• Title/Summary/Keyword: Adhesive strength

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Cracking Behavior Under Contact Stress in Densely Coated Porous Engineering Ceramics (치밀층으로 코팅된 다공성 엔지니어링 세라믹스에서의 접촉응력에 의한 균열 거동)

  • Kim, Sang-Kyum;Kim, Tae-Woo;Kim, Do-Kyung;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.554-560
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    • 2005
  • The engineering ceramic needs the properties of high strength, hardness, corrosion-resistance and heat-resistance in order to withstand thermal shock or applied nonuniform stresses without failure. The densely coated porous ceramics can be used for machine component, electromagnetic component, bio-system component and energy-system component by their high-performances from superior coating properties and light-weight characteristics due to the structure including pore by itself. In this study we controlled the porosity of silica and alumina, $8.2\~25.4\%$ and $23.4\~36.0\%$, respectively, by the control of sintering temperature and starting powder size. We made bilayer structures, consisting of a transparent glass coating layer bonded to a thick substrate of different porous ceramics by a thin layer of epoxy adhesive, facilitated observations of crack initiation and propagation. The elastic modulus mismatch could be controlled using different porous ceramics as the substrate layer. Then we applied 150 N force using WC sphere with a radius of 3.18 mm by Hertzian indentation. As a result, the crack initiation in the coating layer was delayed at lower porosity in the substrate layer, and the damage in the coating layer was relatively smaller at the bilayer structure coated on higher elastic substrate.

Characteristics of Joint Between Ag-Pd Thick Film Conductor and Solder Bump and Interfacial Reaction (Ag-Pd 후막도체와 솔더범프 사이의 접합특성 및 계면반응)

  • 김경섭;한완옥;이종남;양택진
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.1
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    • pp.1-6
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    • 2004
  • The requirements for harsh environment electronic controllers in automotive applications have been steadily becoming more and more stringent. Electronic substrate technologists have been responding to this challenge effectively in an effort to meet the performance, reliability and cost requirements. An effect of the plasma cleaning at the ECM(Engine Control Module) alumina substrate and the intermetallic compound layer between Sn-37wt%Pb solder and pad joints after reflow soldering has been studied. Organic residual carbon layer was removed by the substrate plasma cleaning. So the interfacial adhesive strength was enhanced. As a result of AFM measurement, conductor pad roughness were increased from 304 nm to 330 nm. $Cu_6/Sn_5$ formed during initial reflow process at the interface between TiWN/Cu pad and solder grew by the succeeding reflow process, so the grains became coarse. A cellular-shaped $Ag_3Sn$ was observed at the interface between Ag-Pd conductor pad and solder. The diameters of the $Ag_3Sn$ grains ranged from about 0.1∼0.6 $\mu\textrm{m}$. And a needle-shaped was also observed at the inside of the solder.

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Numerical Study on Failure Mechanism of Tunnel Shotcrete Lining (터널 숏크리트 라이닝 파괴 메커니즘에 대한 수치해석적 고찰)

  • Shin, Hyusoung;Shin, Dongin;Bae, Gyujin;Kim, Donggyu
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.7
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    • pp.167-177
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    • 2009
  • This study investigates a failure mechanism of a tunnel shotcrete lining with respect to a concentrated load due to blocky rock mass. First of all, it is carried out to survey relevant researches to shotcrete failures by literature reviews and to numerically re-investigate the failure modes of shotcrete lining given by previous researches. Through this study, the failure modes are relocated with the conditions which induce each failure mode newly proposed by this study. In addition to this, the arching shape of tunnel lining, which has not been considered in the previous research despite of inherent geometrical characteristics in tunnels, is taken into consideration in numerical investigation on lining failure in this study. As a result, it is shown that more simplified failure modes can be found on the tunnel boundary condition and the corresponding failure condition to each mode can be different from ones of the previous study due to a tunnel arching effect.

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Repair of seismically damaged RC bridge bent with ductile steel bracing

