• Journal of Adhesion and Interface
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• v.4 no.3
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• pp.9-13
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• 2003

In this paper, the effects of crosslinking agent and pH controlling agent on adhesive properties and water solubility of water soluble acrylic pressure sensitive adhesives were studied by adding the crosslinking agents or pH controlling agents after the polymerization. the tack, cohesive strength, and peel strength were measured to evaluate adhesive properties. the turbidity was also measured to evaluate water solubility of pressure sensitive adhesives. When crosslinking agent was added less than 0.2 wt%, tack increased and cohesive strength and peel strength decreased with increasing concentration. When crossinking agent was added more than 0.2 wt%, the results were opposited. When pH controlling agent was added, tack and water solubility decreased and peel strength and cohesive strength increased with increasing concentration. the influence of pH controlling agents on adhesive properties and water solubility of pressure sensitive adhesive increased in the order of lithium hydroxide, potassium hydroxide and sodium hydroxide.

• Journal of the Korea Institute of Building Construction
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• v.12 no.5
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• pp.539-547
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• 2012

To manufacture laminated wood with improved mechanical properties by providing uniform adhesiveness, the adhesive was applied and the plate adhesive was laminated on the wood surface. Then, after laminating the wood on the top part of the adhesivebond, it was heated and dried while the adhesive was stiffened using microwaves, and the test piece was manufactured by compressing it with the press machine for thirty minutes. The temperature and the water content were examined according to the heating time of the wood heated with the microwave, and testing was conducted on the shear strength and flexural strength of the wood. In addition, the microstructure of the adhesive bond between the wood was recorded to confirm the penetrabilityinto the wood structure for the adhesive. After the test was conducted, it was found that the test piece manufactured with wood that has its water content leveled with the microwave heating showed improved shear strength and bending strength compared to the standard test piece. With regard to adhesives, liquefied polyvinyl acetate resin and plate's PVB resin were found to have superior adhesive strength. Also, after filming the cellular microstructure, it was found that when the laminated wood is heated with microwaves, the infiltration of the adhesive into the inside of the wood becomes easy, which makes it effective for improving adhesiveness.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.111-111
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• 2017

There still exist adhesives that have toxic compounds or consist of those materials in both our life and lots of industries. For instance, formaldehyde adhesive had been still used for woodworking and some medical adhesives had been considered as toxicity problems. In this situation, natural adhesives from raw materials have been suggested as an one of considerable interests. Natural adhesives in recent have been reported fabrication methods via biological materials such as proteins, celluloses, and starches. By-products derived from agricultural something have them richly and each has additional special properties. Using these properties to make natural adhesives, unique adhesives would be attained. In particular, rice-based adhesive is such a good example. Rice-based by-product adhesives have interestingly some pros pertaining to high adhesive strength, excellent water resistance and could dramatically be reduced a formaldehyde a harmful component of plywood. Hence, rice-based adhesive like glues could be applied to lots of industries including agricultural and biological technology. This review paper highlighted some recent development on natural adhesives as a promising biomaterial for agricultural and biological technology fields. The design of agricultural by-product-based natural adhesives were described to demonstrate the application of agricultural and biological technology

• Journal of the Korea Furniture Society
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• v.12 no.2
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• pp.1-10
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• 2001

As finger joint method has a high rate of yield and high strength and ease in working, it has been widely used as an end joint method for solid wood and wood based-material. Therefore, we end-joined the material of Pinus densiflora, Quercus variabilis and populus euramericana with polyvinyl acetate adhesive and resorcinol phenol resin adhesive. The effect of difference (0, 0.15, 0.3, 0.45mm) between the dimensions of tip width and root width of the finger (DTRW) on bending strength properties was as follows: 1. In the case of polyvinyl acetate adhesive, DTRW had no effect on bending modulus of elasticity(MOE) and modulus of rupture(MOR) of the three kinds of species, because their bonding layers were destroyed by slippage, not their woody parts. 2. In the case of resorcinol phenol resin adhesive, the material of Quercus variabilis showed an optimal result at 0.15 or 0.3 of DTRW, while the poplar did at 0 of DTRW 3. The differences in efficiency ratio of bending MOR of populus euramericana, Pinus densiflora and Quercus variabilis species according to the kind of adhesive were 13-29%, 23-30% and 45-53%, respectively.

• Journal of Adhesion and Interface
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• v.9 no.4
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• pp.12-16
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• 2008

Hot-melt adhesive was solid phase in room temperature as 100% solid contents. So it has advantage which attach to substrate with the low pressure heat, fast adhesion speed and environment friendly. In this study, We studied about the effect of a kind of SBS resin and petroleum resin as a tackifier resin and their ratio for hot-melt adhesive on properties. The styrene and $C_9$ resin contents in hot-melt adhesive was increased with increasing viscosity, tensile strength, peel strength and thermal resistance.

