• Title/Summary/Keyword: Acryl binder

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Preparation of Acryl Binder with Silane Type Chain Transfer Agent (실란계 사슬 이동제를 사용한 아크릴 바인더의 제조)

  • Kim, Jin-Gon;Shin, Min-Jae;Shin, Jae-Sup
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.351-356
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    • 2012
  • Acryl binder is a representative organic additive for the manufacture of the display electronic equipment. Acryl binder is usually synthesized by radical copolymerization. Glycidyl methacrylate (GMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were used in this copolymerization of acryl binder. In this study the silane type mercaptane compound was used as a chain transfer agent (CTA) to enhance the adhesion property of the acrylic binder. The CTA used in this experiment was (3-mercaptopropyl) trimethoxysilane (MPTMS). Molecular weight of the copolymer, thickness of the coating, transmittance, and adhesion property were measured. The molecular weight was controlled and the adhesion property was improved by using this silane type chain transfer agent.

The develop of hydrogen coating agent used for discolor improvement of DTP (Color발색을 개선한 실사출력용 수성코팅제 개발)

  • Lee, Eun-Jeong;Gu, Gang;Yun, Jin-Yong;Jo, Yeon-Jeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.138-140
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    • 2008
  • 현재 현수막의 코팅에서 기능을 부여하는 수요가 늘고 있다. 본 실험에서는 코팅제의 유기용제 사용으로 인한 환경오염 문제및 폐기물 처리비용 부담을 줄이기 위하여 수성코팅제를 개발하려한다. acryl binder, 탄산칼슘, silica, 유화제등을 혼합한 코팅제를 knife coating한 후 170$^{\circ}C$로 1분 30초간 열처리 하였다. 이때 acryl binder의 첨가비율은 35${\sim}$55%로 변화를 주었다. 처리한 폴리에스테르에 DTP printing을 한 후 CCM 측정, 내수성, 접착성을 알아본 결과 acryl binder의 첨가비율은 45%일때 가장 우수한 발색성 및 printing 특성을 나타내었다. 기존 수성코팅제에 대비 20${\sim}$30% 발색성이 개선되었다.

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Application Technology of Environmental-friendly Starch-based Biobinder and Synthesized Binder as a Substitute for SB Latex (2) - Application of Substitute Binder for Top-coating Layer - (SB latex 대체용 친환경 전분계 바이오바인더 및 합성바인더의 적용 기술 개발 (제2보) - 대체용 바인더의 Top-coating 적용 -)

  • Lee, Yong Kyu;Hong, Seong-Ho;Won, Jong Myoung;Kim, Young-Hun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.141-146
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    • 2015
  • This study was carried out to elucidate the partial substitutability of SB latex with environmental-friendly coating binders for coated paper. Starch-based biobinder, ethylene vinyl acetate and acryl-based binder were evaluated for this purpose. Several combinations of above binders were applied to top layer coating, and properties of coating colors and printability were evaluated. When 20% and 30% of SB latex were substituted by acryl-based synthetic binder, ethylene vinyl acetate and biobinder, the brightness, whiteness and opacity of coated paper were similar to those obtained from SB latex. Ink set and stiffness of coated paper manufactured through 20% and 30% substitution of SB latex by biobinder and EVAc were improved, but dry- and wet-pick strength were decreased. The research works on the improvement of dry- and we-pick strength, mechanical stability and rheological properties at high shear condition should be continued for the commercial application of biobinder, EVAc and acryl-based binder.

Application Technology of Environmental-friendly Starch-based Biobinder and Synthesized Binder in order to Substitute SB Latex for Paper Coating (1) - Application of Substitute Binder for Pre-coating Layer - (SB latex 대체용 친환경 전분계 바이오바인더 및 합성바인더의 적용 기술 개발 (제1보) - 대체용 바인더의 Pre-coating 적용 -)

  • Lee, Yong Kyu;Kim, Sun-Goo;Won, Jong Myoung;Kim, Young-Hun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.134-140
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    • 2015
  • This study was carried out to evaluate whether EVAc, acryl latex and biobinder could substitute the part of SB latex for pre-coating color formula or not. Different coating colors prepared through the substitution of 30% SB latex with EVAc, acryl latex, and biobinder were applied for pre-coating layer. 100% SB latex is used as a binder for top coating color. The optical properties, gloss, roughness, stiffness, dry- and wet-pick strength were measured. There were no significant differences in the brightness, whiteness, opacity, roughness, ink set-off and gloss of paper coated with 5 different coating colors. However the stiffness, dry- and wet-pick strength were somewhat lower than those of conventional coating color which 100% SB latex was used as a binder. Although the part of SB latex could be substituted with EVAc, acryl latex and biobinder without sacrificing the qualities of coated paper. Further researches on the improvement of stiffness, dry- and wet-pick strength, and the optimization of rheology of coating color in order to improve the qualities of coated paper are strongly recommended.

Flame-retarding effects depending on the number of phosphonate groups attached to phosphorus flame-retarding compounds and coating binder resins (인계 난연화합물 및 코팅 바인더 수지에 부착된 phosphonate group에 따른 난연효과)

  • Park, Hyo-Nam;Kim, Hae-Rim;Choi, Seong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.6
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    • pp.1678-1686
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    • 2021
  • In this study, we prepared phosphorous flame-retarding coating solutions by mixing triphosphate (3 phosphonate), phytic acid (6 phosphonate), or ammonium polyphosphate (10 phosphonate) with boric acid as a crosslinking agent and acryl resin binder. Prepared phosphorous flame-retarding coating solutions were coated onto non-woven fabrics, respectively, to obtain high flame-retarding effects. These prepared flame-retardant non-woven fabrics were evaluated using smoke density standard test (ASTM E662), limit oxygen index standard test (ISO E622), and vertical burning standard test (UL 94). Their flame-retarding effects were affected by the number of phosphonate groups. Regardless of natural or synthetic binder resins, their effects showed the following order: ammonium polyphosphate > phytic acid > triphosphate. Natural hydrocarbon compounds were also examined to determine the possible retardancy of binder resins. Results showed that natural hydrocarbon binder resins could be used for preparing fire-retardant nonwoven fabrics.

