• 제목/요약/키워드: Acrylonitrile Butadiene Styrene (ABS)

검색결과 111건 처리시간 0.026초

PC/ABS 블렌드의 사출조건에 따른 모폴로지 및 기계적 성질 변화에 관한연구 (Effect of Injection Molding Conditions on the Morphology and Mechanical Properties of PC/ABS Blends)

  • 김형수
    • 유변학
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    • 제8권3_4호
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    • pp.177-186
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    • 1996
  • 압출가공으로 제조된 Polycarbonate(PC)/Acrylonitrile-Butadiene-Styrene(ABS) 블 렌드의 사출조건에 따른 모폴로지와 기계적 성질의 변화와 그 상관관계를 고찰하였다. 사출 온도와 금형온도가 높아질수록 분산상간의 coalescence 현상이 활발히 진행되었으며 이러한 모폴로지 변화로 인하여블렌드의 인장강도 굴곡강도 그리고 충격강도 등의 기계적 성질이 급격히 저하되었다. 사출온도와 금형온도의 증가에 따른 coalescence의 심화는 높은 온도에 서 연속상과 분산상의 점도가 저하되어 분산상 사이에 존재하는 연속상 성분의 배출이 보다 용이하게 이루어져 나타난 현상으로 설명된다. 실용적으로 특정한 상용화제가 투입되지 않 는 PC/ABS 블렌드를 사출공정을 거쳐 제품을 생산할 경우에는 급격한 모폴로지와 물성변 화가 일어나지 않는 범위에서 사출온도를 유지하는 것이 제품의 품질관리 측면에서 매우 중 요하다.

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Effects of Molecular Weight of PC on Mechanical Properties of PC/ABS Blends using High-Shear Rate Processing

  • Lee, Eun Ju;Park, Hee Jung;Kim, Se Mi;Lee, Seung Goo;Lee, Kee Yoon
    • Korean Chemical Engineering Research
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    • 제56권3호
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    • pp.343-348
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    • 2018
  • Each of the two polycarbonates (PC) of different molecular weights was blended with acrylonitrile-butadiene-styrene (ABS) under high-shear rate processing to afford PC/ABS. Sizes of ABS dispersed phases and mechanical properties of PC/ABS blends were investigated and high-shear rate processing of PC/ABS was carried out by changing screw speed and processing time. Prepared specimens were examined by scanning electron microscope (SEM) to observe morphology changes. Sizes of ABS dispersed phases in PC/ABS blends were observed to decrease gradually as screw speeds increased. Tensile strengths and elongations of specimens were investigated by universal testing method (UTM) to study the influence of molecular weight of PC exerting on PC/ABS blends. As a result, PC1/ABS blends (PC1: higher molecular weight PC) exhibited more strengthened properties than PC2/ABS (PC2: lower molecular weight PC). The tensile strength of PC1/ABS showed an increasing tendency when the screw speed increased, and the elongation did not show a significant decrease, but increased slightly with increasing shear time at a constant screw speed of 1000 rpm.

Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS

  • Nguyen, Congtranh;Kim, Jin-Hwan
    • Macromolecular Research
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    • 제16권7호
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    • pp.620-625
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    • 2008
  • A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.

가전설비용 절연재의 유전열 분석 (The Dielectric Analysis of Insulators for Home Appliances)

  • 정진수;정종욱;이건호;배석명
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.206-207
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    • 2006
  • This paper describes the dielectric analysis of several insulators for home appliances. The dielectric characteristics of ABS(acrylonitrile butadiene styrene) were tested in relative permittivity, dielectric loss($tan{\delta}$) and specific resistance and compared with those of the other 4 insulators of PE(polyethylene) series. As a result, the relative permittivity of only the ABS slightly decreased with temperature. In the case of the tan6, the ABS showed higher dielectric loss than the other insulators but more excellent thermal performance. In addition, its changing pattern in specific resistance was very similar to that in $tan{\delta}$.

