• Ocean Systems Engineering
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• v.12 no.2
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• pp.225-245
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• 2022

More and more shipping containers are falling into the sea due to bad weather. Containers lost at sea negatively affect the shipping line, the trader and the consumer, and the environment. The question of locating and recovering dropped containers is a challenging engineering problem. Model-testing of small-scaled container models is proposed as an efficient way to investigate their falling trajectories to salvage them. In this study, we first build a standard 20-ft container model in SOLIDWORKS. Then, a three-dimensional (3D) geometric model in the STL (Standard Tessellation Language) format is exported to a Stratasys F170 Fused Deposition Modeling (FDM) printer. In total, six models were made of acrylonitrile styrene acrylate (ASA) and printed for the purpose of testing. They represent three different loading conditions with different densities and center of gravity (COG). Two samples for each condition were tested. The physical models were dropped into the towing tank of University of New Orleans (UNO). From the experimental tests, it is found that the impact of the initial position after sinking can cause a certain initial rolling velocity, which may have a great impact on the lateral displacement, and subsequently affect the final landing position. This series of model tests not only provide experimental data for the study of the trajectory of box-shape objects but also provide a valuable reference for maritime salvage operations and for the pipeline layout design.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.3
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• pp.421-431
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• 2023

Recently, the destructive power of typhoons is continuously increasing due to the influence of global warming. In a situation where the installation of floating wind turbines is increasing around the world, concerns about the huge loss and collapse of floating offshore wind turbines due to strong typhoons are deepening. Regarding to the safe operation of the floating offshore wind turbine, the development of a new type of disconnectable mooring system is required. A new fairlead chain stopper considered in this study is devised to more easily attach or detach the floating offshore wind turbine with mooring lines comparing to other disconnectable mooring apparatuses. In order to investigate the structural safety of the initial design of fairlead chain stopper that can be applied to MW-class floating type offshore wind turbine, scale-down structural models were produced using a 3-D printer and structural tests were performed on the models. For the structural tests of the scale-down models, tensile specimens of acrylonitrile butadiene styrene material that was used in the 3-D printing were prepared, and the material properties were evaluated by performing the tensile tests. The finite element analysis of fairlead chain stopper was performed by applying the material properties obtained from the tensile tests and the same load and boundary conditions as in the scale-down model structural tests. Through the finite element analysis, the structural weak parts on the fairlead chain stopper were reviewed. The structural model tests were performed considering the main load conditions of fairlead chain stopper, and the test results were compared to the finite element analysis. Through the results of this study, it was possible to experimentally verify the structural safety of the initial design of fairlead chain stopper. It is also judged that the study results can be usefully used to improve the structural strength of fairlead chain stopper in a detailed design stage.

• Design & Manufacturing
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• v.18 no.2
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• pp.57-63
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• 2024

In this study, the recyclability of commonly used PP (polypropylene) and ABS (acrylonitrile butadiene styrene) was evaluated by molding test specimens from mixture of virgin and shredded material, followed by measuring their strength properties, Experiments were conducted o two type of PP (transparent and non-transparent) and two types of ABS (white and yellow). Test specimens for each resin were prepared with shredded material ratios ranging from 10% to 50% in 10% increments. Changes in tensile strength, elastic modulus, and elastic limit were analyzed based on the mixing ratio of the shredded material. The experimental results demonstrated that the strength properties of all the resins remained consistent within a certain range, even with increasing proportions of shredded material. For transparent PP, the tensile strength ranged from 30.87± MPa, the elastic modulus from 1.23±0.04 GPa, and the elastic limit from 19.17±0.44%. Non-transparent PP exhibited a tensile strength ranging from 27.71±0.58 MPa, an elastic modulus from 1.03±0.06 GPa, and an elastic limit from 17.35±0.41%. For ABS, white ABS had a tensile strength of 39.42±0.28 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 36.76±0.25%. Yellow ABS showed a tensile strength of 39.25±0.78 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 37.14±0.23%, with values remaining consistent within this range. Based on these results, it was confirmed that the mechanical properties of the resins used in this study do not change significantly when mixed with recycled shredded material, indicating excellent mechanical recyclability.