An Experimental Study on Friction and Wear Characteristics of Air Curable $MoS_2$ Bonded Films with Polymeric Binder Materials (결합제 변화에 따른 상온 경화성 접착형 $MoS_2$ 고체윤활 피막의 마찰.마모 특성)

  • 한흥구;공호성;윤의성;권오관
    • Tribology and Lubricants
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    • v.14 no.4
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    • pp.72-78
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    • 1998
  • In this work, the effects of binder materials on the tribological behavior were experimentally evaluated for air curable MoS$_2$bonded film lubricants. The binders tested were basically alkyd and acryl based resins, and also were modified by nitro-cellulose in various weight percentages. Effects on the binder ratio to solid lubricants and the molecular weight of binders were also investigated in all aspects of the tribological behavior. For the tests, LFW-1 and Falex tester were used to measure mainly the endurance life and load carrying capacity of bonded lubricants. Results showed that lubricants of methacrylic resin has the better performance than those of other resins, and also the properties of lubricants both of alkyd and acrylic resins could be improved by modification with nitro-cellulose. It was also shown that the optimum ratio of nitro-cellulose related closely to the binder material and the testing machine.

The Study on Prediction of Oxidative Decomposition Potential by Comparison between Simulation and Electrochemical Methods to Develop the Binder for High-voltage Lithium-ion Batteries (고전압용 리튬이차전지 바인더 개발을 위한 시뮬레이션 및 전기화학 평가 비교를 통한 산화분해전압 예측 연구)

  • Yu, Jee Min;Kashaev, Alexey;Lee, Maeng-Eun
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.177-183
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    • 2013
  • As the development of available binder in the harsh conditions is needed, we propose the proper binder for high-voltage lithium-ion secondary batteries based on the quantum chemistry modeling. The optimized structures, HOMO (Highest Occupied Molecular Orbital) energies and ionization potentials of 4 binders, which were considered from monomer to tetramer, were investigated by the semi-empirical and DFT (Density Functional Theory) calculations. The results show that the ionization potential values by calculation tend to be close to the oxidation potentials from the measurement of linear sweep voltametry (LSV). The order of oxidative resistance from high value to low value is following: poly(hexafluropropylene), poly(vinylidene fluoride), poly(methyl acrylate) and poly(acryl amide). Also these results correspond with the experimental values. Thus, we find the reason why HOMO (Highest Occupied Molecular Orbital) energy of PHFP has the highest value than other binders by analysis of HOMO orbital structures.

Synthesis of Fluorene-containing Photosensitive Polymer and Its Application to the Carbon Black-based Photoresist for LCD Color-Filter (Fluorene 단위 구조를 함유한 감광성 고분자의 합성 및 LCD 컬러필터용 카본블랙 포토레지스트로의 응용)

  • Kim, Joo-Sung;Park, Kyung-Je;Lee, Dong-Guen;Bae, Jin-Young
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.87-93
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    • 2011
  • We developed a fluorene-containing multifunctional binder polymer for LCD color filter resist, and employing the binder polymer, carbon black based black photoresist (CBR) was prepared in order to apply it to the black matrix (BM). To obtain the multifunction of the binder polymer, we synthesized bisphenol fluorene epoxy acrylate-containing unsaturated polyester and identified the binder polymer structure with $^1H$ NMR, GPC and FTIR. The corresponding BFEA-polyester binder polymer was compared with the commercially available acryl binder toward the application to the CBR. From the BM lithography test, we found that the synthesized BFEA-polyester binder had better photocrosslinking capability and alkali solubility. In addition, the newly developed binder gave a good process margin, good resolution and adhesion property on a glass substrate.

The characteristics of microencapsulated phase-change materials (상전이 마이크로캡슐 재료의 축열특성)

  • 임대우
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.53-56
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    • 2003
  • The objective of this research is to investigate the thermal behavior of microencapsulated phase-change materials(MEPCM), and a shell of melamine-formaldehyde. These PCM materials were tested using DSC and thermal data station. Fabrics with enhanced thermal properties were prepared by padding the fabrics with the microcapsules containing PCM and acryl binder. The rate of temperature increase was significantly decreased as the amount of MEPCM added on the surface of the fabrics increased.

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Preparation and Characteristics of Heat-releasing Sheet Containing AlN(alunimum nitride) Powder (AlN 분말을 이용한 방열 Sheet의 제조와 그 특성)

  • Kim, Sang-Mun;Lee, Seok-Moon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.6
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    • pp.431-434
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    • 2012
  • In this paper, heat-releasing sheets made of AlN powder and acryl binder as thermoset were prepared using tape casting method. The crystal structure and morphology, the thermal properties as nonvolatile solid content and thermal conductivity, and the surface resistance of heat-releasing sheet were measured by using X-ray diffractometer, field emission-scanning electron microscopy, thermo gravimetric analyzer and laser flash instrument, and surface resistance meter. It was proved that thermal conductivity is greatly affected by the content of binder in heat-releasing sheet. Superior thermal conductivity above 3.5 W/mK and suface resistance were obtained at heat-releasing sheet with above 90% of AlN powder.