• Journal of Surface Science and Engineering
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• v.32 no.3
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• pp.393-400
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• 1999

The surface characteristics of nitrogen ion implanted iron aluminides were investigated using various electrochemical methods in $H_2$$SO_4$+KSCN and HCl solutions. Nitrogen ion implantation was performed with doses of $3.0$\times$10^{17}$ /ions/$\textrm{cm}^2$ at an energy of 150keV. Nitrogen ion implanted iron aluminides increased the corrosion potential and significantly decreased grain boundary activation, the active current density, and passive current density. Nitrogen implanted iron aluminides with Mo increased the corrosion, pitting potential, repassivation potential and │$E_{pit}$-$E_{corr}$│ value. Whereas, implanted iron aluminides containing boron reduced the pitting and repassivation potential in comparison with nitrogen implanted iron aluminides with Cr and Mo.o.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.31A no.10
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• pp.79-86
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• 1994

Gain-guided broad-area single quantum well separate confinement heterostructure diode lasers have been fabricated from structures grown by metal organic vapor phase epitaxy. The active layer of the epi-structure is InGaAs emitting 962-965nm and the guiding layer GaAs. The channel width is fixed to 150${\mu}$m and the cavity length varys within the range of 300~800${\mu}$m. For uncoated LD's, the output power of 0.7W has been obtaained at a pulsed current level of 2A, which results about 60% external quantum efficiency. The threshold current density is 200A/cm$^{2}$ for the cavity lengths of 800.mu.m LD's. The stain effect upon the transparent current density has been observed. The internal quantum efficiency is expected to be 88% and the internal loss to be 18$cm^{-1}$. The beam divergence has been measured to be 7$^{\circ}$to lateral and 40$^{\circ}$to transverse direction. finally, 1.2W continuous-wave output power has been obtained at a current level of 2A for AR/HR coated LD's die-bonded on Cu heat-sink and cooled by TEC.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.5
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• pp.495-501
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• 2005

Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.72-72
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• 2010

Recent development of organic solar cell approaches the level of 8% power conversion efficiency by the introduction of new materials, improved material engineering, and more sophisticated device structures. As for interface engineering, various interlayer materials such as LiF, CaO, NaF, and KF have been utilized between Al electrode and active layer. Those materials lower the work function of cathode and interface barrier, protect the active layer, enhance charge collection efficiency, and induce active layer doping. However, the addition of another step of thin layer deposition could be a little complicated. Thus, on a typical solar cell structure of Al/P3HT:PCBM/PEDOT:PSS/ITO glass, we used Li:Al alloy electrode instead of Al to render a simple process. J-V measurement under dark and light illumination on the polymer solar cell using Li:Al cathode shows the improvement in electric properties such as decrease in leakage current and series resistance, and increase in circuit current density. This effective charge collection and electron transport correspond to lowered energy barrier for electron transport at the interface, which is measured by ultraviolet photoelectron spectroscopy. Indeed, through the measurement of secondary ion mass spectroscopy, the Li atoms turn out to be located mainly at the interface between polymer and Al metal. In addition, the chemical reaction between polymer and metal electrodes are measured by X-ray photoelectron spectroscopy.

• Proceedings of the KIPE Conference
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• 2006.06a
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• pp.369-371
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• 2006

Conventional active-clamp forward converter has narrow ZVS range of main switch. Although utilizing high magnetizing current can realize wide ZVS range, it increases the conduction loss. To solve this problem, a new asymmetric two-transformer active clamp forward converter is proposed. Proposed converter achieves wide ZVS range without severe conduction loss penalty, which results in high efficiency and high power density.

