• Title/Summary/Keyword: Acrylic Resin

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Dispersion of Carbon Black in Acrylic Resin Aqueous Solution (아크릴 수지 수용액에서의 Carbon black의 분산에 관한 연구)

  • 오지만;김성빈;권대환
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.16-27
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    • 2002
  • Recently, the attraction for water-based ink is increasing, Because Solvent ink, based on organic solvent, cause bad effect on environment and rise the cost. Instead of organic solvent that cause environment pollution as well as cost-rise by rise of petroleum price, Binder based on alkali-soluble resin is popular and studied by many other country. However, in domestic, research and development for alkali-soluble resin is not like, because of lack of understanding environmental pollution and safety, therefor alkali-soluble resin development and research for the properties of the water-based ink used by alkali-soluble resin is not study very well. In this paper, we studied dispersion of carbon black in acrylic resin solution and the properties of water-based ink used by carbon black and acrylic binder.

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USE OF ACRYLIC RESIN IN RELEASING CHLORHEXIDINE (아크릴릭 레진상을 이용한 클로르헥시딘의 방출에 관한 연구)

  • Lee, Eun-Young;Choi, Yeong-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.25 no.4
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    • pp.797-810
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    • 1998
  • The purpose of this study was to develop a new way of delivery system of chlorhexidine using self-curing acrylic resin. Different preparations of chlorhexidine, such as chlorhexidine varnish($Chlorzoin^{(R)}$) and chlorhexidine diacetate crystalline, were mixed into self-curing acrylic resin with different methods. Every resin plate was made and was immersed in 100ml of distilled water individually, and kept in an incubator at $37^{\circ}C$. Solution(0.8ml) was collected from the each container at every 24 hours, and the amount of released chlorhexidine in the solution was measured in an ultraviolet spectrophotometer at 255nm. Flexural strength of all of the resin plates in the Experiment 2-A and 2-B were measured using Instron at the end of the experimental periods. The results were as follows: 1. It was found that chlorhexidine was released from the experimental groups in the Experiment 1, 2-A, and 2-B. And the release of chlorhexidine from all of the experimental groups showed a pattern of sustained-release preparation. 2. It seemed likely that a condition of "dryness" reduced a release of chlorhexidine from the chlorhexidine varnish. 3. It may be stated that a method of "chlorhexidine diacetate mix" with the polymer be more efficient than a method of "Chlorzoin mix" with the monomer. 4. Although it was evident that a flexural strength of the acrylic resin plates be reduced by a mix of either Chlorzoin or chlorhexidine diacetate crystalline, it seemed likely that the resin plates except Group 4 and 5 in the Experiment 2-B may be usable in the clinical situation.

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The Effect of Changes in Polymerization Conditions of Orthodontic Acrylic Resin on Maximum Load (Orthodontic Acrylic Resin의 중합조건 변화가 최대하중에 미치는 영향)

  • Lee, Gyu Sun
    • Journal of Technologic Dentistry
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    • v.35 no.2
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    • pp.127-136
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    • 2013
  • Purpose: In order to find out the impact of changes in polymerization conditions of orthodontic acrylic resin on maximum load. Methods: While maintaining mixing ratio 3:1 of polymer and monomer in spray-on way in the production condition of polymerization temperature $25^{\circ}C$ or $37^{\circ}C$ for 10 minutes or 30 minutes of polymerization time by pressure $3kfg/cm^2$ or $6kfg/cm^2$ in the lab maintaining $25^{\circ}C$ of room temperature, the change in maximum load rise rate was tested by producing 5 acrylic resin specimens for orthodontics per group to meet the standards of $25mm{\times}2mm{\times}2mm$ and using INSTRON with the 3rd bar 2mm in diameter and parallel support bending device of $15{\pm}0.1mm$ as test equipment showing 30.00mm/min of crosshead speed, $50{\pm}16$ N/min of load ratio in the laboratory of $24^{\circ}C$ room temperature and as a result, the following results were obtained. Results: 1. When increasing pressure from $3kfg/cm^2$ to $6kfg/cm^2$, maximum load was lowered by -4.285%. 2. When increasing polymerization time from 10 minutes to 30 minutes, maximum load rose by 3.848%. 3. When increasing polymerization temperature from $27^{\circ}C$ to $37^{\circ}C$, maximum load rose by 5.854%. Conclusion: Considering the above test results that polymerization time and polymerization temperature when polymerizing acrylic resin for orthodontics according to changes in working conditions had an impact on the rate of rise of maximum load values but the rate of rise was lowered when increasing pressure from $3kfg/cm^2$ to $6kfg/cm^2$, we came to a conclusion that high pressure more than necessary does not affect the rate of rise of maximum load.

Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings

  • Yoo, Gyu-Yeol;Kim, Ji-Hyun;Park, Hong-Soo;Kim, Young-Geun;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.1-14
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    • 2008
  • To prepare weather-resistant modified silane acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The composition of monomers was adjusted to fix the glass transition temperature of acrylic polymer for $20^{\circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects on weatherability were examined. The presence of MPTS in modified silane acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the modified silane acrylic resins containing 30 wt% of MPTS had superior weathering properties.

Reforming of Expanded Graphite for Improving Fire Resistance of Fireproof Sealant (방화용 실란트의 내화성 향상을 위한 첨가제로서 팽창흑연의 개질)

  • Hong, In Kwon;Lee, Won Jae;Lim, Hyun Seok;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.437-441
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    • 2017
  • This study was carried out to investigate the volumetric expansion ratio and hardness of expanded graphite after coating with various resins which were used as an additive of fireproof sealant. The coating thickness of the resin, which represents the coating rate, was dependent of the drying speed of the resin and the viscosity of the resin. Therefore the coating thickness was shown as follows: polyvinyl acetate > acrylic resin > urethane resin > water soluble latex. Furthermore, the volumetric expansion ratio was as follows: urethane resin > water soluble latex > acrylic resin > polyinyl acetate and the hardness was as follows: polyvinyl acetate resin > acrylic resin > water soluble latex > urethane resin. This showed that the volume of expansion was reduced by expansion, which was not covered by coating, but significantly increased by increasing hardness and allowed it to be used as a refractory addition. According to the response surface methodology, the optimized addition amount and stirring speed of acrylic resin were 37.6 wt% and 441.4 rpm, respectively.

PULP RFSPONSE TO SELF-CURING RESIN (즉시중합(卽時重合) 레진에 대(對)한 치수반응(齒髓反應))

  • Lim, Sung-Sam
    • Restorative Dentistry and Endodontics
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    • v.2 no.1
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    • pp.7-9
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    • 1976
  • This study was performed to reveal the effect of self-curing acrylic resin to dental pulp when the resin was used directly on the freshly cut dentin. Class V cavity preparations were made on the teeth of dogs with No. 701 carbide bur at a speed of 200,000 rpm and with an air water spray. Petrolatum jelly was coated on the inner surfaces of the cavities. After that, doughs of self-curing acrylic resin were filled in these cavities and before completely set these were removed and cemented with zinc oxide and eugenol cement. The dogs were sacrified between 1 day and 3 weeks at the intervals of one week and routinely processed with hematoxylin and eosin stain for histopathologic interpretation. The results were as followings; 1. The inflammatory changes of the pulp can be seen after the use of self-curing acrylic resin on freshly cut dentin. 2. The inflammatory changes of the pulp were not completely subsided until the end of third experimental week.

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Fabrication of refractive PMMA microlens array using transparent acrylic resin (투명 아크릴 레진을 이용한 초소형 PMMA 렌즈 배열의 제작)

  • Ahn, Si-Hong;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 1999.07g
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    • pp.3316-3318
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    • 1999
  • PMMA(poly-methyl methacrylate) microlens array is fabricated using transparent acrylic resin. PMMA is commonly used material for plastic lens due to its excellent visibility larger than 90% and other optical characteristics so much close to those of glass. Orthodontic resin (DENTSPLY International Inc.), commonly used in dentistry, is an transparent acrylic resin kit including MMA liquid and polymerization powder. Their mixture results in PMMA through polymerization. Using the resin PMMA layer is formed on the substrate through spin-coating. Designed pattern of lens structure is transferred to PMMA layer by RIE (Reactive Ion Etching) with oxygen plasma. Final lens shape is formed by thermal treatment that causes PMMA to reflow, The thickness of PMMA spun on the substrate is $17{\mu}m$ that is also final sag of microlens, Designed diameters of the microlenses are $200{\mu}m$, $300{\mu}m$,and $500{\mu}m$, respectively.

