• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 춘계학술대회 논문집 방전 플라즈마 유기절연재료 초전도 자성체연구회
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• pp.11-14
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• 2004

In this paper, the effect of adhesion properties of semiconductive-insulating interface layer of silicone rubber on electrical properties was investigated. The modifications produced on the silicone surface by oxygen plasma were accessed using ATR-FTIR, contact angle and AFM. Adhesion was obtained from T-peel tests of semiconductive layer having different treatment durations. In addition, ac breakdown test was carried out for elucidating the change of electrical property with duration of plasma treatment. From the results, the treatment in the oxygen plasma produced a noticeable increase in surface energy, which can be mainly ascribed to the the creation of O-H and C=O. It is observed that adhesion performance was determined by not surface energy but roughness level of silicone surface. It is found that ac dielectric strength was increased with improving the adhesion between the semiconductive and insulating interface.

• Journal of Electrochemical Science and Technology
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• 제9권4호
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• pp.330-338
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• 2018

The adhesion strength as well as the electrochemical properties of $LiNi_{0.4}Mn_{0.4}Co_{0.2}O_2$ electrodes containing various conductive carbons (CC) such as fiber-like carbon, vapor-grown carbon fiber, carbon nanotubes, particle-like carbon, Super P, and Ketjen black is compared. The morphological properties is investigated using scanning electron microscope to reveal the interaction between the different CC and the active material. The surface and interfacial cutting analysis system is also used to measure the adhesion strength between the aluminum current collector and the composite film, and the adhesion strength between the active material and the CC of the electrodes. The results obtained from the measured adhesion strength points to the fact that the structure and the particle size of CC additives have tremendous influence on the binding property of the composite electrodes, and this in turn affects the electrochemical property of the configured electrodes.

• 한국재료학회지
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• 제29권6호
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• pp.378-384
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• 2019

Ice accumulation on Aluminum Conductor Steel Reinforced(ACSR) cable during winter is an important matter in terms of safety, economy, and efficient power supply. In this work, the ice adhesion strengths of ACSR cable oxidized during different periods(7 years oxidized and 15 years oxidized) are evaluated. At first, a plate type dry oxidation standard specimen, whose surface characteristics are similar to those of ACSR cable, is prepared. Dry oxidation standard specimens are heat-treated at $500^{\circ}C$ for 20, 60, and 120 minutes in order to obtain different degrees of oxidation. After the dry oxidation, surface properties are analyzed using contact angle analyzer, atomic force microscopy, spectrophotometer, and gloss meter. The ice adhesion strengths are measured using an ice pull-off tester. Correlations between the surface properties and the ice adhesion strength are obtained through a regression analysis indicating a Boltzmann equation. It is revealed that the ice adhesion strength of 15-year oxidized ACSR cable is approximately 8 times higher than that of ACSR-bare.

• 접착 및 계면
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• 제3권1호
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• pp.43-51
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• 2002

Advanced adhesive technologies and demanding applications of adhesive joints can no longer be developed successfully by the traditional "trial and error" approach. Appropriate technical solutions require reference to a reliable basis of well-established scientific knowledge about the elementary mechanisms of adhesion (i.e. the 'fundamental adhesion') as they are responsible for the capability of the compound w transmit mechanical force between the adhesive and the substrate surface (i.e. the 'practical adhesion'). Adhesion mechanisms also influence the formation of polymer structure in the adhesive and the resulting macromolecular dynamics in the interphase that is formed in the adhesive near to the substrate. These manifold molecular factors rule the macroscopic behaviour of an adhesive bond line in terms of mechanical and other physical properties as well as in terms of durability. This paper reviews the level of refinement that understanding of fundamental adhesion has achieved up to now.

• Composites Research
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• 제29권5호
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• pp.276-281
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• 2016

본 연구에서는 돌침대용 석재/목재 복합재의 열적특성 및 접착특성 개선에 대한 연구를 진행하였다. 기초 물성을 체크하기 위해 인장실험을 진행하였고 석재 및 목재의 실시간 온도측정을 진행하였다. 석재/목재 복합재의 가열부위에 따른 열적 특성을 알아보기 위해 석재를 위로 두었을 때와 목재를 위로 두었을 때 두 가지 방법으로 가열을 실시하였다. 에폭시 접착제에 CNT를 넣음으로써, 열적 및 접착특성의 변화를 알아보기 위하여 실시간 온도측정과 랩 전단 실험을 실시하였다. 실험결과 목재를 위로 두었을 때 열적 특성이 좋은 것을 확인하였고 에폭시 접착제에 CNT를 넣음으로써 접착특성 및 열적특성이 개선됨을 볼 수 있었다.

