• Transactions of the Korean hydrogen and new energy society
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• v.34 no.3
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• pp.316-326
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• 2023

Development of carbon-neutral fuel production technologies to solve climate change issues is progressing worldwide. Among them, methane can be produced through the synthesis of hydrogen produced by renewable energy and carbon dioxide captured through a CO₂ methanation reaction, and the fuel produced in this way is called synthetic methane or e-methane. The CO₂ methanation reaction can be conducted via biological or thermochemical methods. In this study, a 30 Nm³/h thermochemical CO₂ methanation process consisting of an isothermal reactor and an adiabatic reactor was used. The CO₂ conversion rate and methane concentration according to the temperature measurement results at the center and outside of the adiabatic reactor were analyzed. The gas flow into the adiabatic reactor was found to reach equilibrium after about 1.10 seconds or more by evaluating the residence time. Furthermore, experimental and analysis results were compared to evaluate performance of the reactor.

• Journal of Korean Tunnelling and Underground Space Association
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• v.11 no.1
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• pp.37-45
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• 2009

In this study, experiments of development and application of 50 MPa high-performance concrete are performed for large dimensional tunnel linings. In order to produce 50MPa high-performance concrete, eight optimal mixtures replacing with fly ash and ground granulated blast furnace slag up to 50 percent of type I Portland cement were selected then tests for mechanical properties and simple adiabatic temperature rise tests were carried out. And in order to assess the quantitative characteristics of heat of hydrations of developed mixtures, three mixtures that the type I Portland cement (OPC) and each one mixture of binary and ternary mixtures (BS30, F15S35) were reselected, then the adiabatic temperature rise tests and mock-up tests were performed. Consequently, the comparisons between the results of mock-up tests and finite element analysis can be enhanced the reliability of analyzing routines of thermal behaviours of the developed high-performance concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.489-492
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• 2008

Adiabatic temperature rise and autogenous shrinkage experiments were performed for three silica-fume included mass concrete mixtures and a reference mixture without silica-fume, in order to investigate the influence of silica-fume on the hydration heat and autogenous shrinkage properties of mass concrete, and to examine applicability of silica-fume to mass concrete. It was revealed from the experiment that, for mass concrete, the rate of hydration was hardly increased while the maximum adiabatic temperature rise decreased about 5$^{\circ}$C by the addition of silica-fume, and the amount of autogenous shrinkage was almost the same regardless of silica-fume replacement. These facts imply that silica-fume can enhance the resistance of mass concrete to temperature cracking as well as the durability.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.4
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• pp.399-405
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• 1994

Beacuse of the energy resources exhaustion, the aggravating environmental air pollution and the smoke phenomena etc., the importance of clean gas fuel compared with liquid fuel is highly considered in recent years. The combustion system which consists of porous media is actively studied as a new method for solving above problems. Therefore, excess enthalpy combustion using porous media was interested by many researchers and investigated through numerical and experimental analysis. In this study, the simplified combustor has the unique combustion characteristics of mixture gas preheated effect using radiative and convective heat energy by changing the flow passage of unburned gas with solenoid valves and has the intensive excess enthalpy phenomena As the result of according to reduce equivalence ratio, flame temperature was remarkably higher than adiabatic flame temperature. This show the ability of super-lean combustion.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.05a
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• pp.61-65
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• 2008

This study, having combined and displaced blast furnace slag("BS" hereinafter) known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for W/B 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing BS with admixture material at level 5 of 0%, 20%, 40%, 60% and 80% for cement(OPC+CC), experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more BS displacement rate increased, the more it decreased. Also, as for simple adiabatic temperature rise by the CC and BS displacement rates, it decreased as displacement rate increased, and particularly in the case of displaced BS of 80%, It showed temperature reduction effect of about 63% companing with plain. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

• Nuclear Engineering and Technology
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• v.53 no.6
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• pp.1931-1938
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• 2021

Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF₄ is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO₂F₂ concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF₄ having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF₄. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF₂ phase diagram.

