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A study on the synthesis of porous silica from a sodium silicate (물유리로부터 다공성 실리카 제조에 관한 연구)

  • Yoo, Jeong-Kun;Keum, Young-Ho;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.4
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    • pp.2519-2525
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    • 2014
  • WeI have studied the process for synthesizing porous silica with a specific surface area of minimum $800m^2/g$ by adding surfactant [Poly Etylene Glycol(PEG) and Hydroxy Propyl Cellulose(HPC)] to the sol-gel reaction between sodium silicate and hydrochloric acid. NaCl, the by-product of the sol-gel reaction, was water cleaned and removed; when 200 ml of water was used to clean 50 g of silica gel, NaCl remaining in the silica gel was reduced to maximum 0.81wt%. The appropriate level of surfactant for silica gel synthesizing proved to be below 5%. As a result of the experiment, for the silica synthesized by adding surfactant of HPC(2.5%)+PEG(2.5%), the surfactant area was $860m^2/g$ and grain size was $20-50{\mu}m$. From this study, we have concluded that it is of industrial significance that specific surface area is improved and silica of a regular grain size is obtained just by adding surfactant in the gel process or drying process of silica.

A Study on Quality Characteristics of Backsulgi with Adding Agar Powder (Agar 첨가에 따른 백설기의 품질특성 연구)

  • Kim, Kyoung-Ja;Yang, Ji-Na
    • Korean Journal of Human Ecology
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    • v.8 no.1
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    • pp.33-48
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    • 2005
  • The purpose of this is to agar powder addition to retard retragradation for making Backsulgi. Backsulgi is manufactured promptly by adding ingredients having agar powder and then observation of sensory and texture characteristics. Then Backsulgi determinded in storing at the temperatures of 20 and Celsius degrees for 0, 24, 48 and 72 hours, respectively. The results from this study are as follow; 1. Moisture absorption of control show 34.4%, compared with, Backsulgi with agar powder added 3%, 6%, 9%, 12%, 15% show higher 37.03%, 39.28%, 41.72%, 43.5%, 44.70%, respectively. 2. In terms of chromaticity, lightness of control show $70.68{\pm}7.248{\sim}61.25{\pm}0.90$, the longer time is and much agar powder Backsulgi show lower and 15% agar powder added Backsulgi show $51.53{\pm}0.921{\sim}54.715$. Then redness(a) of control show $-0.70{\pm}0.14$, compared with 15% agar powder added Backsulgi show $-0.32{\pm}0.047$. 15% agar powder Backsulgi show $9.03{\pm}0.313$ higher in yellowness than control $5.47{\pm}0.40$. 3. Control and agar powder Backsulgi was shown pH 6.1~6.3, the longer time is, all Backsulgi was shown pH 5.5~5.9 and much agar powder Backsulgi was shown an weakly acidity. 4. Swelling and pore ratio of control was shown 85.36% and 118.32%, compared with, agar powder added Backsulgi was higher a rate of increase. 5. For a sensory evaluation, the longer time is, adding agar powder rice cake is more perfected at 20$^{\circ}C$ in times if smooth, inner moisture, chewiness, after selling, overall quality. 6. Determination of texture characteristics by a reometer shows that Backsulgi with agar powder added change more in hardness that controls, indicating that effect of retarding retrogadation is higher when storage time is longer. 7. The correlation of hardness, springness between sensory and instrumental evaluation showed significantly positive function.

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A Study on Combustion Characteristics and Evaluating of RDFs(Refused Derived Fuels) from Mixture of Petrochemical Wastewater Sludge and Organic Matters (석유화학폐수슬러지와 유기성 폐기물 혼합에 의한 연소특성 및 고형연료 폐기물화 재활용에 관한 연구)

