• Title/Summary/Keyword: Adsorption efficiency

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Development of Inner Packaging Material for Maintaining the Freshness of Fruits and Vegetables

  • Won, Jong-Myoung;Song, Je-Yun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.1 s.119
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    • pp.64-68
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    • 2007
  • The oak and pine charcoal were used to develop the inner packaging material for maintaining the freshness of vegetables and fruits, and to investigate the possibility in the application for inner packaging. The effects of the charcoal type, species, particle size, and grammage on the adsorption efficiency of ethylene gas were studied. White charcoal has superior ethylene gas adsorption performance to those of black charcoal. Pine charcoal was superior to oak charcoal in the ethylene gas adsorption. Higher gas adsorption was obtained by the higher grammage sheet. The difference in the adsorption efficiency was not significant between ONP and KOCC.

나노 크기 적철석 입자 피복 모래를 이용한 지하수내 비소 3가와 5가의 제거 기술 개발

  • 고일원;이철효;이상우;김주용;김경웅
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.78-82
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    • 2003
  • Development of hematite-coated sand was evaluated for the application of the PRB (permeable reactive barrier) in the arsenic-contaminated subsurface of the metal mining areas. The removal efficiency of As(III) and As(V), the effect of anion competition and the capability of arsenic removal in the flow system were investigated through the experiments of adsorption isotherm, arsenic removal kinetics against anion competition and column removal. Hematite-coated sand followed a linear adsorption isotherm with high adsorption capacity at low level concentrations of arsenic (< 1.0 mg/l). When As(III) and As(V) underwent adsorption reactions in the presence of anions (sulfate, nitrate and bicarbonate), sulfate caused strong inhibition of arsenic removal, and bicarbonate and nitrate caused weak inhibition due to specific and nonspecific adsorption onto hematite, respectively. In the column experiments, high content of hematite-coated sand enhance the arsenic removal, but the amount of the arsenic removal decreased due to the higher affinity of As(V) than As(III) and reduced adsorption kinetics in the flow system, Therefore, the amount of hematite-coated sand, the adsorption affinity of arsenic species and removal kinetics determined the removal efficiency of arsenic in the flow system. arsenic, hematite-coated sand, permeable reactive barrier, anion competition, adsorption.

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Adsorption/desorption of CO2 on Activated Carbon Fibers Using Electric Swing Adsorption (활성탄소섬유상에서 전기변동법을 이용한 CO2의 흡/탈착)

  • Shim, JaeWoon;Moon, SeungHyun
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.432-437
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    • 2005
  • An electric swing adsorption (ESA) process for recovering highly pure $CO_2$ from the mixed gases was tested. In this study, activated carbon fibers were used as an adsorbent. The activated carbon fibers showed fast adsorption rate and the high adsorption capacity for $CO_2$ adsorption under the condition of the ambient pressure. Activated carbon fiber with higher specific surface area was suitable to repeated adsorption-desorption cycle process, showing consistent breakthrough curve. Especially, the regeneration method by vacuum combined with ESA improved the performance of desorption process by an additional 17% regeneration efficiency compared to a vacuum only method, and showed the high regeneration efficiency at comparatively low 7-8 Wh energy.

Validation of Adsorption Efficiency of Activated Carbons through Surface Morphological Characterization Using Scanning Electron Microscopy Technique

  • Malik, Ruchi;Mukherjee, Manisha;Swami, Aditya;Ramteke, Dilip S.;Sarin, Rajkamal
    • Carbon letters
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    • v.5 no.2
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    • pp.75-80
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    • 2004
  • The studies on activated carbon prepared from walnut shell and groundnut shell were undertaken to ascertain the effect of initial state of precursor and activation process on the development of porosity in the resulting activated carbon. Walnut shell based carbon shows the presence of cellular pores while Groundnut shell based carbon shows fibrillar pore structure. The adsorption parameters, characterization of product and scanning electron microscopic studies carried out showed the presence of mainly Micro, Meso and Macro porosity in carbon prepared from Walnut shell while mainly micro porosity was observed in Groundnut shell based activated carbon. An interrelationship between the adsorption efficiency and porosity in terms of quality control parameters, for before and after activation, was validated through the scanning electron microscopic data.

