• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 추계 총회 및 학술발표회
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• pp.199-203
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• 2004

Fibrous arsenic (As) adsorbent was synthesized by loading zirconium (Zr) on fibrous phosphoric adsorbent that was directly synthesized by radiation-induced graft polymerization of 2-hydroxyethyl methacrylate phosphoric acid on polyethylene-coated polypropylene nonwoven fabric. Zirconium reacted with phosphoric acid grafted in the polyethylene layer. Zirconium density of the resulting adsorbent was 4.1 mmol/g. The breakthrough curve of As(V) adsorption was independent of the flow rate up to $1300\;h^{-1}$ in space velocity. The total capacity of As(V) was 2.0 mmol/g-adsorbent at pH of 2. The adsorbed Zr(IV) could be evaluated by 0.4 M sodium hydroxide solution because negligible Zr(IV) could be found in the eluted solution.

• Journal of Microbiology and Biotechnology
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• 제9권3호
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• pp.292-296
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• 1999

The high density mixed mode adsorbent known by the trade name of Mimo-AD was used to purify lysozyme directly from the hen egg white (HEW). The homogenized hen egg white was treated with the adsorbent in a stirred vessel for lysozyme adsorption, and then the adsorbent, easily separated from the HEW by sedimentation, was packed into a column. The remaining HEW and contaminant proteins were removed by washing with pH 11 distilled water in an expanded-bed state, and subsequently the elution was performed with pH 12 distilled water in a packed-bed state. By this simple and rapid adsorption, washing, and elution procedure, lysozyme was purified to＞95％ with an overall recovery yield of 66％. This process offers a great potential for industrial application by allowing the extraction of lysozyme while retaining the commercial value of HEW.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.296-299
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• 2001

Data on the oil spill recovery from the water surface by light floating electromagnetic plants using a new magnetic adsorbent are given. The feasibility scope for further oil recovery from such gathered mixtures(oil+adsorbent), reuse of this magnetic adsorbent and its properly reclaiming and recycling were shown. The basic conception of the oil spill recovery and efficiency of this method were set forth.

• 한국물환경학회지
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• 제23권2호
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• pp.216-221
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• 2007

The adsorption characteristics of malachite green on waste garnet have been investigated for its treatment from aqueous solution by employing waste garnet which is generated from the abrasive production process as an adsorbent. The influential factors examined were the initial concentration of malachite green in solution, reaction temperature, and the amount of adsorbent. Also, the effect of the modification of the surface of adsorbent on adsorption was examined. As the initial malachite green was increased with reaction temperature and the color removal of malachite green-containing solution was promoted with the amount of adsorbent. Finaly, increased adsorption of malachite green could be attained when the surface of glass was modified by hexamethyldisilazane.

• 한국폐기물자원순환학회지
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• 제34권5호
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• pp.468-473
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• 2017

This study was carried out to examine the characteristics of hydrogen sulfide adsorption using an iron hydroxide-based adsorbent. The prepared adsorbent was discussed with regard to its adsorption capacity and analyzed via surface analysis methods to illustrate the physical characteristics of hydrogen sulfide adsorption. As the drying temperature increased, the adsorption capacity of the adsorbent decreased from 29.15wt% to 22.73wt%. The adsorption capacity was decreased as the space velocity increased and showed an adsorption capacity of about 3.65 at $3,157.6h^{-1}$. The effect of sulfur dioxide was to decrease the adsorption capacity from 29.15wt% to 27.94wt%. The adsorbent exhibited the amorphous type in its physical appearance based on XRD and EDS analysis.

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.406-414
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• 2010

A novel polyacrylamide grafted hydrous ferric oxide adsorbent composite has been synthesized by using glow discharge electrolysis plasma. To optimize the synthesis conditions, the following parameters were examined in detail: applied power, discharge time, post polymerization temperature, post polymerization time, amount of crosslinking agent and hydrous ferric oxide gel added and so on. The adsorbent was characterized by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). The removal percentage of the adsorbent in Pb(II) solution was examined and the data obtained showed that the adsorbent composite has a high capacity for lead ion. For the use in wastewater treatment, the thermodynamic and kinetic of Pb(II)-capture were also studied. Results indicated that the adsorption reaction was a spontaneous and an endothermic process, and it seems to be obeyed a pseudo-secondorder rate model. Moreover, the adsorption isotherm of Pb(II)-capture is following the Langmuir and Freundlich isotherm models.

