• 제목/요약/키워드: Active Metal

검색결과 868건 처리시간 0.029초

Fabrication of Hollow Metal Microcapsules with Mesoporous Shell Structure: Application as Efficient Catalysts Recyclable by Simple Magnetic Separation

  • Jang, Da-Young;Jang, Hyung-Gyu;Kim, Gye-Ryung;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3274-3280
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    • 2011
  • Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.

금속/세라믹 복합구조 선형 초음파 모터의 양방향 운동 (Bidirectional Motion of the Metal/Ceramic Composit Structure Linear Ultrasonic Motor)

  • 이재형;박태곤;김명호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.79-82
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    • 2002
  • In this paper, a single phase driven piezoelectric motor design was presented for linear motion. Two metal/ceramic composite actuators, a piezoelectric ring which was bonded to a metal endcap from one side, were used as the active elements of this motor. The motor was composed of a piezoelectric ceramic, a metal ring which has 4 arms, and a guider. Motors with 30.0[mm] and 35.0[mm] diameter were studied by finite element analysis and experiments. As results, the maximum speed of motor was obtained at resonant frequency. When the applied voltage of the motor increased, the speed was increased. Also, bidirectional motion of the motor was achieved by combining two motors which have different resonant frequency.

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The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

  • Kim, Kyoung-Ho;Kim, Min-Soo;Yeu, Tae-Whan
    • Bulletin of the Korean Chemical Society
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    • 제31권11호
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    • pp.3183-3189
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    • 2010
  • In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials. The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides. The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects; the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium ($Li^+$) ions. The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrode.

금속수소화물과 제올라이트의 혼성화물제조 및 수소화반응 (Preparation of Hybrid Materials with Zeolite and Metal Hydride, and Their Hydrogen Absorbing Properties)

  • 은원표;이공희;배장순;박찬교
    • 한국수소및신에너지학회논문집
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    • 제14권2호
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    • pp.146-154
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    • 2003
  • The hybrids of zeolite and metal hydride were prepared to improve the absorption properties as media for hydrogen storage. The zeolites which was deposited on the surface by metal hydride vapor showed excellent absorption properties and sodalite was proved to be better than zeolite-A in the reaction velocity and hydrogen storage capacity. This suggests the metal hydride could be used effectively as catalytic active material for enhancing the hydrogen storage in zeolite containing $\alpha$-cages and furthermore the hydrogen molecules have preference tobe occluded in their cavities containing $\alpha$-cages more effectively than that containing a and $\beta$-cages.

Enhancement of the surface plasmon-polariton excitation in nanometer metal films

  • Kukushkin, Vladimir A.;Baidus, Nikoly V.
    • Advances in nano research
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    • 제2권3호
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    • pp.173-177
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    • 2014
  • This study is aimed to the numerical modeling of the surface plasmon-polariton excitation by a layer of active (electrically pumped) quantum dots embedded in a semiconductor, covered with a metal. It is shown that this excitation becomes much more efficient if the metal has a form of a thin (with thickness of several nanometers) film. The cause of this enhancement in comparison with a thick covering metal film is the partial surface plasmon-polariton localized at the metal-semiconductor interface penetration into air. In result the real part of the metal+air half-space effective dielectric function becomes closer (in absolute value) to the real part of the semiconductor dielectric function than in the case of a thick covering metal film. This leads to approaching the point of the surface plasmon-polariton resonance (where absolute values of these parts coincide) and, therefore, the enhancement of the surface plasmon-polariton excitation. The calculations were made for a particular example of InAs quantum dot layer embedded in GaAs matrix covered with an Au film. Its results indicate that for the 10 nm Au film the rate of this excitation becomes by 2.5 times, and for the 5 nm Au film - by 6-7 times larger than in the case of a thick (40 nm or more) Au film.

중간재가 질화규소/스테인레스 스틸 접합체의 굽힘강도에 미치는 영향 (Effect of Interlayers on the Bending Strength of Silicon Nitride/Staineless Steel Joints)

  • 박상환;최영화;김태우
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.251-258
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    • 1996
  • The reactions between an active metal brazing alloy and interlayers together with the effects of interlayer type on the interfacial microstructure change were investiaged for silicon nitride/stainless steel joint. The bending strengths were measured for joints with Mo, Cu, Ni interlayer type of different thicknesses. It was found that the interlayer with a low yield strength value is effective to improve the bending strength of the Si3N4/stainless steel joint. The maximum joint strength obtained at room temperature for a laminated Cu/Mo interlayer was about 460 MPa. The combined use of Mo and thin Cu layer was found to be effective in enhancing the bending strength for the Si3N4/S.S.316 joint.

