• 한국응용과학기술학회지
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• 제18권1호
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• pp.49-54
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• 2001

Ultra-thin films of organic charge transfer complex were prepared on a hydrophilic substrate by Langmuir-Blodgett(LB) technique. In this study, the photoelectric properties of a LB film consisting of (N-docosyl quinolinium)-TCNQ(1:2) complex was investigated. The visible light(${\lambda}$ : 700 nm) of xenon lamp was illuminated on the LB films and light absorptivity and photoconductivity were observed. The photocurrent increased linearly and was saturated at the light intensity of 23 ${\mu}W/cm^{2}$.

• 상하수도학회지
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• 제33권6호
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• pp.469-480
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• 2019

This study was conducted to evaluate the degradation and mineralization of PPCPs (Pharmaceuticals and Personal Care Products) using a CBD(Collimated Beam Device) of UV/H₂O₂ advanced oxidation process. The decomposition rate of each substance was regarded as the first reaction rate to the ultraviolet irradiation dose. The decomposition rate constants for PPCPs were determined by the concentration of hydrogen peroxide and ultraviolet irradiation intensity. If the decomposition rate constant is large, the PPCPs concentration decreases rapidly. According to the decomposition rate constant, chlortetracycline and sulfamethoxazole are expected to be sufficiently removed by UV irradiation only without the addition of hydrogen peroxide. In the case of carbamazepine, however, very high UV dose was required in the absence of hydrogen peroxide. Other PPCPs required an appropriate concentration of hydrogen peroxide and ultraviolet irradiation intensity. The UV dose required to remove 90% of each PPCPs using the degradation rate constant can be calculated according to the concentration of hydrogen peroxide in each sample. Using this reaction rate, the optimum UV dose and hydrogen peroxide concentration for achieving the target removal rate can be obtained by the target PPCPs and water properties. It can be a necessary data to establish design and operating conditions such as UV lamp type, quantity and hydrogen peroxide concentration depending on the residence time for the most economical operation.

• Bulletin of the Korean Chemical Society
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• 제2권2호
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• pp.71-75
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• 1981

Vacuum ultraviolet photolysis of ethyl bromide was studied at 104.8-106.7 nm (11.4-11.6 eV) in the pressure range of 0.2-18.6 torr at $25^{\circ}$ using an argon resonance lamp with and without additives, i.e., NO and He. Since the ionization potential of $CH_3CH_2Br$ is lower than the photon energy, the competitive processes between the photoionization and the photodecomposition were also investigated. The observations indicated that 50% of absorbed light leads to the former process and the rest to the latter one. In the absence of NO the principal reaction products for the latter process were found to be $CH_4, C_2H_2, C_2H_4, C_2H_6, and C_3H_8$. The product quantum yields of these reaction products showed two strikingly different phenomena with an increase in reactant pressure. The major products, $C_2H_4$ and $C_2H_6$, showed positive effects with pressure whereas the effects on minor products were negative in both cases, i.e., He and reactant pressures. Addition of NO completely suppresses the formation of all products except $C_2H_4$ and reduces the $C_2H_4$ quantum yield. These observations are interpreted in view of existence of two different electronically excited states. The initial formation of short-lived Rydberg transition state undergoes HBr molecular elimination and this state can across over by collisional induction to a second excited state which decomposes exclusively by carbon-bromine bond fission. The estimated lifetime of the initial excited state was ${\sim}4{\times}10^{-10}$ sec. The extinction coefficient for $CH_3CH_2Br$ at 104.8-106.7 nm and $25{\circ}$ was determined to be ${varepsilon} = (1/PL)ln(I_0/I_t) = 2061{\pm}160atm^{-1}cm6{-1}$ with 95% confidence level.