  • Han, Young-Rip;Choi, Young-Ik
    • Journal of Environmental Science International
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    • v.24 no.2
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    • pp.237-244
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    • 2015
  • This objectives of research are to figure out combustion characteristics with increasing temperature with petrochemical sludge by adding wasted organic matters which are waste electric wire, anthracite coal and sawdust, and to exam heating value and ignition temperature for using refused derived fuels(RDFs). After analyzing TGA/DTG, petrochemical sludge shows a rapid weight reduction by vaporing of inner moisture after $170^{\circ}C$. Gross weight reduction rate, ignition temperature and combustion rates represent 68.6%, $221.9^{\circ}C$ and 54.1%, respectively. In order to assess the validity of the RDFs, the petrochemical sludge by adding wasted organic matters which are waste electric wire, anthracite coal and waste sawdust. The materials are mixed with 7:3(petrochemical sludge : organic matters)(wt%), and it analyzes after below 10% of moisture content. The ignition temperatures and combustion rates of the waste electric wire, anthracite coal and waste sawdust are $410.6^{\circ}C$, $596.1^{\circ}C$ and $284.1^{\circ}C$, and 85.6%, 30.7% and 88.8% respectively. In heating values, petrochemical sludge is 3,600 kcal/kg. And the heating values of mixed sludge (adding 30% of the waste electric wire, anthracite coal and waste sawdust) each increase up to 4,600 kcal/kg, 4,100 kcal/kg and 4,300 kcal/kg. It improves the ignition temperatures and combustion rates by mixing petrochemical sludge and organic matters. It is considered that the production of RDFs is sufficiently possible by using of petrochemical sludge by mixing wasted organic matters.

Changes in Physical and Chemical Properties of Sandy Loam Soils by Hematite Addition (적철석 첨가에 의한 사질양토의 물리·화학적 특성변화)

  • Kim, Jae Gon;Dixon, Joe B.;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.31 no.4
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    • pp.291-296
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    • 1998
  • Pedogenic hematite is a well known agent for sink of pollutants and nutrients and for aggregation of particles in soils. Changes in physical and chemical properties of two sandy loam soils (Anahuac and Crowley soils) from the Southern Coastal Plain, the United States of America, were tested after adding finely ground crystalline hematite prepared for drilling fluid weighting material. There was an increase in hydraulic conductivity (HC) of the soils with addition of up to 3% by weight of hematite but a decrease in HC with addition of more hematite. The aggregate stability (AS) of the soils was not affected by adding hematite. Anahuac soil with higher content of organic matter and lower sodium adsorption ratio (SAR) had higher values of HC and AS than Crowley soil. Adding hematite also resulted in a slight increase in zinc (Zn) adsorption by the soils, but had no influence on the adsorption of phosphate.

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Effects of Adding UV and H2O2 on the Degradation of Pharmaceuticals and Personal Care Products during O3 Treatment

  • Kim, Il-Ho;Kim, Seog-Ku;Lee, Hyun-Dong;Tanaka, Hiroaki
    • Environmental Engineering Research
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    • v.16 no.3
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    • pp.131-136
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    • 2011
  • The degradation of 30 pharmaceuticals and personal care products (PPCPs) subjected to $O_3$, $O_3$/UV, and $O_3/H_2O_2$ treatments were investigated using semi-batch tests and evaluated by their pseudo-first-order rate constants. The additional application of UV or $H_2O_2$ during $O_3$ treatment significantly improved the degradation rate of most of the PPCPs. At the same $O_3$ feed rate, $O_3$/UV treatment exhibited much higher PPCP degradation efficiency than that of $O_3$ treatment. This was probably due to degradation of the PPCPs by $O_3$, direct UV photodegradation, and OH radicals that formed from the photodegradation of $O_3$ during $O_3$/UV treatment. PPCP degradation by $O_3$ was also promoted by adding $H_2O_2$ during the $O_3$ treatment. However, when the initial $H_2O_2$ concentration was high during $O_3$ treatment, OH radicals were likely to be scavenged by excess $H_2O_2$, leading to low PPCP degradation. Therefore, it is important to determine the appropriate $H_2O_2$ dosage during $O_3$ treatment to improve PPCP degradation when adding $H_2O_2$ during $O_3$ treatment.