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.266-271
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• 2014

The effects of antioxidants on the properties of Polycarbonate/Acrylonitrile-Butadiene-Styrene(PC/ABS) blends were studied for the functions of the screw speed and loaded duration of high shear rate processing in order to investigate the degradation for PC/ABS blends. Tris-(2,4-di-tert-butyl-phenyl phosphate) (A1) and Bis(2,4-dicumylphenyl) pentaerythritol diphosphite (A3) as phosphite antioxidants and Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate (A2) as a phenolic antioxidant are used. The thermal properties were detected by TGA and severely decreased, after the processing. The stress-induced and thermal degradation for PC/ABS blends with the antioxidant A3 was retarded better than the others. By using UTM, the mechanical properties also showed individually decreased according to the antioxidants, after the processing, especially, the elongations showed considerable decline behaviors, while the tensile strengths of PC/ABS blends changed very little. For example, in the operating conditions of 1000rpm of screw speed and 20 seconds of loaded period, the elongations decreased from 148% before the processing, to 91.6% with the A1, to 63% with the A2 and to 131% with the A3 after the processing, respectively. In order to get the morphological properties, the size distributions of the dispersed phases for PC/ABS were investigated by SEM analysis and tended to decrease, as the screw speed and loaded period of the processing increased. Therefore, we confirmed that the antioxidant A3 was the best of all of three to inhibit the stress-induced degradation of PC/ABS blends during the high shear rate processing.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.11
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• pp.771-780
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• 2014

In this study, the various organic supports (i.e., silicone, acrylonitrile-butadiene-styrene, epoxy, and, butadiene rubber) with great sorption capacity of organic contaminants were chosen to develop nano-ZnO/organic composites (NZOCs) and to prevent the detachment of nano-ZnO particles. The water resistance of the developed NZOCs were evaluated, and the feasibility of the developed NZOCs were investigated by evaluating the removal efficiency of 1,1,2-trichloroethylene (TCE) in the aqueous phase. Based on the results from water-resistance experiments, long-term water treatment usage of all NZOCs was found to be feasible. According to the FE-SEM, EDX, and imaging analysis, nano-ZnO/butadiene rubber composite (NZBC) with various sizes and types of porosity and crack was measured to be coated with relatively homogeneously-distributed nano-ZnO particles whereas nano-ZnO/silicone composite (NZSC), nano-ZnO/ABS composite (NZAC), and nano-ZnO/epoxy composite (NZEC) with poorly-developed porosity and crack were measured to be coated with relatively heterogeneously-distributed nano-ZnO particles. The sorption capacity of NZBC was close to 60% relative to the initial concentration, and this result was mainly attributed to the amorphous structure of NZBC, hence the hydrophobic partitioning of TCE to the amorphous structure of NZBC intensively occurred. The removal efficiency of TCE in aqueous phase using NZBC was close to 99% relative to the initial concentration, and the removal efficiency of TCE was improved as the amount of NZBC increased. These results stemmed from the synergistic mechanisms with great sorption capability of butadiene rubber and superior photocatalytic activities of nano-ZnO. Finally, the removal efficiency of TCE in aqueous phase using NZBC was well represented by linear model ($R^2{\geq}0.936$), and the $K_{app}$ values of NZBC were from 2.64 to 3.85 times greater than those of $K_{photolysis}$, indicating that butadiene rubber was found to be the suitable organic supporting materials with enhanced sorption capacity and without inhibition of photocatalytic activities of nano-ZnO.

• Analytical Science and Technology
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• v.25 no.3
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• pp.178-189
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• 2012