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광센서를 이용한 로터리 보빈용 단채널 밑실 감지기 개발에 관한 연구 (Development of Single-Channel Thread Sensor for Rotary Bobbin by Optical Sensing)

  • 정용섭;조장현;변지수
    • 대한기계학회논문집A
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    • 제38권10호
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    • pp.1085-1091
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    • 2014
  • 광센서를 이용한 로터리 밑실 감지기를 개발하여 출력 변화에 따른 신호 특성을 분석하였다. 로터리 보빈과 결합되는 광센서 마운트는 ABS(acrylonitrile-butadiene-styrene) resin으로 3D 프린터를 이용하여 형상화하고 로터리 밑실 감지 상태에 따른 출력 변화를 분석하였다. 로터리 밑실 상태에 따라 상대적으로 변화하는 광신호는 충분한 출력신호대비가 관측되어 안정된 제어가 가능하였으며, 이를 통하여 로터리 밑실의 끊김이나 풀림이 효과적이고 신속하게 감지되고 제어되는 방직시스템의 개발이 가능하여 고가원단 손실 감소의 효과를 기대할 수 있다.

열변형 해석을 이용한 냉장고 수축팽창 소음저감 (Reduction of contraction and expansion noise of refrigerator using thermal deformation analysis)

  • 박성규;김원진
    • 한국음향학회지
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    • 제38권3호
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    • pp.344-351
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    • 2019
  • 본 연구에서는 수축 및 팽창 소음 발생 메커니즘을 분석하고, 냉장고 운전 중에 소음발생 빈도를 줄이기 위한 효과적인 방법을 제안하였다. 냉장고의 수축팽창음 발생 시에 제품의 품질비용 상승에 영향을 주기 때문에 저감이 필요하다. 먼저, 무향실에서 측정된 음압 신호를 이용하여 주파수 스펙트럼 분석을 수행하여 소음의 특성과 발생 빈도를 분석하였다. 둘째, 열변형 해석을 수행하여 소음원의 위치를 예측했다. 분석결과에서 가장 큰 열변형은 냉동실의 왼쪽 내부 케이스의 중간에서 발생하였다. 또한 음원 위치의 가속도 레벨을 평가한 결과, 소음을 발생시키는 내부 부품이 냉동실의 세 번째 선반임을 알 수 있었다. 냉장고의 중앙 ABS(Acrylonitrile Butadiene Styrene) 두께 증가에 의한 열변형 저감을 통하여 수축팽창음을 저감할 수 있는 방법을 제안하였다.

고속전단에 의한 폴리카보네이트/ABS 블렌드의 열분해 및 기계적 특성 연구 (Thermal Decomposition and Mechanical Properties of Polycarbonate/ABS Blends Prepared by High Shear Rate Processing)

  • 유재정;용다경;이한기;김대식;이형일;김선홍;이기윤;이승구
    • 폴리머
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    • 제38권4호
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    • pp.471-476
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    • 2014
  • Polycarbonate(PC)/acrylonitrile-butadiene-styrene(ABS) 블렌드를 고속전단압출성형기로 1000 rpm 이상의 스크류 속도로 압출하여 전단속도와 전단시간에 따른 PC/ABS 블렌드의 열분해와 기계적 특성을 조사하였다. 고속전단 조건으로 스크류 회전속도를 1000에서 3000 rpm 범위에서 조절하였고, 전단부하시간은 10에서 40초로 변화를 주었다. 그 결과, 2000 rpm 이상의 고속전단을 통해 얻어진 시편의 경우, 고분자의 열분해의 발생으로 열분해 시작 온도가 낮아졌다. 스크류 회전속도와 전단부하시간에 따라 열분해에 의하여 시편의 인장강도와 신율이 낮아지는 결과를 얻었다. 이러한 PC/ABS 블렌드의 고속전단 조건에 따라 기계적 특성이 크게 변화하였으며 특히, 신율이 고속전단에 크게 영향을 받았다.