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Activity of Some Intracellular Enzymes of Three Virulent Erwinia sp. in Presence of Some Heavy Metal Salts

  • Saleh, Youssry-E.;Naguib, Mohamed-I.;Shehata, Nabil-E.
    • Archives of Pharmacal Research
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    • 제13권4호
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    • pp.298-305
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    • 1990
  • Based on equal number of cells, supplementation of 10$^{-6}$ M cadimium highly simulated the intracellular amylase. GCT, LDH as well as the glucose and erea content of E carotovora var, carotovaro cells. This was coupled with initiation of highly active GOT, CPK as well as accumulation of cholesterol in the cells. Lanthanum was less active and unable to initiate COT or CPK. Nickel was almost without effect though reduced LDH activity without initiating either enzyme or cholesterol production. Similar stiulations and/or initiations were observed, though to variable extents, when the same concentration of the three elements were supplied to E. carotovora var, citullis or E. toxica. The highest yield of amylase, GPT, GGT or glucose was obtained when E. carotovora var. carotovora was supplemented with Cd + Ni. The highest urea level was recorded in Erwinia carotovara var, cirullis, amended with Cd + La.

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최신의 고능률 브레이징 기술개발 동향 (Recent Study of Technical Development for High Efficient Brazing)

  • 유호천
    • Journal of Welding and Joining
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    • 제34권2호
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    • pp.36-45
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    • 2016
  • Recent developing tendency for technologies of high efficient brazing are studied by searching of NDSL, Science Direct, KIPRIS, PCT and so on. Active metal brazing, arc brazing, fluxless brazing, brazing with low melting point, reactive air brazing, laser brazing, laser droplet brazing are investigated. By optimal selecting of the above mentioned technologies, it needs to investigate an economical metallurgical design and the advanced brazing methods. To improve the embrittlement of intermetallic compound at brazing interface, it must be studied the inexpensive variant metals including nonmetals and the heat sources(MIG, TIG, Laser) by hybrid techniques.

유기 과산화물에 의한 메탄올 폭발 사례 연구 (A case study of methanol explosion by metal hydroperoxid)

  • 원유존;강경식
    • 대한안전경영과학회지
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    • 제7권5호
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    • pp.119-133
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    • 2005
  • In the June, 1991, there was the explosion in which methanol rectified column as a part of the new surface active agent's manufacturing processes. The type of explosion was estimated as the 'detonation'. The methanol rectified column was ruined, and broken pieces of the column were scattered within 900m. Also, there were victims such as the two deads and thirteen wounded persons. The cause of the explosion was heat explosion by being concentrated locally from 0.1% to several tens% of supply fluid at Metal Hydroperoxide, which was produced by methanol and hydrogen peroxide used as the bleach of surface active agent, during the operation stoppage process of methanol rectified column.

투명 ZnO를 활성 채널층으로 하는 박막 트랜지스터 (Thin Film Transistor with Transparent ZnO as active channel layer)

  • 신백균
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권1호
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    • pp.26-29
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    • 2006
  • Transparent ZnO thin films were prepared by KrF pulsed laser deposition (PLD) technique and applied to a bottom-gate type thin film transistor device as an active channel layer. A high conductive crystalline Si substrate was used as an metal-like bottom gate and SiN insulating layer was then deposited by LPCVD(low pressure chemical vapour deposition). An aluminum layer was then vacuum evaporated and patterned to form a source/drain metal contact. Oxygen partial pressure and substrate temperature were varied during the ZnO PLD deposition process and their influence on the thin film properties were investigated by X-ray diffraction(XRD) and Hall-van der Pauw method. Optical transparency of the ZnO thin film was analyzed by UV-visible phometer. The resulting ZnO-TFT devices showed an on-off ration of $10^6$ and field effect mobility of 2.4-6.1 $cm^2/V{\cdot}s$.