As phthalates classified as toxic to reproduction category 2 and endocrine disrupting chemicals were more strictly regulated as Substances of Very High Concern (SVHC) for authorization in under EU REACH and considered as priority substances in RoHS II, standardization of phthalate testing method is now being proposed in IEC 62321 of IEC TC 111 and the 2nd revision of KS M 1991 is also finished. In order to assist standardization activities related to phthalating testing, solvent extraction part of existing national standards were compared and verified. Recovery of DEHP (diethylhexyl phthalate) from PVC (polyvinyl chloride) by Soxhlet extraction increased in the order of methanol, toluene, dichloromethane and hexane from 46.9% to 95.3% as measured by GC-MS. Optimum extraction time was verified to be 6 hours using hexane. Recovery of DBP (dibutyl phthalate), BBP (butylbenzyl phthalate), and DEHP from different matrixes such as PVC, nitro cellulose, ABS (acrylonitrile butadiene styrene). and EPDM(ethylene propylene diene monomer) rubber were evaluated to be more than 90% up to 99%. The detection limits of phthalates in solvent extraction followed by GC-MS analysis were 0.08~0.3 ${\mu}g/mL$ in solution and 8~30 mg/Kg in polymeric samples. GC-MS analyses of phthalates were carried out using different solvent extraction based on the EN 14372, ASTM D 7083, Japanese test method (MHLW 0906-4) and KS M 1991, proving that equivalent recoveries ranging from 98%~99% were obtained. DBP and DEHP were detected in three consumer products such as a child toy, a power cable and manicure with the amount of 22~1,910 mg/kg.

• Journal of the Korean Electrochemical Society
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• v.16 no.2
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• pp.91-97
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• 2013

Solid polymer electrolyte films are prepared by ultraviolet radiation in the mixtures of an ionic liquid salt (1-ethyl-3-methylimidazolium tetrafluoroborate, $EMIBF_4$) and solvent (acetonitrile (ACN) or propylene carbonate(PC)), and an oligomer (poly(ethylene glycol)diacrylate, PEGDA, 45-60 wt.%). Electrochemical properties of activated carbon supercapacitors adopting the solid polymer electrolyte films as a separator are also examined by cyclic voltammetry and impedance measurement techniques. As a result, the supercapacitor adopting the PEGDA as much as 45 wt.% exhibits a superior capacitance of $46Fg^{-1}$ at $20mVs^{-1}$. It seems that this is due to fast kinetics of ion conduction by sufficient film flexibility, which can be allowed by comparatively weak ultraviolet curing of small anount of the PEGDA.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.11
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• pp.233-238
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• 2020

Although the interest in NBR has been increasing due to the recent developments of the aerospace sector, there are few reports on HNBR's aeronautical oil, particularly evaluations of the accelerated life of harsh factors. In this study, the tensile strength was adopted as a performance evaluation factor to evaluate the accelerated life of HNBR used in the aviation field. The accelerated stress factor affecting the performance-aging characteristics was defined as temperature. The acceleration stress factor was determined to be temperature, and the result of measuring the tensile strength change over time. The sample for the acceleration condition was taken out of the oven for a certain period and left at room temperature for 24 hours. The dumbbell type 3 specimens were manufactured according to the standard specified in KS M 6518 and were measured the tensile strength, a factor in accelerated life evaluations. The activation energy was 0.895, and the shape parameter was 1.152 using the Arrhenius model. The characteristic life obtained from the tensile strength of the HNBR specimen immersed in aviation oil at 20℃ was 272,256 hours; the average life was 258,965 hours, and the B10 life was 38,624 hours.

• Analytical Science and Technology
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• v.26 no.4
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• pp.245-255
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• 2013

Identification of paint on victim's clothing and a vehicle are valuable for forensic examination when investigating hit-and-run accidents. Automotive paints on clothes are used to prove a victim caused by traffic accident and to identify a suspected vehicle. The comparison of transferred paints between victim's vehicle and suspected vehicle can be an important evidence in reconstructing the accident situation and in discovering the truth. The paints such as white, yellow, red, blue, or black are hard to examine particle shape under a stereomicroscope because of it is not included aluminum, pearl, and mica flakes in the pigments. The aim of this study under forensic aspect is to compare pigment among basecoat layers of solid paints by identifying inorganic elemental compositions and binder resins of pigments using by micro-FT-IR and micro-XRF spectrometer. The pigment samples were analyzed by using two methods of FT-IR: Reflectance and ATR method. Two methods of FT-IR were useful in discriminating binder resins of pigments by comparing characteristic peaks and patterns of spectra. Also, XRF spectrometer could identify the elemental compositions in inorganic pigments of trace paints which are difficult to compare the identification by FT-IR.

• Elastomers and Composites
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• v.37 no.3
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• pp.159-169
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• 2002

The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).