• Title/Summary/Keyword: Activation energies

Search Result 534, Processing Time 0.025 seconds

An Experimental Study on Effect of Plasma for Exhaust Emissions in Small High-Speed Diesel Engine (소형 고속 디젤엔진의 배기 배출물에 미치는 플르즈마의 영향에 관한 실험적 연구)

  • 백태실
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.23 no.6
    • /
    • pp.755-760
    • /
    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conver-sion to $NO_2$ and /or $HNO_3$ due to high activation energies for NO oxidation and reduction, NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

  • PDF

A Rheological Study of Topical Vehicles

  • Min, Shin-Hong;Rhee, Shanghi;Kim, Yong-Bae
    • Archives of Pharmacal Research
    • /
    • v.2 no.2
    • /
    • pp.89-97
    • /
    • 1979
  • To find out the rheological characteristics of several pharamaceutical semisolid products, experiments were carriedout over the temperature range of 20 to 30 .deg.C . From continuous shear rheograms obtained with a Ferranti-Shirley cone and plate viscometer, loop area, shear rates, ryild values, limiting viscosities and activation energies were calculated. The systems were metastable and their viscosity decreased with time. As the temperature was raised, products studied showed a decrease in viscosity and yield value.

  • PDF

An Experimental Stduy on NOx Reduction in Exhaust Gas from Diesel Engine with Plasma (플라즈마를 이용한 디젤엔진 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 조기현;황의현
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.7 no.8
    • /
    • pp.83-90
    • /
    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

  • PDF

On Crystallization of Hadong Kaolin Granulated Cylindrically Treated with Aqueous Sodium Hydroxide Solution (원주형으로 성형된 하동고령토의 수산화나트륨 수용액 처리에 의한 결정의 변화)

  • 김면섭
    • Journal of the Korean Ceramic Society
    • /
    • v.15 no.1
    • /
    • pp.21-27
    • /
    • 1978
  • Hadong Kaolin (Halloysite) was granulated cylindrically and treated with 1N aqueous sodium hydroxide solution for 6-48 hrs at 60-10$0^{\circ}C$. The crystalling structure of surface of the products was studied by X-ray powder diffraction method. The reaction rate of halloysite to sodium A zeolite showed a gradual decrease from surface to inner layer. At the surface layer, the reaction mechanism was observed as first order consecutive reaction as follows: halloysitelongrightarrowamorphous aluminosilicatelongrightarrowsodium A zeolitelongrightarrowhydroxysodalite By applying the above reaction mechanism, the rate constants and activation energies was measured.

  • PDF

Effects of GN Contents on Thermal Decomposition of Epoxy Resin System (GN 함량에 따른 에폭시 수지계의 열분해 특성)

  • 안현수;심미자;김상욱
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1997.11a
    • /
    • pp.389-392
    • /
    • 1997
  • Glutaronitrile(GN) was introduced to diglycidyl ether of bisphenol A(DGEBA)/ 4,4'-methylene dianiline(MDA) system to improve toughness. Effects of GN contents on thermal decomposition of epoxy resin system were investigated. To study the characteristics of thermal decomposition, thermo-gravimetric analysis(TGA) and Kissinger equation were used. Thermal degradation temperatures were about 365$^{\circ}C$ regardless of GN contents. Activation energies of thermal decomposition in epoxy resin system were almost constant below 10 phr and decreased above 15 phr.

  • PDF

Effects of Surface States on the Transconductance Dispersion and Gate Leakage Current in GaAs Metal - Semiconductor Field-Effect Transistor (GaAs Metal-Semiconductor Field-Effect Transistor에서 표면 결함이 소자의 전달컨덕턴스 분산 및 게이트 표면 누설 전류에 미치는 영향)

  • Choe, Gyeong-Jin;Lee, Jong-Ram
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.38 no.10
    • /
    • pp.678-686
    • /
    • 2001
  • Origins for the transconductance dispersion and the gate leakage current in a GaAs metal semiconductor field effect transistor were found using capacitance deep-level transient spectroscopy (DLTS) measurements. In DLTS spectra, we observed two surface states with thermal activation energies of 0.65 $\times$ 0.07 eV and 0.88 $\times$ 0.04 eV and an electron trap EL2 with thermal activation energy of 0.84 $\times$ 0.01 eV. Transconductance was decreased in the frequency range of 5.5 Hz ~ 300 Hz. The transition frequency shifted to higher frequencies with the increase of temperature and the activation energy for the change of the transition frequency was determined to be 0.66 $\times$ 0.02 eV. From the measurements of the gate leakage current as a function of the device temperature, the forward and reverse currents are coincident with each other below gate voltages lower than 0.15 V, namely Ohmic behavior between gate and source/drain electrodes. The activation energy for the conductance of electrons on the surface of MESFET was 0.63 $\times$ 0.01 eV. Comparing activation energies obtained by different measurements, we found surface states H1 caused the transconductance dispersion and the fate leakage current.