Microstructure and PTCR Characteristics of Porous BaTiO3-based Ceramics Prepared by Adding Carbon Black (카본블랙을 첨가하여 제조한 다공성 BaTiO3계 세라믹스의 미세구조 및 PTCR 특성 변화)

  • Lee, Ki-Ju;Tang, Dongxu;Cho, Won-Seung
    • Journal of Powder Materials
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    • v.18 no.1
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    • pp.41-48
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    • 2011
  • As a pore precursor, carbon black with different content of 0 to 60 vol% were added to (Ba,Sr)$TiO_3$ powder. Porous (Ba,Sr)$TiO_3$ ceramics were prepared by pressureless sintering at $1350^{\circ}C$ for 1h under air. Effects of carbon black content on the microstructure and PTCR characteristics of porous (Ba,Sr)$TiO_3$ ceramics were investigated. The porosity of porous (Ba,Sr)$TiO_3$ ceramics increased from 6.97% to 18.22% and the grain size slightly decreased from $7.51\;{\mu}m$ to $5.96\;{\mu}m$ with increasing carbon black contents. PTCR jump of the (Ba,Sr)$TiO_3$ ceramics prepared by adding carbon black was more than $10^5$, and slightly increased with increasing carbon black. The PTCR jump in the (Ba,Sr)$TiO_3$ ceramics prepared by adding 40 vol% carbon black showed an excellent value of $9.68{\times}10^5$, which was above two times higher than that in (Ba,Sr)$TiO_3$ ceramics. These results correspond with Heywang model for the explanation of PTCR effect in (Ba,Sr)$TiO_3$ ceramics. It was considered that carbon black is an effective additive for preparing porous $BaTiO_3$ based ceramics. It is believed that newly prepared (Ba,Sr)$TiO_3$ cermics can be used for PTC thermistor.

Optimal Treatment of Molasses Wastewater Using UASB Process (UASB 공정에 의한 당밀폐수의 최적처리 방안)

  • Huh, Kwan-Yong;Jeong, Eui-Geun;Chung, Yoon-Jin;Yoo, Sang-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.11 no.2
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    • pp.112-127
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    • 1997
  • The purpose of this study is to get optimum operating factors of Upflow Anaerobic Sludge Blanket (UASB) reactor by introducing methods that make it to reduce inhibition possible in each process wastewater treatment. The used substrates, concentrated corn starch liquid (CSL) wastewater, modified starch, filtering and decoloring wastewater, ion refining wastewater, and mixed wastewater including modified starch and not including modified starch, are generated from molasses process. The seeding sludge is the digested sludge that had been applied to molasses wastewater. Batch test to reduce the inhibition factors that might be existed in each wastewater was examined. Based on the this test, the optimum operating factors according to alkalinity and pH variation was studied through the continuous test using three 5.5 L UASB reactor. The first reactor added $NaHCO_3$ to control alkalinity. The hydraulic retention time (HRT) reduced to 8 hours and the organic loading rate increased gradually. The second reactor changed the pH of influent from 7.0 to 6.0 using NaOH. The third reactor was operated without changes to compare the above two reactors. As the result, the inhibition in concentrated CSL wastewater was removed by adding iron (II). When trace metals were added to mixed wastewater not including modified starch, the digestability by gas production rate increased to more fifty percentage than mixed wastewater that was not adding the trace metals. The reason that the inhibition did not decreased in spite of adding trace metals and nutrients was influenced by high concentration generated during the acid fermentation. The UASB reactors using the mixed wastewater with the most effective performance were operated as 500 mg/L as $CaCO_3$ alkalinity and 6.0 pH at steady state, and at this time, the gas production rates were 283 and 311mL gas/g $COD_{added}$. The COD removal rates were 84.7 and 86.3%, respectively.

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Quality Characteristics and Antioxidant Activities of Cookies added with Gochujang (고추장을 첨가한 쿠키의 품질 특성 및 항산화성)

  • Kim, Do-Yeon;Yoo, Seung-Seok
    • Journal of the East Asian Society of Dietary Life
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    • v.27 no.2
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    • pp.148-158
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    • 2017
  • This study was conducted to investigate the effects of adding gochujang addition to cookie dough on the quality characteristics of cookies. Cookies were prepared by replacing 0% 5%, 10%, 15% and 20% flour with gochujang. The gochujang pH, total soluble solid and salinity were $4.84{\pm}0.02$, $63.33{\pm}4.19%$ and $7.63{\pm}009%$, respectively. The moisture content in gochujang was $40.10{\pm}0.10%$, and the color values of gochujang was were as L-value $24.46{\pm}0.06$, a-value $10.18{\pm}0.13$, and b-value $7.44{\pm}0.10$. The pH values of cookies decreased according to the addition of gochujang. The values of density and loss rate in cookies were not-significantly different among the samples. Spread factor and moisture content of cookies increased with amounts of added gochujang. The salinity and total soluble solid content of cookies with gochujang were significantly higher than those of the control. L-value was significantly reduced, and a-value and b-value increased by adding gochujang. Total phenolic content and DPPH free radical scavenging activities were increased according to the amount of gochujang. For sensory evaluation, gochujang added cookies were more preferred in terms of color, softness and overall preference. Overall, these results indicate that adding 10% gochujang is desirable for making gochujang cookies.