• Carbon letters
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• v.1 no.1
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• pp.27-30
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• 2000

Performance of direct methanol fuel cell using high porous active carbon as an uncatalysed diffusion layer in anode (composite electrode) has been evaluated. Effects of porous active carbon in anode were investigated by galvanostatic method and Fourier Transform Infrared spectroscopy. The single cell was operated with 2.5 M methanol at temperature of $80-120^{\circ}C$ and showed performance of $210-510\;mA/cm^2$ at 0.4V. By replacing conventional electrode with composite electrode, the increment of $290\;mA/cm^2$ in current density was obtained at $90^{\circ}C$and 0.4V. The potential decay of the single cell was about 14.5% for 20 days operation.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.12
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• pp.2962-2969
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• 1993

Recently, a study on the mirror-like surface grinding of brittle materials is active and as branch of these study, new dressing method for superabrasive wheel, electrolytic inprocess dressing(Elid) was developed. Using Elid, the mirror-like surface of brittle material can be generated without polishing or lapping process. In the future, Elid grinding will take important place in industry. But so far the analysis on Elid grinding was not quantitative but qualitative. In this study, The purpose is the quantitative analysis on Elid grinding by computer simulation, For computer simulation, the mean and the variance of the abrasive distribution were measured by tracing of the grinding wheel with stylus in transverse direction in the case of respective dressing current condition. This measurement result in a density distribution of abrasive by mathematical formulation using statistical method. The prediction of the surface roughness in Elid grinding was based on this density distribution.

• Proceedings of the KIEE Conference
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• 1990.07a
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• pp.207-210
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• 1990

The purpose of this study is to research and develop polymer secondary battery. This paper describes the first discharge characteristics of PAn/Li-Al secondary battery. PAn was prepared in $HBF_4$ aqueous solution by galvanostatic electropolymerization and then used as cathode active material. PAn/Li-Al secondary battery was prepared in 2025 coin type. Characteristics of this battery are summarized as follows. ${\bullet}$ Open curcuit voltage and discharge end voltage was 3.5V and 2.9V, respectively. ${\bullet}$ The ratio of electricities in discharge to theoretical electricities in all undoping of PAn cathode was 56% at constant current discharge of 1mA. ${\bullet}$ The capacity density, energy density and maximum power density per weight of PAn electroactive material were 56.1Ah/kg, 168.4Wh/kg and 16.9kW/kg, respectively.

• Journal of the Korean Electrochemical Society
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• v.13 no.4
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• pp.240-245
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• 2010

This work explored the catalytic effect of Pt in multi-wall carbon nanotube and poly-pyrrole conductive polymer electrocatalysts (Pt/PPy/MWCNT). A home-made Pt/PPy/MWCNT catalyst was first evaluated by comparing its electrochemical active surface area (ESA) with E-Tek commercial catalysts by cyclic voltammetry in $H_2SO_4$ solution. Then, the methanol oxidation currents of Pt/PPy/MWCNT and the hydrogen peaks in $H_2SO_4$ solution were serially measured with microporous electrode. This provided the current density of methanol oxidation based on the ESA, allowing a quantitative comparison of catalytic activity. The current densities were also measured for Pt/C catalysts of E-Tek and Tanaka Precious Metal Co. The current densities for the different catalysts were similar, implying that catalytic activity depended directly on the ESA rather than charge transfer or electronic conductivity.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.296-296
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• 2013

Supercapacitor is a capacitor with extraordinarily high energy density, which basically consists of current collector, active material and electrolyte. Ruthenium oxide ($RuO_2$) is one of the most widely studied active materials due to its high specific capacitance and good electrical conductivity. In general, it is known that the coating of $RuO_2$ on nanoarchitectured current collector shows improved performance of energy storage device compared to the coating on the planar current collector. Especially, the surface structure with standing coaxial nanopillars are most desirable since it can provide direct paths for efficient charge transport along the axial paths of each nanopillars and the inter-nanopillar spacing allows easy access of electrolyte ions. However, well-known fabrication methods for metal or metal oxide nanopillars, such as the process using anodize aluminum oxide (AAO) templates, often require long and complicated nanoprocess.In this work, we developed relatively simple method fabricating indium tin oxide (ITO) nanopillars via sputtering. We also electrodeposited $RuO_2$ nanoparticles onto these ITO nanopillars and investigated its physical and electrochemical properties.