• 한국인쇄학회지
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• 제6권1호
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• pp.59-66
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• 1988

One of the rising problems in the field of environmental engineering is the eutrophic phenomenon which appears in the closed water basin. This study is the elimination orthophosphate by adsorption, which is indispensible nutritive element for eutrophication Ziriconium(IV) oxide hydrate-activatedcarbon complex. which has excellent adsorptivity for orthophosphate and can easily be reused after desorption process has been made and used as adsorbents. The main purpose of this study is to obtain intraparticle diffusivity which is basic data for the design of adsorption operation the experimental results were as follows. 1. Optimum condition which gave maxinum adsorption of orthophosphate was ph5 2. Equilibrium adsorption showed good consistency with Freundlich type. q=10.80C1/2.08 3. Pore diffusivity and surface diffusivity obtained the kinetic experiment of batch adsorption were respectivity 5.38 and 2.06 ($\textrm{cm}^2$/sec)

• 도시과학
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• 제8권2호
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• pp.19-23
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• 2019

With the continuous progress of modern science and technology and the rapid development of economy, with the continuous development of society, the treatment of industrial and domestic sewage has become a hot concern. Toxic substances and non-degradable pollutants in wastewater also have a great impact on the environment. This paper mainly expounds the current environmental situation and the adsorption mechanism of activated carbon. And the application and development of activated carbon adsorption in wastewater.

• 한국세라믹학회지
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• 제40권5호
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• pp.468-474
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• 2003

안정화 PAN(Polyacronitrile)계 섬유를 이용하여 물리적인 방법과 화학적인 방법으로 활성탄소섬유(Activated Carbon Fibers)를 제조하고, 그 특성을 비교평가 하였다. 본 연구에서는 안정화 PAN계 섬유를 수증기 및 $CO_2$를 이용한 물리적 활성화와 KOH를 이용한 화학적 활성화에 의해 여러 등급의 활성탄소섬유를 제조하였고, 비표면적, 요오드흡착량, 미세구조, 세공구조 등을 측정하였다. 물리적 활성화 방법에는 수증기와 $CO_2$가 사용되었는데, 수증기활성화의 경우 99$0^{\circ}C$의 활성화 온도에서 1635 m$^2$/g의 비표면적을 나타내었고, $CO_2$ 활성화의 경우에는 99$0^{\circ}C$의 활성화 온도에서 671 m$^2$/g의 비표면적을 나타내었다. KOH를 이용한 화학적 활성화 방법에서는 KOH와 안정화 PAN계 탄소섬유의 비가 1.5 : 1인 경우 90$0^{\circ}C$의 활성화 온도에서 3179 m$^2$/g의 비표면적을 나타내었다. 물리적 활성화와 화학적 활성화로 제조된 활성탄소섬유의 질소흡착등온선의 결과로 보면 type I의 형태와 type I에서 type II로의 전이형태의 등온흡착곡선을 나타내었다.

• 한국대기환경학회지
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• 제19권6호
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• pp.689-699
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• 2003

This study was to examine characteristics of treating toluene vapor, which gets to be problematic due to its harmful carcinogenicity and mass generation from various sources, through a biological treatment facility which is environment-friendly and adopts a high-efficient and low-cost clean technology. In order to identify whether Alnus Firma Fruit (AFF) can be used as a media for a bioreactor, its utility and basic operating factors, a study was conducted on pressure drop, supply of nutrient substances and retention time which are operating factors of a biofilter, and eliminating characteristics were compared between AFF and the conventional biological activatedcarbon (BAC) widely used as filter media. In the case of AFF, the initial microbial deposits was 2.3${\times}$10$^{7}$ CFU/g dry AFF, which represents the initial microbial density higher than the case of BAC showing 5.5${\times}$10$^{6}$ CFU/g dry BAC And it took about 2 weeks to acclimate until its eliminating rate got to be increased over 90%. As a result of comparing pressure loss taking place with the lapse of time between BAC and AFF, after 130 days passed at SV 25h$^{-1}$ , BAC showed that its eliminating efficiency had a tendency to drop greatly due to a great pressure loss (0.53\longrightarrow54.7 mm$H_2O$/m) caused by an excess of biomass as accumulated. On the other hand. AFF showed that the pressure drop was 0.53 mm$H_2O$/m, about 2 times as much as the initial pressure loss of 0.4 mm$H_2O$/m, which represents no great change in the pressure loss, and its eliminating efficiency was also shown to be continuously high. Therefore, when AFF was used as a filler for a biological treatment facility, a biological filter enabling improvement of the purifying efficiency to be promoted could be provided, and moreover, the pressure loss was so small that the filler replacement cycle or the back flushing cycle could be extended. So, even in terms of the operating cost, it was identified to be an economical filler When an inorganic material was used as a filler, the biofilters performance acted sensitively on whether nutrient substances were supplied or not. In the case of AFF with low adsorptivity, addition of ethyl-alcohol increased the solubility of toluene, and consequently, biodegradation got to be actively made by microbes, and thus, its eliminating rate could be increased. As the flow velocity and the inflow concentration got to be more increased, its eliminating rate got to be lower, and particularly, an increase in the flow velocity made its eliminating rate drop more greatly than an increase in the concentration.