Mechanism of Jaeumgenby-tang adding Aurantii FructusㆍGastrodae Rhizoma on the Improvement against Changes of Cerebral Hemodynamics in Cerebral Ischemia Rats (자음건비탕 가지각ㆍ천마가 뇌허혈동물의 뇌혈유력학 변동 개선에 미치는 작용기전)

  • Woo Jeong Hyun
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.17 no.5
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    • pp.1194-1201
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    • 2003
  • Jaeumgenby-tang(JGT) have been used in oriental medicine for many centries as a therapeutic agent of vertigo caused by deficiency of qi(氣) and blood(血). Effect of Aurantii Fructus(AF) take off the phlegm by promoting the circulation of qi, Gastrodae Rhizoma(GR) has effects treating for headarch, vertigo by calming the liver and suppressing hyperactivity of the liver-yang (陽). I investigated whether injection of JGT adding AFㆍGR extract(JTG) affects cerebral hemodynamics [regional cerebral blood f1ow(rCBF), pial arterial diameter(PAD) in cerebral ischemia rats by MCA occlusion method, and I designed to make manifest whether JTG is mediated by adrenergic β-receptor, cyclooxygenase or guanylate cyclase. The changes of rCBF was determinated by laser-doppler flowmetry(LDF), and the changes of PAD was determinated by video microscope and width analyzer. The results were as follows in cerebral ischemic rats; The changes of rCBF and PAD were increased stabilizly by treatment with JTG(10 ㎎/kg, i.v.) during the period of cerebral reperfusion, and pretreatment with propranolol and indomethacin were increased JTG induced increase of rCBF and PAD during the period of cerebral reperfusion. Pretreatment methylene blue was decreased JTG induced increase of rCBF and PAD during the period of cerebral reperfusion. In conclusion, JTG causes a diverse response of rCBF and PAD, and action of JTG is mediated by adrenergic β-receptor and cyclooxygenase. I suggest that JTG has an anti-ischemic effect through the improvement of crebral hemodynamics.

PREPERATION OF AMPHOTERIC STARCHS AND STUDY ON WET END CHEMISTRY IN PAPERMAKING

  • Shan, Chen-Fu;Su, Xie-Lai;Yi, Wang-Hai;Quan, Long-Yan
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.386-389
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    • 1999
  • Amphoteric polymers have brought to papermakers' attention gradually. In this paper, a series of amphoteric starches with different cationic and anionic degree of substitution (DS) are prepared. Better product has been selected and used under different condition. As retention and drainage aids, amphoteric starches were used in shorter fiber length, weak strength and poor drainage bleached AQ-Soda wheat straw pulp. In neutral and alkaline papermaking system, when amphoteric starches contain 0.024-0.026 anionic degree of substitution (DS), it is shown that the higher the cationic degree of substitution (DS) in amphoteric starches, the better the filler retention. The filler retention is improved 12.5%, 30.3%, and 35.1% and 32.5% respectively by adding 1% amphoteric starch LS-L2 -1 (0.034), LS-L2-2 (0.040), LS-L2-3 (0.047) and LS-L2-4 (0.052). But the strength of handsheets if affected a little. By adding 2% Al2 (SO4)3 and 1.5% LS-L2-3 at pH 7.5, filler retention can be improved from 38% to 80%, and breaking length of sheet only decreases 3.2%. As dry strengthening aids, amphoteric starches were used in eucalyptus APMP. Amphoteric starches are used in eucalyptus APMP. The amphoteric starch LS-L2-2 is better dry strength aid. Adding 1% LS-L2-2 can improve breaking length 24.5%, burst index 42.9%, tear index 38.8%, folding endurance and density of the handsheets.