  • PDF

Thermal Deintercalation of Ethylammonium-Aluminosilicate Intercalates with Various Layer Charges

  • Choy, Jin-Ho;Choi, Young-Joon;Han, Yang-Su
    • The Korean Journal of Ceramics
    • /
    • v.1 no.1
    • /
    • pp.40-44
    • /
    • 1995
  • Ethylammonium-layered aluminosilicates intercalates were prepared by ion exchange reaction between the layered silicates with different layer changes density of 0.32∼0.41 e per unit formula and ethylammonium chloride. A kinetic study on the thermal deintercalation of the ethylammonium-layered silicate intercalates was carried out by range of 350℃ to 480℃ (heating rate of 10℃/min). Based on the Ozawa's method, the activation energies of the thermal deintercalation reaction were estimated as 171.2∼133.0 kJ/mol, which increase linearly with the layer charge densities.

  • PDF

Optical and Dielectric Properties of Reduced SrTiO3 Single Crystals

  • Kang, Bong-Hoon
    • Journal of the Korean Ceramic Society
    • /
    • v.48 no.4
    • /
    • pp.278-281
    • /
    • 2011
  • The optical band gap energy for $SrTiO_3$ by reduction at high temperature was 3.15 eV. The reflectivity of reduced $SrTiO_3$ single crystals showed little variation, however, the reflectivity by the reduction condition had no effect. For the phonon mode at about 790 $cm^{-1}$, a blue-shift took place upon $N_2$ reduction and the decreased. However, a red-shift took place upon a $H_2-N_2$ reduction and the increased at the same phonon mode. With decreasing temperature the dielectric constant decreased rapidly. The thermal activation energies were 0.92-1.02 eV.

Sintering Behaviors of ITO Ceramics with Additions of TiO$_2$ (TiO$_2$첨가에 따른 ITO 세라믹스의 소결 거동)

  • 정성경;김봉철;장세홍;김정주
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.4
    • /
    • pp.347-354
    • /
    • 1998
  • Densification and grain growth behaviors of ITO ceramics were investigated as a function of TiO2 ad-ditions. TiO2 addition led to inhibition of the grain growth and promotion of the densification of ITO ceram-ics. From the microstructure observation it was found that the crack-like voids which were formed in pure ITO specimens decreased with increase of TiO2 additon. The grain growth exponent(n) was measur-ed to be 4 for pure ITO 3 for TiO2-doped ITO specimens respectively. It was supposed that the grain boun-dary migration of pure ITO ceramics was controlled by the pores which were moved by surface diffusion. On the contrary the grain boundary migration of TiO2-doped ITO specimens was depressed by solute drag effect. The activation energies for grain growth were measured to be 1013 kJ/mol for pure ITO ceramics and 460kJ/mol for TiO2-doped ITO specimens respectively.

  • PDF

Electrical Properties of Ultrafine $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ Powders Prepared by Glycine Nitrate Process for the High Efficient Solid Oxide Fuel Cell Applications

  • Lee, Kang-Ryeol;Park, Sung
    • The Korean Journal of Ceramics
    • /
    • v.7 no.1
    • /
    • pp.6-10
    • /
    • 2001
  • Ultrafine $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ solid solution powders synthesized by the glycine-nitrate process, with specific surface areas of $19-23\;\textrm{m}^2$/g were sintered at $1500^{\circ}C$ for various sintering times and then their electrical characteristics were investigated using AC impedance and four-point probe measurements. The electrical resistivity of the sintered $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ bodies showed the minimum value at the sintering time of 10 hrs. The minimum total resistivity of the $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ bodies sintered at $1500^{\circ}C$ for 10 hrs seems to result from the lowest activation energy for the electrical resistivity by the combination between the activation energies for the resistivities at the grain interior and grain boundary.

  • PDF