• Nuclear Engineering and Technology
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• v.52 no.12
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• pp.2836-2846
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• 2020

During severe nuclear power plant (NPP) accidents, a H₂/CO mixture can be generated in the reactor pressure vessel by core degradation and in the containment as well by molten corium-concrete interaction. In spite of its importance, a state-of-the-art methodology predicting H₂/CO combustion risk relies predominantly on empirical correlations. It is therefore necessary to develop a proper methodology for flammability evaluation of H₂/CO mixtures at ex-vessel phases characterized by three factors: CO concentration, high temperature, and diluents. The developed methodology adopted Le Chatelier's law and a calculated non-adiabatic flame temperature model. The methodology allows the consideration of the individual effect of the heat transfer characteristics of hydrogen and carbon monoxide on low flammability limit prediction. The accuracy of the developed model was verified using experimental data relevant to ex-vessel phase conditions. With the developed model, the prediction accuracy was improved substantially such that the maximum relative prediction error was approximately 25% while the existing methodology showed a 76% error. The developed methodology is expected to be applicable for flammability evaluation in chemical as well as NPP industries.

• Progress in Superconductivity and Cryogenics
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• v.14 no.3
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• pp.53-59
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• 2012

Adiabatic demagnetization refrigerator (ADR) for hydrogen re-liquefaction operating between 24 K and 20 K has been designed. $Dy_{0.9}Gd_{0.1}Ni_2$, whose Curie temperature is 24 K, is selected as a magnetic refrigerant. The magnetic refrigerant powder is sintered with oxygen-free high purity copper (OFHC) powder to enhance its effective thermal conductivity as well as to achieve relatively high frequency. A perforated plate heat exchanger (PPHE) operated with forced convection is utilized as a heat switch. The forced convection heat switch is expected to have fast response relative to a conventional gas-gap heat switch. A conduction-cooled high Tc superconducting (HTS) magnet is employed to apply external magnetic field variation on a magnetic refrigerant. $2^{nd}$ generation GdBCO coated conductor HTS tape with Kapton$^{(R)}$ insulation (SUNAM Inc.) will be utilized for the HTS magnet. The magnetization and demagnetization processes are to be achieved by the AC operation of the HTS magnet. The designed magnetic field and target ramp rate of the HTS magnet are over 4 T with 180 A and 0.4 T/s, respectively. AC loss distribution on HTS magnet is theoretically estimated.

• Journal of the Korean Society of Safety
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• v.13 no.2
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• pp.76-87
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• 1998

This study was carried out to investigate the effect of on temperature control from actuating method, recycling ratio and the position (top, middle and bottom) of set and controlled temperature within the reactor in adiabatic ebullated recycling condition, when the disturbance was occurred. Estimation of the solution were performed numerically using the finite difference method. It was assumed that the reaction is in constant with heat of reaction and the physical properties(density, heat capacity and viscosity, etc) of the reactants are same condition within the reactor.

• Journal of the Korean Association of Geographic Information Studies
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• v.16 no.4
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• pp.29-38
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• 2013

This study is to construe the spatio-temporal characteristics of temperature in cities and the changes of climatical regions by analyzing a climate change in Korea peninsular. We used daily mean air temperature data which were collected in South and North climate stations for the past 34 years from 1974 to 2007. We created temperature maps of 500m resolution with Inverse Distance Weight in application with adiabatic lapse rate per month in linear relation with height and temperature. In the urbanization area, the data analyzed population in comparison with temperature changes by the year. The south climate region in Korea by the Warmth index was expanded to the middle climate region by the latitude after 1990s. A rise of mean temperature was $0.5{\sim}1.2^{\circ}C$ in urban areas such as Seoul, metropolitan and cities which had a rapid urbanization and industrialization with the population increase between 1980s and 1990s. In case of North Korea, cities such as Pyeongyang, Anju, Gaecheon, and Hesan had the same pattern.