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Identification of two coliphages from Han-river and its adsorption-elution effect on soil materials (한강에서 분리한 이종 coliphage의 동정과 점토질에 대한 흡착 및 용출효과)

  • 홍순우;하영칠;안태석;이영숙
    • Korean Journal of Microbiology
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    • v.20 no.4
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    • pp.210-222
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    • 1982
  • Coliphages isolated from Han-River from September 1980 to August 1981 were classified by morphological and physiological characteristics. Effects of soil metrial on the fate of coliphage in nature were investigated. 1. The correlation coefficient between coliphage and E.coli which was host of coliphages in nature was 0.7173 (p=0.004). 2. Coliphage I isolated from Han-River of which DNA molecular weight was $27{\times}10^6$ daltons was identified as $T_1$ phage and coliphage II of which DNA molecular weight $72{\times}10^6$ daltons was classified as $T_5$ phage. 3. Soil material SW was composed of 63.65% silt and 21.92% clay. Clay was consisted of illite, kaolinite and chlorite evenly. Soil material J was composed of 68.92% silt and 11.67% clay. Clay consisted of smectite only. 4. Coliphage was absorbed to soil material J more than soil material SW, and $T_1$ coliphage was absorbed to soil material more than $T_5$ coliphage was. 5. The phage adsorption efficiency to soil material was enhanced at lower pH : the phage adsorption efficiency at pH 4 was 27 time higher than at pH 7. 6. Divalent $(Ca^{2+})\;and\;trivalention\;(Al^{3+})$ enhanced the phage adsorption efficiency to soil material from 4 to 39 and from 17 to 91 times higher than monovalent $ion(Na^+)$, respectively. 7. The concentration of organic compound was inversely related to the phage adsorption efficiency to soil. 8. Adsorption of phage onto soil material, and elution efficiency of elutants was in the order of D.D.W>tap water>river water>seawater. 9. The higher the concentration of organic compound was, the more were adsorbed phages to soil eluted. 10. Coliphages survived longer in sterile soil suspension than in nonsterile soil material suspension.

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A Study on Optimal Dye-coating Conditions to Reduce Dye-adsorption Time with Improved DSSC Efficiency

  • Seo, Yeong-Ho;Choe, Eun-Chang;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.481.1-481.1
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    • 2014
  • Dye-sensitized solar cell (DSSC) has been extensively investigated as the next generation energy source. Despite attractive features of simple fabrication process and its economical efficiency, there are some problems such as low efficiency and low long-term stability. Many groups have attempted the proposed way to improve the cell efficiency and long-term stability such as low recombination rate between $TiO_2$ surface and electrolyte, the development of new dye molecules capable of light adsorption as broadly as possible, the fabrication of a solid-state DSSC by replacing the liquid electrolyte, and protective coating on glass. In this work, we confirmed new dye-coating conditions to maximize the dye adsorption between the dye and $TiO_2$ nanoparticle surface. The experiment results coating conditions with the coating temperature of $70^{\circ}C$, the dye concentration of 10 mM and the coating time of 3 min. Conditions have two times, three times cycle the experiment in progress efficiency rises.

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Adsorption Characteristics of Heavy Metals by Various Forest Humic Substances

  • Ahn, Sye-Hee;Koo, Bon-Wook;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.6
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    • pp.73-82
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    • 2003
  • Various forest humic substances were collected at different climate regions with different forest types, and adsorption of heavy metals such as Cu(II), Zn(II), Cd(II) and Cr(III) were characteristically conducted to obtain optimal adsorption conditions and to evaluate the removal efficiency of heavy metals by each forest humic substance. The adsorption isotherms for Cu(II), Zn(II), Cd(II) and Cr(III) conformed to Langmuir's equation. In the stirred reactor, the removal efficiencies of Cu(II), Zn(II) and Cd(II) by forest humic substances were more than 90% but that of Cr(III) was less than 60%. The adsorption capacities of heavy metals in the stirred reactor were considerably varied depending on the type of forest humic substances. Among humic substances, the one from deciduous forest at subtropical region showed the highest removal efficiency for Cu(II). There was no significant difference in removal efficiency by each heavy metal depending on reaction temperature ranged from 20 to 50oC except for Cr(III), and the adsorptions of Cu(II), Zn(II) and Cd(II) were occurred rapidly in the incipient stage within 10 min, while Cr(III) needed more reaction time to be adsorbed. The stirred and packed bed column reactors showed similar adsorption characteristics of heavy metals by humic substances, but the removal efficiency was considerably higher in the packed bed column reactor than in the stirred reactor. Therefore, in actual operation process, a continuous packed bed column reactor was more economical.

