• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1999.10a
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• pp.81-84
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• 1999

The aqueous geochemical characteristics of Cr(III) and Cr(Ⅵ) in environmental systems are very different from one another: Cr(Ⅵ) is highly soluble, mobile and toxic relative to Cr(III) Reduction of Cr(Ⅵ) to Cr(III) are beneficial in aquatic systems because of the transformation of a highly mobile and toxic species to one having a low solubility in water, thus simultaneously decreasing chromium mobility and toxicity. Fe(II) species are excellent reductants for transforming Cr(Ⅵ) to Cr(III), and in addition, keeping Cr(III) concentrations below the drinking water standard of 52 ppb at pH values between 5 and 11. Investigations of the effects of NOM on Cr(Ⅵ) reduction are for examining the feasibility of using ferrous iron to reduce hexavalent chromium in subsurface environments. Experiments in the presence of soils, however, showed that the solid phase consumes some of the reducing capacity of Fe(II) and makes the overall reduction kinetics slower. The soil components bring about consumption of the ferrous iron reductant. Particular attention is devoted to the complexation of Fe(II) by NOM and the subsequent effect on Cr(Ⅵ) reduction. Cr(Ⅵ) reduction rate by Fe(II) was affected by the presence of NOM (humic acid), The effects of humic acid was different from the solution pH values and the concentration of humic acid. It was probably due to the reactions between humic acid and Cr(Ⅵ), humic acid and Fe(II), and between Cr(Ⅵ) and Fe(II), at each pH.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.22 no.1
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• pp.47-59
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• 2019

This study was composed of four treatments [no treatment, phosphate + limestone layer treatment, phosphate + sodium bicarbonate + cement layer treatment, and phosphate + sodium bicarbonate + limestone layer treatment] for figuring out vegetation effects on the acid drainage slope. Treated acid neutralizing techniques were effective for neutralizing acidity and vegetative growth in order of [first: phosphate + sodium bicarbonate + limestone layer treatment, second: phosphate + sodium bicarbonate+cement layer treatment, third: phosphate + limestone layer treatment and fourth: no treatment] on the acid drainage slope. We found out that sodium bicarbonate treatment was additory effect on neutralizing acidity and increasing vegetaive growth besides phosphate and neutralizing layer treatments. In neutralizing layer treatments, Limestone layer was more effective for vegetation and acidity compared to cement layer treatment. Cement layer showed negative initial vegetative growth probably due to high soil hardness and toxicity in spite of acid neutralizing effect. Concerning plants growth characteristics, The surface coverage rates of herbaceous plants, namely as Lotus corniculatus var. japonicus and Coreopsis drummondii L were high in the phosphate + sodium bicarbonate + limestone layer treatment while Festuca arundinacea was high in the phosphate + sodium bicarbonate + cement layer treatment. We also figured out that soil acidity affected more on root than top vegetative growth.

• Journal of Soil and Groundwater Environment
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• v.20 no.3
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• pp.65-73
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• 2015

The hydrofluoric acid (HF) leakage accident occurred on September 2012 in Gumi, Korea affected the surrounding soils and plants. In this study, we investigated fluoride migration in Gumi area through geochemical properties of soil-liquid phase (pore water F and water-soluble F). The concentrations of porewater F and water-soluble F were obtained from N.D (Not detected) to 9.79 mg/L and from 0.001 to 21.4 mg/L, respectively. F in pore water seemed to be affected by artificial and natural origin, and PHREEQC results implied that fluorite is F control factor. F concentrations of soil and soil-liquid phase did not exceed concern level of regulatory criteria and showed similar trends compared by previous studies. Therefore, F contents remained in the soil and soil-liquid phase were considered to be not affected by HF leakage accident.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.22 no.2
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• pp.159-171
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• 2024

