• Title/Summary/Keyword: Adsorbed

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Mg으로 개질한 Zeolite를 이용하여 염색공장 폐수처리 평가 (Performance Evaluation of Modified Zeolite with Mg for the Treatment of Dyeing Wastewater)

  • 최희정
    • 한국물환경학회지
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    • 제31권4호
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    • pp.392-398
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    • 2015
  • The aim of this study was to investigate the bio-adsorption using modified zeolite with Mg (Mg-zeolite) in the dyeing wastewater treatment. Mg-zeolite adsorbed successfully 100% of the color, suspended solid (SS). chemical oxygen demand (COD), biological oxygen demand (BOD), total nitrogen (TN) and total phosphorus (TP) in the dyeing wastewater at the following optimal Mg-zeolite loading: 20 mg/L for colour, SS, TN and TP, 30 mg/L for BOD and COD. These results indicated that the amount of 1 mg/L Mg-zeolite adsorbed 11.6 mg/L for color, 9.5 mg/L for SS, 45.0 mg/L for COD, 12.7 mg/L for BOD, 0.91 mg/L for TP and 2.25 mg/L for TN. The bio-adsorbent, Mg-zeolite, can be a promising adsorption due to its high efficiency and low dose requirements.

Desorption and Regeneration Characteristics for Previously Adsorbed Indium Ions to Phosphorylated Sawdust

  • Kwon, Taik-Nam;Jeon, Choong
    • Environmental Engineering Research
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    • 제17권2호
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    • pp.65-67
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    • 2012
  • The desorption characteristics of previously adsorbed indium ions on phosphorylated sawdust were tested by various chemical reagents such as HCl, $HNO_3$, NaCl, ethylenediaminetetraacetic acid, and nitrilotriacetic acid. Among them, HCl was chosen as the best desorbing agent in terms of economics. The desorption efficiency of HCl for indium ions was about 97% at a concentration of 0.5 M. The desorption efficiency for indium ions was very high at about 94% even at a solid/liquid ratio of 10.0, and the desorption process was quickly performed within 60 min. The removal efficiency of indium ions in recycled phosphorylated sawdust could be maintained at 85% in the 4th cycle.

PDP용 격벽재의 승온 탈가스 특성 (Characteristics of Outgas from Heated Barrier Rib for POP)

  • 김선호;주정훈;이석영;이강욱;오상진
    • 한국표면공학회지
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    • 제37권3호
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    • pp.185-190
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    • 2004
  • Plasma Display Panel is a display device emitting fluorescent light from gas discharge between a front and a rear panel sealed together. Front and rear panel have multitude of film layers and barrier ribs in the rear panel has the largest area so releasing various gases and affecting light emitting characteristics and lifetime. The remaining gases in a barrier rib were studied by thermal desorption analysis up to $400^{\circ}C$ and main gases were $H_2$ $H_2$O, CO. During sustaining at $300^{\circ}C$, the outgassing rates from other gases were decreased but$ H_2$ kept constantly increasing until 1 hour, which can be originated from the dissociation of organics remained in the inside of barrier rib material. In $H_2$O, two distinct peaks were observed: desorption from physically adsorbed one at $l00^{\circ}C$ and from chemically adsorbed one $400^{\circ}C$. The result can be utilized in interpretation of electronic and optical characteristics and evacuation process control of PDP

Electrical Instabilities of Mesoporous Silica Thin Films

  • ;정현담
    • 통합자연과학논문집
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    • 제3권4호
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    • pp.219-225
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    • 2010
  • On the surface of mesoporous silica thin films (MSTF) which were fabricated by sol-gel approach there are existences of water and three different silanol types including chained, germinal and isolated silanol. Their amounts changes as a function of aging time of used sol solution, as confirmed by FT-IR. The adsorbed water generates ionic carriers such as H+ and OH- and passivates the Si dangling bonds at the interface of silicon wafer-MSTF. The ionic carriers can not only transport across the thickness of thin film to enhance the leakage current but also diffuse toward the silicon wafer-MSTF interface to depassivate Si dangling bonds. On the other hand, chained silanols or germinal silanols promote the moisture adsorption of MSTF and tend to form strongly hydrogen bonded systems with adsorbed water molecules resulting in very high dielectric constant. Isolated silanol, on the contrary, affects less on electrical properties of thin film.

Study on Charge Transfer Characteristics of Self-Assembled Viologen Monolayers

  • Park Sang-Hyun;Lee Dong-Yun;Kwon Young-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • 제5C권4호
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    • pp.161-164
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    • 2005
  • Viologen has been extensively investigated in the paper because their well-behaved electrochemistry has led to their use in a variety of theses, including the electron acceptor for the electric charge delivery mediation of the devices. It was formed monolayer in QCM by self-assembly method. We could know the adsorbed mass of viologen molecules from the frequency shift. We calculated that the adsorbed mass was about 196 [$ng/cm^2$]. We studied the electron transfer property of viologen by the cyclic voltammetry among the electrochemical process so we changed an anion like 0.1 M $NaClO_4$ and $Na_3PO_4$ electrolyte solution and investigated the interrelationship between scan rate and peak current when scan rates were increased twice.

