• Title/Summary/Keyword: Adsorption and Removal

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Evaluation of Rhizofiltration for Uranium Removal with Calculation of the Removal Capacity of Raphanus sativus L. (무순(Raphanus sativus L.)의 제거능 계산에 의한 뿌리여과법의 우라늄 제거 가능성 평가)

  • Han, Yikyeong;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.20 no.7
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    • pp.43-52
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    • 2015
  • The uranium removal capacity of radish sprouts (Raphanus sativus L.) in groundwater was calculated on the basis of the amount of uranium accumulated in the radish sprouts rather than the concentration in solution, of which process was very limited in previous studies. Continuous rhizofiltration clean-up system was designed to investigate the feasibility of radish sprouts, applying for uranium contaminated groundwater (U concentration: 110 μg/L) taken at Bugogdong, Busan. Six acrylic boxes (10 cm × 30 cm × 10 cm) were connected in a direct series for the continuous rhizofiltration system and 200 g of radish sprouts cultivars was placed in each box. The groundwater was flushed through the system for 48 hours at the constant rate of 5 mL/min. The rhizofiltration system was operated in the phytotron, of which conditions were at 25℃ temperature, 70% of relative humidity, 4,000 Lux illumination (16 hours/day) and 600 mg/L of CO2 concentration. While 14.4 L of contaminated groundwater was treated, the uranium removal efficiency of the radish sprouts (1,200 g in wet weight) was 77.2% and their removal capacities ranged at 152.1 μg/g-239.7 μg/g (the average: 210.8 μg/g), suggesting that the radish sprouts belong to the group of hyper-accumulation species. After the experiment, the sum of U amounts accumulated in radish sprouts and remained in groundwater was 1,472.2 μg and the uranium recovery ratio of this rhizofiltration experiment was 92.9%. From the results, it was investigated that the radish sprouts can remove large amounts of uranium from contaminated groundwater in a short time (few days) because the fast growth rate and the high U accumulation adsorption capacity.

필터시스템을 이용한 비소처리흡착제의 성능비교분석

  • Bang Seon-Taek;Kim Ju-Yong;Kim Gyeong-Ung
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.13-16
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    • 2005
  • Laboratory and field experiments were conducted to study the effectiveness of five adsorbents for the removal of arsenic. The adsorbents included activated alumina (AA), iron coated AA (ICAA), and granular ferric hydroxide (GFH), granular ferric oxide (GFO), and granular titanium dioxide (GTD). Laboratory experiments were conducted to investigate arsenic removal using challenge water prepared in accordance with NSF International Standards 53 (ANSl/NSF 53-2001). Field experiments were conducted using arsenic-contaminated groundwater In laboratory experiment, the treatment capacity decreased in the following order GTD > GFO > GFH. In contrast, the treatment capacity decreased in the following order GFO > GTD > GFH > ICAA > Ah in field experiments.

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Study on development of Smart ventilation system using a adsorbent for the removal of CO2 (CO2 제거용 흡착제를 이용한 스마트 환기시스템 개발 연구)

  • Shin, Jae-Ran;Moon, Sung-Ho;Kim, Jae-Kang;Choi, Jin-Sik;Lim, Yun-Hui;Park, Byung-Hyun;Lee, Ju-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.578-582
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    • 2015
  • In this study, We evaluated the efficiency of the smart ventilation system being developed at the test-bed(KCL). Smart ventilation system improve the indoor air quality by absorbing carbon dioxide. It is reducing the infusion of outside air can be reduced to minimum energy consumption. To evaluate the energy savings and carbon dioxide removal efficiency. It was more effective when working with air conditioning and ventilation system at the same time.

Desorption Characteristics of $H^{14}CO_3$ ion from Spent Ion Exchanged Resin by Solution Stripping Technology

  • Park Geun-IL;Kim In-Tae;Kim Kwang-Wook;Lee Jung-Won;Won Jang-Sik;Yang Ho-Yeon
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.214-221
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    • 2005
  • Spent ion-exchanged resin generated from various purification systems in CANDU reactor is causing concern due to a limited storage capacity and safe disposal. As a suggestion for a proper treatment technology for the spent ion-exchanged resin containing a high activity of C­14 radionuclide which would be classified as Class A and C wastes, a fundamental study for the development of C-14 removal technology from a spent resin was performed. The adsorption characteristics of the inactive $HCO_3^-$ ion and other ions in a stripping solution on IRN-150 mixed resin was evaluated and the removal technology of the $HCO_3^-$ ion adsorbed on IRN-150 by an alkaline stripping method was proposed.

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PAC Pretreatment for Ultrafiltration of RBC Effluent (PAC-한외여과막을 이용한 회전원판 처리수의 고도처리)

  • Ahn, Kyu-Hong;Song, Kyung-Guen;Park, Joon-Hong;Kweon, Ji-Hyang;Kim, Hyung-Soo;Kwak, Jong-Woon
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.2
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    • pp.70-79
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    • 1996
  • Ultrafiltration(UF) and powdered activated carbon(PAC) adsorption were combined to treat wastewater contaminated with refractory organic compounds. Secondary sewage effluent of RBC process was used for the investigation. It was determined from batch test results that a contact time of 2 hours and a PAC dose of 450mg/l would be used in the experiments. Backwashing was accomplished by forcing the permeates back ward with pressure of $2.5kgf/m^2$ for 90 seconds. It was shown that refractory organics removal by the PAC-UF process was more efficient than UF process without PAC pretreatments. As backwashing frequency was decreased from four times to one time in an hour, the removal efficiency was significantly increased. The addition of PAC to the UF process mitigated the fluctuation of filtrate quality which was increased in UF process without PAC treatment as transmembrane pressure was increased.