Enhancement of Efficiency of Activated Carbon Impregnated Chitosan for Carbon Dioxide Adsorption

  • Patkool, Chaiwat;Chawakitchareon, Petchporn;Anuwattana, Rewadee
    • Environmental Engineering Research
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    • v.19 no.3
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    • pp.289-292
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    • 2014
  • The effect of carbon dioxide ($CO_2$) on global warming is serious problem. The adsorption with solid sorbents is one of the most appropriate options. In this study, the most interesting adsorbent is granular activated carbon (GAC). It is suitable material for $CO_2$ adsorption because of its simple availability, many specific surface area, and low-cost material. Afterwards, GAC was impregnated with chitosan solution as impregnated granular activated carbon (CGAC) in order to improve the adsorption capacity of GAC. This research aims to compare the physical and chemical characteristics of GAC and CGAC. The experiment was carried out to evaluate the efficiency of $CO_2$ adsorption between GAC and CGAC. The results indicated that the iodine number of GAC and CGAC was 137.17 and 120.30 mg/g, respectively. The Brunauer-Emmett-Teller results (BET) of both GAC and CGAC show that specific surface area was 301.9 and $531.3m^2/g$, respectively; total pore volume was 0.16 and $0.29cm^3/g$, respectively; and mean diameter of pore was 2.18 and 2.15 nm, respectively. Finally, the $CO_2$ adsorption results of both GAC and CGAC in single column how the maximum adsorption capacity was 0.17 and 0.25 mol/kg, respectively; how degeneration time was 49.6 and 80.0 min, respectively; and how the highest efficiency of $CO_2$ adsorption was 91.92% and 91.19%, respectively.

Development and efficiency of filter device for the emission reduction from the diesel engine in fishing boat (어선용 디젤엔진의 배출가스 저감 필터 개발과 저감 효율)

  • Lee, Kyounghoon;Kim, Sang-Keun;Kim, Seonghun;Yang, Yong-Su;Park, Seong-Wook
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.50 no.1
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    • pp.50-57
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    • 2014
  • The performance of five kind adsorbents, which can reduce nitrogen oxide (NOx) from the diesel engine occupying 85% of the fishing boat, was carried out and the emission reduction filter was manufactured and evaluated in the adsorption efficiency of the emission gas for 240 KW diesel portable generator. As a NOx emission filter made of mordenite which has an excellent cation exchange capacity was manufactured by ball type adsorbents having excellent specific surface area. The adsorption efficiency of mordenite material applying the emission reduction filter began to show up at the operating time 10 minutes in comparison with the activated carbon and zeolite materials, and it was exposed to continue until 100% capability with passing by 20 minutes. So the adsorption efficiency of the NOx reduction filter consistently maintained at the averaged 80%.

Effect of Particle Size of Sediment on Adsorption of Fluoride (하천 퇴적물의 입자크기에 따른 불소의 흡착 특성)

  • Kim, Chae-Lim;Oh, Jong-Min
    • Korean Journal of Ecology and Environment
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    • v.49 no.4
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    • pp.289-295
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    • 2016
  • The purpose of this study is to find out the effect of particle size of sediment on adsorption of fluoride. Particle size is classified as sand, silt and clay. Adsorption equilibrium time, adsorption isotherms and the effect of pH were investigated through batch tests. The $pH_{pzc}$ of sand, silt, clay was respectively 6, 8, 4.5 and AEC (anion exchange capacity) was highest in silt, respectively 0.0095, 0.0224, $0.014meq\;g^{-1}$. Adsorption of fluoride on the sediment was in equilibrium within 300 minutes from all particle size. The experimental data of isotherms at various pH were well explained by Freundlich equation. As the experimental results of the effect of pH, the adsorption efficiency of sand and silt were reduced after the $pH_{pzc}$. However, the adsorption efficiency of clay was maintained after the $pH_{pzc}$, and decreased rapidly higher than pH 12.