• 한국재료학회지
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• 제8권4호
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• pp.345-353
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• 1998

음이온 리간드로 hfac이 배위된 세 가지 종류의 구리(l) 전구체들의 열적 안정성, 기상분해 특성, 증착 특성 등을 연구하였다. $^{1}$H-NMR결과로부터 (hfac) Cu(VTMS) (hfac=hexafluoroacetylacetonate, VTMS=vinyltrimethylsilane)와 (hfac)Cu(VTMS) (VTMOS=vinyltrimethoxysilane)는 열적으로 안정한 화합물이라는 것을 확인할 수 있었으며, (hfac)Cu(ATMS)(STMS=allyltrimethylsilane)는 다른 전구체에 비해 열적으로 불안정한 화합물이라는 것을 확인할 수 있었다. In-situ FT-IR을 이용하여 기상 분해 특성을 연구한 결과 (hfac)Cu(VTMS)의 경우 $150^{\circ}C$부근에서 $Cu(hfac)_{2}$, $240^{\circ}C$부근에서 free한 상태의 hfac의 생성을 확인할 수 있었으며, 이러한 특성이 박막의 증착 속도와 물성에 미치는 영향을 확인하였다. 그리고 이들 전구체들의 증착 특성을 연구하였으며 (hfac)Cu(ATMS)의 경우 아르곤 운반 기체하에서 기판 온도가 $60^{\circ}C$일 때 구리 박막이 증착이 시작되는 것을 관찰할 수 있었는데, 이러한 낮은 증착 온도는 상대적으로 약한 구리와 ATMS의 결합력에 의한 것으로 생각된다.

• 상하수도학회지
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• 제26권2호
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• pp.219-228
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• 2012

Problems due to the taste and odor in drinking water are common in treatment facilities around the world. Taste and odor are perceived by the public as the primary indicators of the safely and acceptability of drinking water, and are mainly caused by the presence of two semi-volatile compounds-2-methylisoborneol(2-MIB) and geosmin. Conventional treatment processes in water treatment plants, such as coagulation, sedimentation and chlorination have been found to be ineffective for the removal of 2-MIB and geosmin. Pulse UV system is a new UV irradiation system that is a non-mercury lamp-based alternative to currently used continuous wave systems for water disinfection. This study shows pulse UV system to be effective in treatment of these two compounds. Geosmin removal efficiency of UV process alone achieved approximately 70% at 10sec contact time. 2-MIB removal efficiency of UV only process achieved approximately 60% at 10sec contact time. The addition of $H_{2}O_{2}$ 7mg/L increased geosmin and 2-MIB removal efficiency upto approximately 94% and 91%, respectively.

• 설비공학논문집
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• 제16권1호
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• pp.1-7
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• 2004

This study has been numerically conducted to investigate the removal efficiency of Volatile Organic Compound (VOC) for different photocatalytic honeycomb filters. Recently, the photocatalysis is being applied to air-cleaner, air-conditioner and vacuum-cleaner with the capability of air-purification, sterilization and antibiosis. However, photocatalysis is less efficient than other methods for removing VOC except in the case of low concentration. So far most of studies have focused on an improvement of the photocatalytic materials, but this study have placed emphasis on the improvements of shape of photocatalytic honeycomb filter. UV irradiation, concentration profile and pressure drop have been investigated for different cross sections of filters and for different filter lengths. Light intensity is dropped sharply with increasing distance from the UV-lamp, and becomes very low in the middle of the filters. Since photocatalytic reaction rate is a function of light intensity, VOC concentration gradient might be small in the middle of long filters. Thus, most of reaction have risen within only three times of dimensionless axial distance. These results can be used effectively for the design of advanced photocatalytic honeycomb filters.