• Biotechnology and Bioprocess Engineering:BBE
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• 제11권3호
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• pp.268-272
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• 2006

A dense, pellicular UpFront adsorbent ($p=1.5 g/cm^3$, UpFront Chromatography, Cophenhagen, Denmark) was characterized in terms of hydrodynamic properties and protein adsorption performance in expanded bed chromatography. Cibacron Blue 3GA was immobilised into the adsorbent and protein adsorption of bovine serum albumin (BSA) was selected to test the setup. The Bodenstein number and axial dispersion coefficient estimated for this dense pellicular adsorbent was 54 and $1.63{\times}10^{-5}m^2/s$, respectively, indicating a stable expanded bed. It could be shown that the BSA protein was captured by the adsorbent in the presence of 30% (w/v) of whole-yeast cells with an estimated dynamic binding capacity $(C/C_o = 0.01)$ of approximately 6.5 mg/mL adsorbent.

• Nuclear Engineering and Technology
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• 제47권5호
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• pp.579-587
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• 2015

To support the use of nuclear power as a sustainable electric energy generating technology, long-term supply of uranium is very important. The objective of this research is to investigate the use of new adsorbent material for cost effective uranium extraction from seawater. An activated carbon-based adsorbent material is developed and tested through an electrosorption technique in this research. Adsorption of uranium from seawater by activated carbon electrodes was investigated through electrosorption experiments up to 300 minutes by changing positive potentials from +0.2V to +0.8V (vs. Ag/AgCl). Uranium adsorption by the activated carbon electrode developed in this research reached up to 3.4 g-U/kg-adsorbent material, which is comparable with the performance of amidoxime-based adsorbent materials. Electrosorption of uranium ions from seawater was found to be most favorable at +0.4V (vs. Ag/AgCl). The cost of chemicals and materials in the present research was compared with that of the amidoxime-based approach as part of the engineering feasibility examination.

• 신재생에너지
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• 제5권4호
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• pp.46-51
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• 2009

The purpose of this study is to investigate selective adsorption of $CO_2$ from LFG (Landfill gas) by using commercialized NaX-type zeolite adsorbent under the ambient temperature and pressure. The experiment of $CO_2$ adsorption was carried out by using simulated LFG. The $CO_2$ adsorption capacity and separation efficiency of NaX-type adsorbent were investigated by analyzing gas flow rate and gas composition at inlet and outlet of the adsorption reactor. The adsorbed $CO_2$ were desorbed under decompression condition which 0.5 Torr or by air purge. Through the result to use simulated LFG, when the method of VSA was used, 73.2~75.3 mg of $CO_2$ was adsorbed per 1 g commercial adsorbent, when the method of air purge was used, 78.4~83.2 mg of $CO_2$ was adsorbed per 1 g of commercial adsorbent.

• Bulletin of the Korean Chemical Society
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• 제21권7호
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• pp.715-719
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• 2000

A ceramic powder of destructive adsorbent was synthesized by impregnating copper and manganese on the surface of silica aerosil@. In-site FTIR measurements on pulses of malodorant tert-butylmercaptan injected over the powder showed that rert-butylmercaptan dimerized into di-tert-hutyldisulfide on the surface of the adsorbent in an ambient condition. GC/MS measurement on the gas over the adsorbent showed no tert-butylmercaptan remaining, and showed only the dimerization product of di-tert-butyldisulfide. Most of the dimerization product, di-tert-butyldisulfide,remained on the surface of the adsorbent as physisorbed condense, and apparently Iowered the destruction efficiency by blocking the surface from the access by tert-butylmercaptan. Upon being heated above $100^{\circ}C$ it was observed that the physisorbed di-tert-butyldisulfide dissociated back into tert-butylmercaptan. tert-butylmercaptan physisorbed on the activated carbon, thereby no dimerization was occurring on the surface of the activated carbon. In an argn environment, the dimerization reaction was practically not occurring even on the surface of the adsorbent, indicating the free oxygen in air was also participating in the dimerization reaction. Water was identified as a by-product of the dimerization reaction. Possible reactions on the surface of the adsorbent were proposed.