다중벽 탄소나노튜브를 함유한 PC/ABS 복합재의 마모 특성 및 다중벽 탄소나노튜브의 유출 평가 (Evaluation of MWCNT Exposure and the Wear Characteristics of MWCNT-containing PC/ABS Composites)

  • 이현우;김경식;이재혁;김효섭;김재호;오동훈;류상효;장영찬;김재현;이학주;김광섭
    • Tribology and Lubricants
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    • 제30권5호
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    • pp.278-283
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    • 2014
  • Carbon nanotubes (CNTs) are used in various composite materials to enhance electrical, thermal and mechanical properties of composite materials. In this study, we investigate the wear characteristics of polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) blends containing multi-walled carbon nanotubes (MWCNTs). PC/ABS blends are commonly used in many industrial applications such as cellular phones and display cases and MWCNTs have been added to the PC/ABS blends to improve their electromagnetic interference shielding (EMS). We performed wear tests on PC/ABS blends containing MWCNTs under reciprocating linear sliding conditions with chrome steel balls as a counterpart material. The normal loads were 10, 30, 50, 70, 100 N, the sliding speed was 10 mm/s, the stroke length was 15 mm, and the tests lasted 900 s. The MWCNTs included in the PC/ABS blends lower the wear volume and friction coefficient of the composites. We analyzed the wear debris collected from the composites during the tests in terms of the MWCNT concentration using inductively coupled plasma optical emission spectroscopy. The results show that the quantity of MWCNTs in the debris is proportional to the concentration of MWCNTs in the composite, indicating that the exposure of the MWCNTs to environments by wear could be increased with their concentration in the composite.

FDM 쾌속 조형기를 통해 만들어진 ABS 파트를 이용한 직접 정밀 주조에 대한 연구 (A Study of Using FDM/ABS Parts as Wax-Pattern Substitutes in the Investment Casting Process)

  • 최두선;신보성;김주한
    • 한국정밀공학회지
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    • 제16권10호
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    • pp.59-67
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    • 1999
  • The lead time for new products is very limited in the current manufacturing processes, therefore the Rapid Prototyping process has been introduced and generally used in the industry. Fused Deposition Manufacturing (FDM) is one of the most common methods in this field. In the FDM process, the patterns are made of Wax of ABS and ABS shows better quality of the patterns. To date, the FDM/ABS patterns are used in investment casting for making silicon moulds to produce was patterns because it is very difficult to dewax FDM/ABS directly. The aim of this paper was to propose a feasibility of using FDM/ABS parts as wax-pattern substitutes in the investment casting process. The effects of casting conditions, such as pre-heat temperature and casting temperature, are provided. Comparisons with the conventional investment casting processes using the wax-patterns under the same prototype are made. Lead-time and saving cost are discussed in using FDM/ABS parts as was-pattern substitutes compared with the products from other rapid prototype systems.

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Optimization of FSW of Nano-silica-reinforced ABS T-Joint using a Box-Behnken Design (BBD)

  • Mahyar Motamedi Kouchaksarai ;Yasser Rostamiyan
    • Advances in nano research
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    • 제14권2호
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    • pp.117-126
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    • 2023
  • This experimental study investigated friction stir welding (FSW) of the acrylonitrile-butadiene-styrene (ABS) T-joint in the presence of various nano-silica levels. This study aim to handle the drawbacks of the friction stir welding (FSW) of an ABS T-joint with various quantity of nanoparticles and assess the performance of nanoparticles in the welded joint. Moreover, the relationship between the nanoparticle quantity and FSW was analyzed using response surface methodology (RSM) Box-Behnken design. The input parameters were the tool rotation speed (400, 600, 800 rpm), the transverse speed (20, 30, 40 mm/min), and the nano-silica level (0.8, 1.6, 2.4 g). The tensile strength of the prepared specimens was determined by the universal testing machine. Silica nanoparticles were used to improve the mechanical properties (the tensile strength) of ABS and investigate the effect of various FSW parameters on the ABS T-joint. The results of Box-Behnken RSM revealed that sound joints with desired characteristics and efficiency are fabricated at tool rotation speed 755 rpm, transverse speed 20 mm/min, and nano-silica level 2.4 g. The scanning electron microscope (SEM) images revealed the crucial role of silica nanoparticles in reinforcing the ABS T-joint. The SEM images also indicated a decrease in the nanoparticle size by the tool rotation, leading to the filling and improvement of seams formed during FSW of the ABS T-joint.