• Structural Engineering and Mechanics
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• v.83 no.5
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• pp.693-707
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• 2022

Bonded joints have proven their performance against conventional joining processes such as welding, riveting and bolting. The single-lap joint is the most widely used to characterize adhesive joints in tensile-shear loadings. However, the high stress concentrations in the adhesive joint due to the non-linearity of the applied loads generate a bending moment in the joint, resulting in high stresses at the adhesive edges. Geometric optimization of the bonded joint to reduce this high stress concentration prompted various researchers to perform geometric modifications of the adhesive and adherends at their free edges. Modifying both edges of the adhesive (spew) and the adherends (bevel) has proven to be an effective solution to reduce stresses at both edges and improve stress transfer at the inner part of the adhesive layer. The majority of research aimed at improving the geometry of the plate and adhesive edges has not considered the effect of temperature and water absorption in evaluating the strength of the joint. The objective of this work is to analyze, by the finite element method, the stress distribution in an adhesive joint between two 2024-T3 aluminum plates. The effects of the adhesive fillet and adherend bevel on the bonded joint stresses were taken into account. On the other hand, degradation of the mechanical properties of the adhesive following its exposure to moisture and temperature was found. The results clearly showed that the modification of the edges of the adhesive and of the bonding agent have an important role in the durability of the bond. Although the modification of the adhesive and bonding edges significantly improves the joint strength, the simultaneous exposure of the joint to temperature and moisture generates high stress concentrations in the adhesive joint that, in most cases, can easily reach the failure point of the material even at low applied stresses.

• Journal of Welding and Joining
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• v.24 no.5
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• pp.43-48
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• 2006

This paper is concerned with a fracture strength study of composite adhesive lap joints. The tests were carried out on specimen joints manufactured hybrid stacked composites such as the polyester and bamboo natural fiber layer. The main objective of the work was to test the fracture strength using hybrid stacked composites with a polyester and bamboo natural fiber layer. Tensile and peel strength of hybrid stacked composites are tested before appling adhesive bonding. From results, Natural fiber reinforced composites have lower tensile strength than the original polyester. and The load directional orientation and small amount and low thickness of bamboo natural fiber layer have a good effect on the tensile and peel strength of natural fiber reinforced composites. The failure strength of these materials applied adhesive bonding is also affected by fiber orientation and thickness of bamboo natural fiber layer. There for, Fiber orientation of bamboo natural fiber layer have a great effect on the tensile-shear strength of natural fiber reinforced composites including adhesive bonded joints.

• Journal of Adhesion and Interface
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• v.3 no.1
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• pp.43-51
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• 2002

Advanced adhesive technologies and demanding applications of adhesive joints can no longer be developed successfully by the traditional "trial and error" approach. Appropriate technical solutions require reference to a reliable basis of well-established scientific knowledge about the elementary mechanisms of adhesion (i.e. the 'fundamental adhesion') as they are responsible for the capability of the compound w transmit mechanical force between the adhesive and the substrate surface (i.e. the 'practical adhesion'). Adhesion mechanisms also influence the formation of polymer structure in the adhesive and the resulting macromolecular dynamics in the interphase that is formed in the adhesive near to the substrate. These manifold molecular factors rule the macroscopic behaviour of an adhesive bond line in terms of mechanical and other physical properties as well as in terms of durability. This paper reviews the level of refinement that understanding of fundamental adhesion has achieved up to now.

• Polymer(Korea)
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• v.39 no.2
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• pp.281-286
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• 2015

UV-cured acrylic copolymer pressure sensitive adhesive (PSA) having different amounts of crosslinking agents were prepared and adhesion properties were investigated. 0.01 wt% of MMT clay was dispersed in 2-ethylhexyl acrylate (2-EHA)/acrylic acid (AA) monomer mixture containing 0, 0.05, 0.1 and 0.3 wt% 1,6-hexandiol diacrylate (HDDA) for crosslinking. It was investigated that the curing behavior and surface chemistry of PSAs were merely affected by the presence of MMT clays. On the other hand, adhesive properties were influenced by the MMT addition; a cohesive failure was restrained due to improved molecular elasticity even in uncrosslinked acrylic PSAs. However, it was also appeared that combination of 0.3 wt% crosslinking agent and MMT loading might result in the damage of adhesion properties of PSAs possibly due to the lack of chain flexibility. In our studies, it is suggested that the 2-EHA/AA PSAs incorporating 0.01 wt% of MMT and crosslinked with 0.05 wt% of HDDA exhibited the balanced adhesion properties without severe cohesive failure during strip.

• Journal of Adhesion and Interface
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• v.17 no.1
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• pp.1-6
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• 2016

In this study, to replace a complicated process such as in the rubber component used in the adhesive of the shoe buffing, pretreatment with primers, we studied mechanical properties and adhesive properties with rubber compound added propanamine and 1,6-Hexanediamine. The adhesive properties rubber specimen added propanamine did not occurrence, but The adhesive properties rubber specimen added 1,6-Hexanediamine was occurrence. Also, the contact angle was decreased compared to not added NBR. And rubber compound added 6-Hexanediamine was smaller than the contact angle was evaluated in comparison to the added propanamine. $NH_2$ group on the rubber surface were confirmed with a peak at $1450{\sim}1550cm^{-1}$ in FT-IR spectrum. Rubber compound added propanamine and 1,6-Hexanediamine was reduced mechanical properties and decreased NBS resistance.