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Increase in Color Depth of Polyester Fabric by Resin Treatment (수지처리에 의한 PET직물의 심색화)

  • Kim, Jae-Ho;Kim, Hye-Jin;Kim, Dong-Uk;Hong, Seung-Pyo;Kim, Sang-Jin;Kim, Hee-Dong;Kim, Hyun-Ah;Huh, Man-Woo
    • Textile Coloration and Finishing
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    • v.26 no.3
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    • pp.187-194
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    • 2014
  • To improve the deep coloring effect of PET fabrics, the alkali treated and black dyed PET fabrics were treated with 2 kinds of low refractive compounds such as acrylic resin and silicone resin. The color depth effect of treated PET fabrics was evaluated as lightness(L) change by UV-visible spectrophotometer. As the weight loss of PET fiber treated with alkali increased, the color depth of PET fabrics increased. Lightness(L) of PET fabrics treated with deep coloring agent was lower than that of untreated PET fabrics. The optimum concentration of treated PET with deep coloring agent was 4% o.w.s. The deep coloring effect of PET fabrics treated with silicone resin was higher than one treated with acrylic resin. PET fabrics treated with silicone resin only might be more appropriate process than PET fabrics treated with acrylic and silicone resin for giving deep coloring effect for polyester fabrics.

THE EFFECTS OF BARIUM SULFATE AND IODIDE COMPOUND ON THE CHARACTERISTICS OF DENTAL ACRYLIC RESINS (치과용 아크릴릭 레진의 방사선 불투과도에 관한 연구 - 황산바륨과 요오드 화합물 첨가 -)

  • Lee Yong-Keun;Lee Keon-Il;Jung Sung-Woo
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.26 no.2
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    • pp.133-145
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    • 1996
  • Aspirating or swallowing foreign bodies is a common occurrence. If they are wholly or partly radiopaque, their localization in and progress through the gastrointestinal tract can be more effective. Of the dental origin foreign materials swallowed, the most common things are fragments of anterior maxillary partial denture. But the radiopacity of denture base resins is not sufficient to determine the location of the objects. The purpose of this study was to develop a radiopaque dental acrylic resin, which has clinically detectible radiopacity with minimal change of mechanical properties and color. The radiopacity, color change(CIE 6..E) and microhardness of acrylic resins were determined after mixing barium sulfate or iodide compound. Thermocycling course was conducted to determine the change of characteristic of resins after using for a long time in the mouth. Five or ten percent of barium sulfate to total weight of cured material was mixed with heat curing dental acrylic resin or chemically curing orthodontic resin. In the case of iodide compound, the mixing ratio was two or three percent. After mixing the high radiopaque materials, resin was cured to 20×20×2 mm plate, polished with #600 sand paper and finally polished with Microcloth(Buehler). The specimens were thermocycled in 5 and 55 t distilled water for 2,000 times, and the measurement of radiopacity, color and Vickers hardness was repeated every 500 times thcrmocycling. The radiopacity of specimens on the X -ray films was measured with densitometer(X-rite). The color change was detennined with differential colorimeter(Model TC-6FX, Tokyo Denshoku), and the Vickers hardness number was measured with microhardness tester(Mitsuzawa). The following results were obtained : 1. All the three variables, the kinds of acrylic resins, the mixing or the kinds of high radiopaque materials and thermocycling, had combined effect on the radiopacity of the dental acrylic resins(p<0.0l). 2. The two variables, the mixing or the kinds of high radiopaque materials and thermocycling, influenced on the radiopacity of the dental acrylic resins(p<0.01). But the kinds of acrylic resins did not influence on the color change of mixed dental acrylic resins(p>0.05). 3. Each of the three variables, the kinds of acrylic resins, the mixing or the kinds of high radiopaque materials and thermocycling, influenced on the radiopacity of dental acrylic resins(p<0.0l). 4. The high radiopaque materials used in this study did not yield clinically usable radiopacity, and the color change was great after mixing those materials.

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Experiment to Select Materials for the Conservation and Restoration of a Glass Ewer, Korean National Treasure No.193 (국보 제193호 봉수형유리병의 재보존처리에 사용할 복원재료 선정 실험)

  • Hwang, Hyunsung;Koh, Minjeong;Lim, Sookyung;Lee, Dahae
    • Conservation Science in Museum
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    • v.15
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    • pp.26-37
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    • 2014
  • The Department of Conservation Science at the National Museum of Korea carried out conservation treatment on a prized glass ewer Designated as Korean National Treasure No.193 in order to enhance the ewer's structural stability and restore its true color and transparency. Prior to the conservation treatment, experiments were conducted on various materials e.g., Epoxy Resin, Acrylic Resin, Photopolymer Resin, Water Glass in order to select the most suitable materials for glass conservation. As a result, cyanoacrylate, acrylic, and photopolymer resin were found to be the most appropriate as adhesives, and acrylic resin was an appropriate restoration material. Notably, however, cyanoacrylate resin must not be used solely, and epoxy resin must be detachable.