• Title/Summary/Keyword: Advanced Composite Materials

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A Study on the Microstructure and Physical Properties of Cold Sprayed Cu/CNT Composite Coating (저온 분사 코팅법으로 제조된 Cu/CNT 복합 코팅층의 미세조직 및 물성 연구)

  • Kwon, Seong-Hee;Park, Dong-Yong;Lee, Dae-Yeol;Euh, Kwang-Jun;Lee, Kee-Ahn
    • Korean Journal of Metals and Materials
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    • v.46 no.3
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    • pp.182-188
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    • 2008
  • Carbon nanotubes(CNTs) have outstanding mechanical, thermal, and electrical properties. Thus, by placing nanotubes into appropriate matrix, it is postulated that the resulting composites will have enhanced properties. Cold spray can produce thick metal-based composite coatings with very high density, low oxygen content, and phase purity, which leads to excellent physical properties. In this study, we applied cold spray coating process for the consolidation of Cu/CNT composite powder. The precursor powder mixture, in which CNTs were filled into copper particles, was prepared to improve the distribution of the CNT in copper matrix. Pure copper coating was also conducted by cold spraying as a reference. Annealing heat treatment was applied to the coating to examine its effect on the properties of the composite coating. The hardness of Cu/CNT composite coating represented similar value to that of pure copper coating. It was importantly found that the electrical conductivity of the Cu/CNT composite coating significantly increased from 53% for the standard condition to almost 55% in the optimized condition, taking annealed ($500^{\circ}C/1hr$.) copper coating as a reference (100%). The thermal conductivity of Cu/CNT composite coating layer was higher than that of pure Cu coating. It was also found that the electrical and thermal conductivities of Cu/CNT composite could be improved through annealing heat treatment. The microstructural evolution of Cu/CNT coating was also investigated and related to the macroscopic properties.

Electrical Properties of Gadolinium-doped Ceria/Magnesia (CGO/MgO) Composite Electrolytes (Gadolinium-doped Ceria/Magnesia (CGO/MgO) 복합체 전해질의 전기적 특성 분석)

  • Jo, Seung-Hwan;Muralidharan, P.;Kim, Do-Kyung
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.470-474
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    • 2008
  • Composites of gadolinium-doped ceria/magnesia(CGO/MgO) were synthesized and characterized for the electrolytes of intermediate temperature solid oxide fuel cells. XRD and SEM results revealed that composite electrolytes consisted of their own phases after sintering at $1400^{\circ}C$ without noticeable solid solution of Mg into CGO. As the MgO content increased, the total electrical conductivity decreased, which might be attributed to the decrease of grain boundary conductivity, possibly due to the lowering of the continuity of the CGO grains and blocking effects of the insulating MgO phase. The space charge effect may not be a significant factor to affect the electrical conductivity of the CGO/MgO composites.

Manufacturing and Properties of Metal Based Composite Produced By Friction Stir Processing (마찰교반프로세스를 이용한 금속기 복합소재 제조 및 특성)

  • Choi, Don-Hyun;Yeon, Yun-Mo;Jung, Seung-Boo
    • Journal of Welding and Joining
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    • v.30 no.5
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    • pp.27-33
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    • 2012
  • Friction stir processing (FSP), developed based on the basic principles of friction stir welding(FSW), a solid-state joining process originally developed for various metal alloys, is an emergingmetalworking technique that can provide localized modification and control of microstructures in near-surface layers of processed metallic components. The FSP causes intense plastic deformation, material mixing, and thermal exposure, resulting in significant microstructural refinement, densification, and homogeneity of the processed zone. The FSP technique has been successfully used for producing the fine-grained structure and surface composite, modifying the microstructure of materials, and synthesizing the composite and intermetallic compound in situ. In this review article, the current state of the understanding and development of FSP is addressed.

Grinding Behaviour of Aluminum Powder for Al/CNTs Nano Composites Fabrication by Dry Grinding Process Using a High Speed Planetary Ball Mill (초고속 유성형 매체 분쇄기를 이용한 건식분쇄공정에서 Al/CNTs 복합재 제조를 위한 알루미늄분말의 분쇄거동)

  • Choi, Heekyu;Lee, Jehyun;Kim, Seongsoo;Choi, Gyungpil;Bae, Daehyung;Lee, Sungbak;Lee, Woong
    • Korean Journal of Materials Research
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    • v.23 no.2
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    • pp.89-97
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    • 2013
  • The study of grinding behavior characteristics on aluminum powders and carbon nano tubes (CNTs) has recently gained scientific interest due to their useful effect in enhancing advanced nano materials and components, which significantly improves the property of new mechatronics integrated materials and components. We performed a series of dry grinding experiments using a planetary ball mill to systematically investigate the grinding behavior during Al/CNTs nano composite fabrication. This study focused on a comparative study of the various experimental conditions at several variations of rotation speeds, grinding time and with and without CNTs. The results were monitored for the particle size distribution, median diameter, crystal structure from XRD pattern and particle morphology at a given grinding time. It was observed that pure aluminum powders agglomerated with low rotation speed and completely enhanced powder agglomeration. However, Al/CNTs composites were achieved at maximum experiment conditions (350 rpm, 60 min.) of this study by a mechanical alloy process for Al/CNTs mixed powders because the grinding behavior of Al/CNTs composite powder was affected by addition of CNTs. Indeed, the powder morphology and crystal size of the composite powders changed more by an increase of grinding time and rotation speed.