• 한국콘텐츠학회논문지
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• 제11권3호
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• pp.65-72
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• 2011

첨단 과학기술의 등장으로 유전자 정보의 활용 방법과 다양한 분야에서의 융합 형태가 속출하고 있는 현실에 우리는 서있다. 바이오 데이터의 분석을 기반으로 많은 연구와 개발이 이루어지면서 새로운 연관성과 정보를 찾아내기 위한 바이오인포매틱스의 많은 목표들이 설정되고 있는 실정에서 데이터의 정확한 분석을 도울 수 있는 도구의 필요성이 더욱 더 대두되고 있다. 본 논문에서는 기존에 제공되는 바이오 데이터 분석을 위한 여러 가지 도구들의 단점들을 보완할 수 있는 시스템을 개발함으로써 사용자에게 보다 편리한 연구 도구를 제공하고자 한다. 바이오 데이터 분석을 위한 작업으로 ORF 축출, 바이오 서열 정보 검색 및 유사성 비교등의 작업을 분리된 환경이 아닌 통합된 환경에서 제공하고 기존 분석 시스템에서 부족한 연속성을 제공하도록 설계하였다.

• 한국실내디자인학회논문집
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• 제21권6호
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• pp.129-136
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• 2012

As the importance of eco-friendly and energy saving issues are emphasized in lighting as consciousness about energy saving is elated worldwide, demand for natural resources such as gas increases, supply of LED lighting is spread. Owing to white LED's development and price fall. It is expected to LED High Luminance Emitting Diode. LED's brightness and long life-time that surpass fluorescent light in the latest as well as is used by back light source of thin film LCD, low electric power attrition rate by advantage do and widen the market at the world lighting lamp market that is potential market. Accordingly, study about suitability of LED lighting is activated but space that apply actual LED lighting fixtures yet is less and advanced researches about LED fixtures' applied apaces are slight compared to existing light source up to now because is not many on this. The result of the experiment shows similar tendency with the existing light sources'. Through a psychological reaction experiment in the LED lighting experiencing space that can control of color temperature and lighting level, this study is wished to use to the data for lighting design of space that LED lighting fixtures are applied hereafter.

• 한국정보처리학회:학술대회논문집
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• 한국정보처리학회 2002년도 춘계학술발표논문집 (상)
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• pp.261-264
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• 2002

자동차 전조등에서 나오는 데이터는 다양한 패턴을 가지는 영상자료와 부분적으로 보이는 문자자료이다. 내용기반 영상검색을 통해 자동차 전조등에서 검사자가 판독하는 텍스트와 부분적인 전조등의 영상정보로 차량의 정보를 추출하기 위한 검색 방법을 국립과학수사연구소의 자료를 기반으로 설계하였으며, 영상검색에 사용된 영상특징값의 구성과 영상 검색방법을 연구하였다. 본 논문에서는 영상데이터의 검색을 위해 효과적인 영상특징이 추출 되도록 향상된 방법론을 제시하였다. 특징함수에 대한 유효성 검증을 위해 샘플 영상에서 각 후보 특징함수들에 대한 결과값들을 비교하였으며, 이를 기반으로 유효한 특징함수를 찾아서 검색에 사용되어지도록 구성하였다. 사용되어진 영상의 특징값은 전조등 영상이 가지는 다수의 텍스쳐함수와 가로, 세로 성분값을 사용하였다. 영상 검색을 위해 추출된 영상 특징값을 데이터베이스화하고 용의차량의 전조등 영상을 질의 영상으로 하여 후보 차량에 대한 정보를 검색하도록 하였다.

• 대한임베디드공학회논문지
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• 제10권5호
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• pp.325-333
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• 2015

Vision based night-time vehicle detection has been an emerging research field in various advanced driver assistance systems(ADAS) and automotive vehicle as well as automatic head-lamp control. In this paper, we propose night-time vehicle detection method based on multi-class support vector machine(SVM) that consists of thresholding, labeling, feature extraction, and multi-class SVM. Vehicle light candidate blobs are extracted by local mean based thresholding following by labeling process. Seven geometric and stochastic features are extracted from each candidate through the feature extraction step. Each candidate blob is classified into vehicle light or not by multi-class SVM. Four different multi-class SVM including one-against-all(OAA), one-against-one(OAO), top-down tree structured and bottom-up tree structured SVM classifiers are implemented and evaluated in terms of vehicle detection performances. Through the simulations tested on road video sequences, we prove that top-down tree structured and bottom-up tree structured SVM have relatively better performances than the others.