalator, paddle, screw and rotary type. In case of liquid fertilization process, there are two types of system: aeration and anoxic type. There are about 8,000 liquid fertilization facilities for treatment livestock manure in Korea. For purification of livestock manure, the treatment process is divided by three steps: Solid/Liquid separation process, Secondary purification process and advanced oxidation process. About 21 thousand tons of livestock manure was treated by anaerobic digestion facility in 2012. In every type of facility for livestock manure treatment, it is very important to choose the optimal deodorization equipment for the livestock manure treatment facility. In this study, the investigation has been carried out for six years to analyse the characteristics of livestock manure treatment facilities and related technique of Korea.

Study on Anti-oxidant and Anti-inflammatory Activity of the Tissue-cultured Shoot Clumps from Raoulia australis (라울리아 신초 추출물의 항산화 및 항염 효능에 관한 연구)

  • Park, Chang-Min;Han, Na-Kyeong;Joung, Min-Seok;Paek, Kee-Yoeup;Choi, Jong-Wan
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.4
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    • pp.349-357
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    • 2014
  • In this study, the shoot clumps extract of tissue-cultured Raoulia australis using the bioreactor culture system was tested for use a natural cosmetic ingredient. Tissue-cultured R. australis shoot clumps extract was tested anti-oxidant and anti-inflammatory activity for a cosmetic application. R. australis is a wild herbaceous plant of the asteraceae growing in New Zealand and Australia. Previous studies have reported anti-viral activity of the inhibitory effects for the growth of viruses induced meningitis, bronchitis and respiratory diseases but other biological effects are unknown. The shoot clumps extract of tissue-cultured R. australis showed higher anti-oxidant effect and anti-inflammatory effect than the natural R. australis extract. In DPPH, NBT and ABTS assay, the shoot clumps extract of tissue-cultured R. australis enhanced radical scavenging activity (up to 10~25% at $50{\mu}L/mL$) more than the natural R. australis extract. Also, the shoot clumps extract of tissue-cultured R. australis inhibited expression of iNOS and COX-2 protein in LPS-stimulated Raw 264.7 macrophages more than the natural R. australis extract. From this study, the shoot clumps extract of tissue-cultured R. australis displayed strong possibility as a new natural cosmetic ingredient for skin-care products.

Biological stability in the ozone and peroxone pretreatment systems in river water (하천수 내 생물학적 안정성에 따른 유기물 특성변화와 오존산화기반 전처리 연구)

  • Park, Se-Hee;Noh, Jin-Hyung;Park, Ji-Won;Maeng, Sung-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.159-168
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    • 2018
  • Climate change is believed to increase the amount of dissolved organic matter in surface water, as a result of the release of bulk organic matter, which make difficult to achieve a high quality of drinking water via conventional water treatment techniques. Therefore, the natural water treatment techniques, such as managed aquifer recharge (MAR), can be proposed as a alternative method to improve water quality greatly. Removal of bulk organic matter using managed aquifer recharge system is mainly achieved by biodegradation. Biodegradable dissolved organic carbon (BDOC) and assimilable organic carbon (AOC) can be used as water quality indicators for biological stability of drinking water. In this study, we compared the change of BDOC and AOC with respect to pretreatment methods (i.e., ozone or peroxone). The oxidative pretreatment can transform the recalcitrant organic matter into readily biodegradable one (i.e., BDOC and AOC). We also investigated the differences of organic matter characteristics between BDOC and AOC. We observed the decreases in dissolved organic carbon (DOC) and the tryptophan-like fluorescence intensities. Liquid chromatographic - organic carbon detection (LC-OCD) analysis also showed the reduction of the low molecular weight (LMW) fraction (15% removed, less than 500 Da), which is known to be easily biodegradable, and the biopolymers, high molecular weight fractions (66%). Therefore, BDOC consists of a broad range of organic matter characteristics with respect to molecular weight. In AOC, low molecular weight organic matter and biopolymers fraction was reduced by 11 and 6%, respectively. It confirmed that biodegradation by microorganisms as the main removal mechanism in AOC, while BDOC has biodegradation by microorganism as well as the sorption effects from the sand. $O_3$ and $O_3+H_2O_2$ were compared with respect to biological stability and dissolved organic matter characteristics. BDOC and AOC were determined to be about 1.9 times for $O_3$ and about 1.4 times for $O_3+H_2O_2$. It was confirmed that $O_3$ enhanced the biodegradability by increasing LMW dissolved organic matter.