Application of Composites to Construction Industry and Development of Concrete Filled Composite Compression Member (복합소재의 건설분야 응용현황과 콘크리트 합성압축부재의 개발)

  • 이성우;박신전
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.183-188
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    • 1999
  • Due to many advantages of advanced composite materials, research on the application of composites to the construction industry is initiated. In this paper, fabrication methods efficient for infrastructures and application examples of each method are discussed. It also presents the structural characteristics of concrete filled glass fiber reinforced composite tubular member. Experimental results shows that strength and ductility of composite compression member is considerably increased due to concrete confinement action of composite surface.

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The Effects of Different Cross Section on Natural Frequency of the Advanced Composite Materials Road Structures (복합신소재 도로구조물의 변환단면이 고유진동수에 미치는 영향)

  • Han, Bong Koo
    • International Journal of Highway Engineering
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    • v.15 no.3
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    • pp.23-29
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    • 2013
  • PURPOSES: This paper aims to give a guideline and the way to apply the advanced composite materials theory to the road structures with different cross sections to the practicing engineers. METHODS: To simple but exact method of calculating natural frequencies corresponding to the modes of vibration of road structures with different cross sections and arbitrary boundary conditions. The effect of the $D_{22}$ stiffness on the natural frequency is rigorously investigated. RESULTS: Simple method of vibration analysis for calculating the natural frequency of the different cross sections is presented. CONCLUSIONS: Simple method of vibration analysis for calculating the natural frequency of the different cross sections is presented. This method is a simple but exact method of calculating natural frequencies of the road structures with different cross sections. This method is extended to be applied to two dimensional problems including composite laminated road structures.

Surface and Chemical Properties of Surface-Modified UHMWPE Powder and Mechanical and Thermal Properties of Its Impregnated PMMA Bone Cement V. Effect of Silane Coupling Agent on the Surface Modification of UHMWPE Powder

  • Yang Dae Hyeok;Yoon Goan Hee;Shin Gyun Jeong;Kim Soon Hee;Rhee John M.;Khang Gilson;Lee Hai Bang
    • Macromolecular Research
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    • v.13 no.2
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    • pp.120-127
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    • 2005
  • Conventional poly(methyl methacrylate) (PMMA) bone cement has been widely used as an useful biopolymeric material to fix bone using artificial prostheses. However, many patients had to be reoperated, due to the poor mechanical and thermal properties of conventional PMMA bone cement, which are derived from the presence of unreacted MMA liquid, the shrinkage and bubble formation that occur during the curing process of the bone cement, and the high curing temperature ($above 100^{\circ}C$) which has to be used. In the present study, a composite PMMA bone cement was prepared by impregnating conventional PMMA bone cement with ultra high molecular weight polyethylene (UHMWPE) powder, in order to improve its mechanical and thermal properties. The UHMWPE powder has poor adhesion with other biopolymeric materials due to the inertness of the powder surface. Therefore, the surface of the UHMWPE powder was modified with two kinds of silane coupling agent containing amino groups (3-amino propyltriethoxysilane ($TSL 8331^{R}$) and N-(2-aminoethyl)-3-(amino propyltrimethoxysilane) ($TSL 8340^{R}$)), in order to improve its bonding strength with the conventional PMMA bone cement. The tensile strengths of the composite PMMA bone cements containing $3 wt\%$ of the UHMWPE powder surface-modified with various ratios of $TSL 8331^{R}$ and $TSL 8340^{R}$ were similar or a little higher than that of the conventional PMMA bone cement. However, no significant difference in the tensile strengths between the conventional PMMA bone cement and the composite PMMA bone cements could be found. However, the curing temperatures of the composite PMMA bone cements were significantly decreased.

Heat and Wear Resistance Characterization of SiCp Reinforced Al Matrix Composites (SiCp입자강화 Al 복합재료의 내열 및 마모특성)

  • Kim, Sug-Won;Kim, Wan-Ki;Woo, Kee-Do;Ahn, Haeng-Keun
    • Journal of Korea Foundry Society
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    • v.20 no.6
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    • pp.377-385
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    • 2000
  • Al matrix composites as the most promising MMCs can be expected to be excellent engineering materials in the nearest future. So as to improve material properties of composite, many manufacturing processes have been developed. Among them, squeeze casting process which offers fine microstructure and near-net-shape is one of the most successful MMCs manufacturing processes. But, in case of with subsieve size particles (under 44 ${\mu}m$), it is very difficult to homogeneously distribute particles in matrix of Al matrix composite by various casting processes, including squeeze casting used so far. Duplex process which was developed in previous study was used to distribute the particle of subsieve size more homogeneously in matrix of Al matrix composite. Microstructures, wear and heat resistance characterization of Al-Si-Cu-Mg-(Ni)/SiCp manufactured by duplex process were examined to clarify the effect of manufacturing conditions, particle size of reinforcement and alloying elements. Al matrix composites reinforced with SiCp(10 ${\mu}m$) have the lowest wear amount among composites reinforced with 3 ${\mu}m$, 5 ${\mu}m$ and 10 ${\mu}m$ SiCp. The wear amount of Al matrix composites with 10 wt.% SiCp(3, 5, 10 ${\mu}m$) was decreased according to the increase of the sliding speed because abrasive wear takes place at high sliding speed of 4m/s and worn debris with block type occurs at low sliding speed of 1m/s. As for heat resistance, it is made clear that remarkable heat resistance property can be obtained by addition of Ni element in Al matrix composites.

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