  • Bazaez, Ramiro;Dusicka, Peter
    • Steel and Composite Structures
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    • v.26 no.6
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    • pp.745-757
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    • 2018
  • The inclusion of a ductile steel bracing as means of repairing an earthquake-damaged bridge bent is evaluated and experimentally assessed for the purposes of restoring the damaged bent's strength and stiffness and further improving the energy dissipation capacity. The study is focused on substandard reinforced concrete multi-column bridge bents constructed in the 1950 to mid-1970 in the United States. These types of bents have numerous deficiencies making them susceptible to seismic damage. Large-scale experiments were used on a two-column reinforced concrete bent to impose considerable damage of the bent through increasing amplitude cyclic deformations. The damaged bent was then repaired by installing a ductile fuse steel brace in the form of a buckling-restrained brace in a diagonal configuration between the columns and using post-tensioned rods to strengthen the cap beam. The brace was secured to the bent using steel gusset plate brackets and post-installed adhesive anchors. The repaired bent was then subjected to increasing amplitude cyclic deformations to reassess the bent performance. A subassemblage test of a nominally identical steel brace was also conducted in an effort to quantify and isolate the ductile fuse behavior. The experimental data from these large-scale experiments were analyzed in terms of the hysteretic response, observed damage, internal member loads, as well as the overall stiffness and energy dissipation characteristics. The results of this study demonstrated the effectiveness of utilizing ductile steel bracing for restoring the bent and preventing further damage to the columns and cap beams while also improving the stiffness and energy dissipation characteristics.

Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • v.10 no.5
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

Electrochemical Characteristics of MnO2 Electrodes as a function of Manufacturing Process (제조공정에 따른 MnO2산화물 전극의 전기화학적 특성)

  • 김현식;이해연;허정섭;이동윤
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.486-491
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    • 2004
  • Dimensionally stable anode(DSA) can be used for the hydro-metallurgy of non-ferrous metals like as Zn, and the electrolysis of sea water. MnO$_2$ electrode satisfies the requirements of DSA, and has a good cycle life and a low overpotential for oxygen evolution. MnO$_2$ electrodes based on Ti matrix were prepared by using thermal decomposition method and also MnO$_2$ was coated on Ti and Pb matrix with DMF and PVDF compositions. The MnO$_2$ electrodes prepared by thermal decomposition method had very weak adhesive strength onto Ti matrix and MnO$_2$ layer was removed out so that electrochemical properties for MnO$_2$ were not investigated. The viscosity of solvent used as a binder of MnO$_2$ Powder increased with the increasing PVDF contents. The thickness of the MnO$_2$ layer on Pb matrix in DSA, which was prepared with 5 times dipping at the solution mixed with PVDF : DMF = 1 : 9, was 150${\mu}{\textrm}{m}$. When the ratio of PVDF to MnO$_2$ was lower than 1 : 6, the Pb electrode didn't show any reaction irrespective of the concentrations of DMF. However, When the ratio of PVDF to MnO$_2$ was higher than 1: 6, the Pb electrode showed constant current reactions and homogeneous cyclic voltammetry even though at a high cycle. The reason for the high current and homogeneous cyclic voltammetry is the good catalytic reactions of MnO$_2$ powder in electrode.

Manufacturing and Properties of Low Vacuum Plasma Sprayed W-Carbide Hybrid Coating Layer (진공 플라즈마 스프레이 공정을 이용한 W계 복합 코팅층의 제조 및 특성 연구)

  • Cho, Jin-Hyeon;Jin, Young-Min;Ahn, Jee-Hoon;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.226-237
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    • 2011
  • W-ZrC and W-HfC composite powders were fabricated by the Plasma Alloying & Spheroidization (PAS) method and the powders were sprayed into hybrid coating layers by using Low Vacuum Plasma Spray (LVPS) process, respectively. Microstructure, mechanical properties, and ablation characteristics of the fabricated coating layers were investigated. The LVPS process led to successful production of W-Carbide hybrid coatings, approximately 400 ${\mu}M$ or above in thickness. As the substrate preheating temperature increased from $870^{\circ}C$ to $917^{\circ}C$, the hardness of the W-ZrC coating layer increased due to decreased porosity. Vickers hardness showed higher value (about 108.4 HV) in W-ZrC hybrid coating material compared to that of W-HfC while adhesive strength was found to be similar in both coating layers. The plasma torch test revealed good ablation resistance of the W-Carbide hybrid coating layers. The relatively high performance W-ZrC coating layer at the elevated temperature is thought to be attributed to both the strengthening effect of ZrC particle remained in the layer and the formation of ZrO2 phase with high temperature stability.

Studies on Manufacture of Thin Composite Panel for Substitute Use of Plywood (I) - On the Optimum Manufacturing Condition of Composites - (합판대용(合板代用) 박판상(薄板狀) 복합재(複合材) 제조(製造)에 관(關)한 연구(硏究) (I) - 복합재(複合材) 제조(製造)의 최적조건(最適條件)에 관(關)하여 -)

  • Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.2
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    • pp.55-69
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    • 1995
  • The primary objective of this research was to investigate optimum manufacturing condition of thin composite panels composed of sawdust, polyethylene film and polypropylene net. At the study the experiment was designed to make thin board in which sawdust offers effectiveness as core composing material, polyethylene as adhesive with added urea resin, and polypropylene as stiffness and flexibility in the composition panel. 100 types of thin composite panels were manufactured according to press-lam and mat-forming process of various hot pressing conditions(pressure, temperature and time). They were tested and compared with control boards on bending properties(MOR, MOE, SPL, WML), internal bond strength, thickness swelling, linear expansion and water absorption. At the same time the visual inspections of each types of panels were accomplished. The physical and mechanical properties of composite types passed by visual inspection were analyzed by Tukey's studentized range test. From the statistical analysis, the optimum manufacturing condition of thin composite panels were selected. Compared with two manufacturing processes, mat-forming process performed better than press-lam process in all tested properties. The optimum manufacturing conditions resulted from the experiment and statistical analysis were able to determine as following: the press temperature was shown the most good result at 130$^{\circ}C$ in mat forming process and 140$^{\circ}C$ press lam process, the press time 4 min in both processes, but the press pressure was 25-10kg/$cm^2$ in mat forming and 15k/$cm^2$ press lam process.

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A Study on the Cold Pad Batch Dyeing of a String Wallcovering with Reactive Dyestuff (반응성염료를 이용한 스트링벽지 패딩염색에 관한 연구)

  • Lee, Joonhan;Kang, Youngwoong;Kim, Sunmee
    • Journal of Fashion Business
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    • v.21 no.2
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    • pp.105-112
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    • 2017
  • A string wallcovering is a kind of textile wallcovering which is made of cellulose fiber yarn laminated on base paper. Compared with normal paper or PVC wallpaper, a string wallcovering is preferred continually in the interior design market, as it is not only environmentally friendly but it also has less cost on mass production without the weaving process and has a natural visual effect, excellent functionality such as thermo keeping, permeability, sound absorption. However, in the dyeing process, it is not appropriate to use plenty of energy such as water, electricity, steam or chemicals considering the environmental trend and the government policy plenty of energy such as water, electricity, steam or chemicals. Currently, a string wallcovering is made of raw white yarn and padding with direct dye or pigment which includes toxic elements, especially the use of direct dye is restricted in a part of the developed country due to inclusion of azo. In this study, we researched dyeing based on cold pad batch dyeing of a string wallcovering with reactive dyestuff. The peel strength and bending depth test confirmed that the optimum adhesive type and spread amount improved the water resistance of the string wallcovering. Also, pad batch dyeing with optimum reactive dyestuff enhanced the color fastness to light and rubbing in dry and wet conditions. Additionally, for improvement of color fastness to rubbing in a wet condition, the additional treatment finishing without soaping process which is used water. The results of this study can be used as basic data for environmentally friendly and energy saving of the textile wallcovering.

A Study on the high Temperature Properties of the Graded Thermal Barrier Coatings by APS and PAS (APS법으로 제조된 열장벽 피막과 PAS법으로 제조된 열장벽 성형체의 고온 물성에 관한 연구)

  • 강현욱;권현옥;한주철;송요승;홍상희;허성강;김선화
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.144-156
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    • 1999
  • Thermal Barrier Coating with Functional Gradient Materials (FGM-TBC) can play an important role to protect the parts from harmful environments in high temperatures such as oxidation, corrosion, and wear and to improve the efficiency of aircraft engine by lowering the surface temperature on turbine blade. FGM-TBC can increase the life spans of product and improve the operating properties. Therfore, in this study the evaluations of mechanical and thermal properties of FGM-TBC such as fatigue, oxidation and wear-resistance at high temperatures have been conducted. The samples of both the TBC with 2, 3, 5 layers (YSZ/NiCrAlY) to be produced by Air Plasma Spray method (APS) and the bulk TBC with 6 layers to be produced by Plasma Assisted Sintering method (PAS) were used. Furthermore, residual stress, bond strength, and thermal conductivity were evaluated. The average thickness of the APS was 500$\mu\textrm{m}$ to 600$\mu\textrm{m}$ and the average thickness of the PAS was 3mm. The hardness number of the top layer of APS was 750 Hv to 810Hv and that of PAS was 950 Hv to 1440Hv. The $ZrO_2$ coating layer of APS was composed of tetragonal structure after spraying as the result of XRD analysis. As shown in the results of the high temperature wear test, the 3 layer coating of APS had the best wear resistance at $800^{\circ}C$ and the 5 layer coating of APS had the best wear resistance at $600^{\circ}C$. But, these coatings had the tendency of the low-temperature softening at $300^{\circ}C$. The main mechanism of wear was the adhesive wear and the friction coefficient of coatings was increased as increasing the test temperatures. A s results of thermal conductivity test, the ${\Delta}T$ of the APS coating was increased as number of layer and the range of thermal conductivity of the PAS was $800^{\circ}C$ to $1000^{\circ}C$.

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