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Discrimination of rival isotherm equations for aqueous contaminant removal systems

  • Chu, Khim Hoong
    • Advances in environmental research
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    • v.3 no.2
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    • pp.131-149
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    • 2014
  • Two different model selection indices, the Akaike information criterion (AIC) and the coefficient of determination ($R^2$), are used to discriminate competing isotherm equations for aqueous pollutant removal systems. The former takes into account model accuracy and complexity while the latter considers model accuracy only. The five types of isotherm shape in the Brunauer-Deming-Deming-Teller (BDDT) classification are considered. Sorption equilibrium data taken from the literature were correlated using isotherm equations with fitting parameters ranging from two to five. For the isotherm shapes of types I (favorable) and III (unfavorable), the AIC favors two-parameter equations which can easily track these simple isotherm shapes with high accuracy. The $R^2$ indicator by contrast recommends isotherm equations with more than two parameters which can provide marginally better fits than two-parameter equations. To correlate the more intricate shapes of types II (multilayer), IV (two-plateau) and V (S-shaped) isotherms, both indices favor isotherm equations with more than two parameters.

Removal of CO2 from Syngas(CO2 and H2) Using Nanoporous Na2CO3/Al2O3 Adsorbents (나노기공성 Na2CO3/Al2O3 흡착제를 이용한 합성가스(CO2, H2) 내 CO2 제거)

  • Bae, Jong-Soo;Park, Joo-Won;Kim, Jae-Ho;Lee, Jae-Goo;Kim, Younghun;Han, Choon
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.646-650
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    • 2009
  • Hydrocarbon gases generated from the gasification of waste could be converted into $CO_2$ and $H_2$ using reforming catalysts and then $CO_2$ was selectively adsorbed and removed to obtain pure hydrogen. To optimize adsorption efficiency for $CO_2$ removal, $Na_2CO_3$ was supported on nanoporous alumina and the efficiency was compared with commercial alumina(Degussa). Nanoporous adsorbents formed more uniform pores and larger surface area compared to adsorbents using commercial alumina. The increase of $Na_2CO_3$ loading improved adsorption of $CO_2$. Finally, the highest adsorption capacity per unit mass of $Na_2CO_3$ could be achieved when the loading of $Na_2CO_3$ reached up to 20wt%. When the content of $Na_2CO_3$ increased above 20 wt%, it aggregated on the surface, and the pore volume was decreased. Used adsorbents could be recycled by the thermal treatment.

Treatment of Wastewater Containing Ethanolamine from Coolant of the Secondary System of Nuclear Power Plant by UV/GAC Adsorption Oxidation Method (UV/GAC 흡착산화 공법을 이용한 원자력 발전소 2차 계통 냉각수로부터 발생하는 에탄올 아민 함유 폐수처리)

  • Choi, Min Jun;Kim, Hansoo
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.318-325
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    • 2017
  • Wastewater including ethanolamine used in the second generation of nuclear power plants is filtered out in the ion exchange resin of the condensate polishing plant. In the regeneration process of ion exchange resin, a strong acidic wastewater containing ethanolamine and a lager amount of ionic substances are released. In this study, the process involving UV oxidation part with or without absorbents was developed for treating wastewater released from the ionic exchange resin. The effect of adsorbents on the wastewater treatment was investigated by using UV oxidation system developed by us. As a result, the COD removal efficiency of UV/GAC process with the granular activated carbon (GAC) as an adsorbent was 71.3% at pH 12.8. The removal efficiency was 21.8% higher than that of the wastewater treated using UV oxidation process without any adsorbents at the same condition. The removal of T-N was 88.6% at pH 12.8 when using UV oxidation with the GAC absorbent, which was 18.0% higher than that of using the UV oxidation process without any absorbents. It is thought that ethanolamine adsorbed on the absorbent improved the efficiency of UV oxidation process. Therefore, the UV/GAC adsorption oxidation process can be more effective in treating wastewater containing ethanolamine than that of using the process without any absorbents.

Ozonation of Humic Acid with Heterogeneous Catalysts (불균일 촉매를 이용한 부식산의 오존 처리)

  • Rhee, Dong Seok
    • Journal of Industrial Technology
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    • v.29 no.A
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    • pp.89-94
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    • 2009
  • The efficiency of heterogeneous catalysts has been investigated in ozonation process for organic removal. Heterogeneous catalytic ozonation was conducted for the degradation of humic acid in the presence of Granular Activated Carbon or Zeolite as a solid catalyst. And the results were compared to those of ozonation alone and adsorption alone without ozonation. The degradation characteristics of humic acid in each process were examined with the values of pH, TOC, $UV_{254}$ and $COD_{Cr}$.

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