• 한국환경과학회지
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• 제23권11호
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• pp.1909-1918
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• 2014

In this experiment no solvent based polyurethane(PU) adhesives were prepared with the polyol, isocyanate, dioctyl phthalate(DOP), 2-hydroxyethylacrylate(2-HEA) and other acrylate monomers. The softenening point of the PU adhesives measured by Ring & Ball method were examined in the present study. And adhesion strength and mechanical properties such as tensile strength and 100% modulus of the PU adhesives were evaluated by Universal Test Machine. The experimental results showed that increase of both DPE-41, benzoylperoxide(BPO) and toluene diisocyanate(TDI) increased softenening point, adhesion strength, tensile strength and 100% modulus. However as DOP content increased sofenening point, adhesion strength decreased and tensile strength, 100% modulus also decreased.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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• pp.343-348
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• 2000

The purpose of this study is to clarify properties adhesive strength of polymer-cement slurry for coated reinforcing bars. The epoxy coating material is superior to performance of anti-corrosion but lately age adhesive strength between concrete raise to structural problems. However, polymer dispersion with excellent performance of elasticity and adhesion can solve this problems. From the test results. adhesion of steel with polymer cement slurry using St/BA emulsion is show excellent without concerned coating thickness, and polymer cement slurry using St/BA emulsion is show adhesion in tension 1.2~2.2MPa at polymer cement ratio 50% of more.

• 한국응용과학기술학회지
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• 제24권1호
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• pp.23-30
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• 2007

Kevlar was chemically surface modified with resorcinol-formaldehyde(RF) prepolymer and VP rubber latex for application to high strength tirecords. RF prepolymer was easily obtained by polymerization at room temperature in the presence of a base catalyst. The mechanical and thermal properties of Kevlar were not significantly changed during surface treated under various conditions. The change of adhesion with rubber were investigated through H-test method. Maximum increase of adhesion force between rubber and Kevlar was obtained up to 40% than that of untreated one when the fiber was soaked in RFL dipping solution and thermally treated at $170^{\circ}C$ for 3 - 5min.

• Elastomers and Composites
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• 제34권3호
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• pp.253-261
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• 1999

조성이 다른 접착제를 포함한 고무혼합물의 가교특성은 접착제 조성에서 탄닌이 많이 포함될수록 스코치 시간은 증가하였으며 경화속도는 다소 감소하는 것으로 보아 탄닌 분자의 크기와 형태 때문에 초기 가교반응을 지연시킴과 동시에 경화속도 역시 다소 지연됨을 알 수 있었다. 이들 고무혼합물의 인장물성 역시 탄닌이 많이 함유된 접착제를 고무에 혼합할수록 고무혼합물의 인장강도는 다소 감소하였다. 이는 탄닌이 많이 함유될수록 가교반응을 지연시켜 전체 고무혼합물의 가교도가 감소하기 때문일 것으로 사료되었다. 또한 접착제의 조성이 고무-섬유 접착에 미치는 영향을 보강코드로서 나일론 610 모노필라멘트를 사용하여 TCAT(Tire Cord Adhesion Test) 방법으로 조사하였다. 레소시놀-탄닌-포름알데히드-라텍스(RTFL) 접착제 조성에서 레소시놀 1 mole당 포름알데히드의 mole 비가 증가할수록 접착력은 증가하였고 대략 포름알데히드 5mole 이상에서 최적의 접착력을 나타냈다. 보강코드상의 접착제 수확량(DPU) 역시 최종 접착력에 영향을 미치지만, 나일론 610 모노필라멘트의 경우는 접착제 조성에 따른 DPU가 거의 일정하여 접착력의 차이는 접착제의 조성 중 탄닌의 거동 때문으로 해석될 수 있었다.

• 접착 및 계면
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• 제9권2호
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• pp.32-37
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• 2008

광개시제 함량이 0.5 wt%, 1 wt%, 2 wt%인 UV 경화형 분체도료를 배합하고 낮은 온도에서도 용융되는 수지를 선택하여 열민감성 기재에 적용이 가능함을 알아보았다. 열민감성 기재로는 PVC와 목재제품(MDF, 합판 등)을 선택하여 표면경도, 광택, 부착력을 통해서 기재와의 상관관계를 알아보았다. 광개시제 양이 증가할수록 가교밀도가 증가하여 도막이 brittle해지는 경향을 보였고, 그에 따라 부착력이 감소하였다. 열민감성 기재에 적용한 결과, 표면경도는 기재에 영향을 받지 않았지만 광택은 기재에 따라서 차이가 나타났다. 그리고 UV 경화형 분체도료의 부착력은 열민감성 기재에 적용하기에 충분하였다. 본 연구 결과, UV 경화형 분체도료에서 광개시제 함량이 중요한 인자이며 열민감성 기재에 적용이 가능함을 확인하였다.