Adsorption of molecular oxygen and $SO_2$ on Ni(100)

  • Hyunsukl Jeong;Changmin;Kim, Eunha;Hojun Jeong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.180-180
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    • 1999
  • The interaction of oxygen with a Ni(100) surface has been investigated using X-ray Photoelectron Spectroscopy (XPS) and Near-Edge X-ray Absorption Fine Structure (NEXAFS) technique. Below 200L oxygen exposure, molecular oxygen was dissociated to atomic oxygen. Increasing oxygen exposure, -1s binding energy shifted from 531.0 eV to 533.0 eV due to molecular adsorption. The presence of molecular oxygen species was confirmed by NEXAFS. Molecular oxygen adsorbed on Ni(100) was oriented perpendicular to the surface. Upon heating over 150K molecular adsorbed oxygen surface was also analyzed using NEEXFS.

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SPME로 포집한 김치 휘발성분의 GC-AED및 GC-MSD에 의한 동정 (Analysis of Volatile Organic Compounds in Kinnchi Absorbed in SPME by GC-AED and GC-MSD)

  • 하재호
    • 한국식품영양과학회지
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    • 제31권3호
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    • pp.543-545
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    • 2002
  • Solid phase microextraction(SPME)을 사용하여 김치 중의 향기성분이 매우 용이하게 포집할 수 있었으며 dimethyl-sulfide등 25종의 휘발성성분이 분석되었다. 질량분석기로 동정된 몇몇 성분을 AED로 확신하였을 때 황과 질소를 함유하는 성분임을 명확히 알 수 있어 GC-AED를 사용하면 그 물질의 구성원소를 쉽게 분석할 수 있다.

제일원리 LCAO 방법을 이용한 DNA Nucleobase 흡착된 그라핀의 원자 및 전자구조 연구 (A Study on the Atomic and Electronic Structures of DNA-nucleobases-adsorbed Graphene Through First-principles LCAO Method)

  • 이은철
    • 한국전기전자재료학회논문지
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    • 제24권6호
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    • pp.510-514
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    • 2011
  • Based on first-principles LCAO method, we study the electronic and atomic structures of DNA nucleobases adenine (A), thymine (T), guanine (G), and cytosine (C) adsorbed on graphene surfaces. The ${\pi}-{\pi}$ stacking interactions between graphene and nucleobases lead to the bilayer geometries similar to the Bernal stacked graphite. Through the density of states and charge density analyses, it is found that nucleobases are physisorbed on graphene by dispersive interactions with negligible charge exchange. Our calculations reproduce the atomic structures obtained in previous plane wave calculations accurately with much less computation, and well describe the delocalized ${\pi}-{\pi}$ interactions in graphene-nucleobases system, indicating that the LCAO method is very efficient for investigating graphene-bio systems.

Ionic-to-Metallic Layer Transition in Cs Adsorption on Si(111)-(7$\times$7). Charge-State Selective Detection of Adsorbate by Cs+ Reactive Ion Scattering.

  • 한승진;박성찬;강헌
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.155-155
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    • 2000
  • Adsorption of alkali metals on a silicon surface has attracted much attention due to its importance in metal-semiconductor interface technology, In particular, the bonding nature of alkali metal to silicon substrate has been a focus of fundamental research efforts. We examined the adsorbed layer of Cs on a Si(111)-(7$\times$) surface by reactive ion scattering (RIS) of hyperthermal Cs+ beams. RIS from a Cs-adsorbed surface gives rise to Cs, representing pickup of surface Cs by Cs projectile. The Cs intensity is proportional to surface coverage of Cs at a high substrate temperature (473 K), while it varies anomalously with Cs coverage at low temperatures (130-170 K). This observation indicates that RIS selectively detects metallic Cs on surface, but discriminates ionic Cs. Transition from ionic to metallic Cs adlayer is driven by thermal diffusion of Cs and their clustering process.

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N-type doping and band gap change of Calix adsorbed on Graphene

  • 박선민;양세나;김기정;김봉수;노광현;이한길
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.341-341
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    • 2010
  • Electronic structure of Calix adsorbed on epitaxial graphene (EG) was investigated using high resolution photoemission spectroscopy (HRPES). Increasing the deposition of calix molecule, we found that EG becomes n-type doping using secondary edge measurement (work function change). As we observe bonding nature of O 1s peak, we found that single O 1s peak can be clearly distinguished in the spectra indicating equivalent adsorption state. Finally, we were able to control the band gap of EG using valence band spectra as we change the amount of calix molecule. In this study, we will propose the possibility of band gap modulation of EG using calix molecule.

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