This study aimed to develop an efficient recycling process for wastewater generated from soil-washing used to remediate uranium (U(VI))-contaminated soil. Under acidic conditions, U(VI) ions leached from the soil were precipitated and separated through neutralization using hydrazine (N₂H₄). N₂H₄, employed as a pH adjuster, was decomposed into nitrogen gas (N₂), water (H₂O), and hydrogen ions (H⁺) by hydrogen peroxide (H₂O₂). The residual N₂H₄ was precipitated when the pH was adjusted using sulfuric acid (H₂SO₄) to recycle the wastewater in the soil-washing process. This purified wastewater was reused in the soil-washing process for a total of ten cycles. The results confirmed that the soil-washing performance for U(VI)-contaminated soil was maintained when using recycled wastewater. All in all, this study proposes an efficient recycling process for wastewater generated during the remediation of U(VI)-contaminated soil.

• Asian-Australasian Journal of Animal Sciences
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• v.17 no.9
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• pp.1286-1290
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• 2004

This study was carried out to screen yeasts effective in reducing odor from pig feces. Three isolates from soil and compost sources were selected to treat pig feces. On the basis of morphological and biochemical characteristics, one isolate from compost was Candida rugosa, and two isolates from soil were Candida rugosa and Candida maris. These isolates showed deodorizing activity by reducing the concentration of ${NH}_3$ and R-${NH}_2$. Volatile fatty acids (VFA) are the specific malodorous compounds of pig feces, and the Candida maris from soil showed a 100% reduction of butyric, iso-butyric, and iso-valeric acid in 10% pig slurry medium. However, the Candida rugosa from compost showed a 100% reduction of butyric and iso-butyric acid while that from soil showed a 100% reduction of propionic, butyric acid and iso-valeric acid in the medium. Also, these yeasts were effective in reducing $NH_{4}-N$, soluble-N, and biological oxygen demand (BOD).

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.696-700
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• 2003

$H_2SO_4$ and citric acid had higher extraction efficiency of $^{137}Cs$ from soil than the other chemicals. Thus, $H_2SO_4$and citric acid were used as additives on remediation experiment by electrokinetic method to increase removal efficiency of $^{137}Cs$ from the radioactive soil being stored during a long time. An average velocity of effluent discharged from experimental column $2.0{\times}10^{-2}$/cm/min and a volume of the discharged soil wastewater for 10 days is 3.6 Pore Volume. The 54% of a total of $^{137}Cs$ in the column was decontaminated for 10 days. Furthermore, the predicted values of residual concentration by the developed model were quite similar to those obtained from experiments.

• 보존과학연구
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• s.27
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• pp.203-214
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• 2006

The work focuses on the chemical analysis of organic residues in archaeological soils. Particularly, the detection of manuring in archaeological soils can provide important information concerning early human behavior, diet, parasites, ecological adeptation. In this study, archaeological soils excavated at bunto-ri, Haenam and kumjang-ri, Kyungju were used to assess the possibility as indicators of ancient human activity in archaeological areas. The sampled soils were analyzed soil color, pH for their physical and chemical properties and GC/MSD to detect and quantify specific compound. The results showed that the sampled soils were normal pH(6.8~7.2) and soil color of light brown to yellowish brown. Also, the result from the GC/MS analysis indicated that their compounds were hexadecanoic acid, octadecanoic acid, nonadecane, docosanoic acid, methyl ester, teracosanoic acidand methyl este from bunto-ri site and 1-heptadecene, cyclotetracosane, tetracosane, cyclotetracosane,1-docosene, n-nonadecane, tetracosanoic acid methyl ester, cyclooctacosane, 1-nonadecene, eicosane, cyclotriacontane from kumjang-ri site. These compounds are not only normal soil materials but also animal lipid compounds. And the more scientific analysis of the soils will solve a curiosity for artificially incoming.

• The Korean Journal of Ecology
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• v.26 no.2
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• pp.87-89
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• 2003

Although a forest damage of large area due to air pollution has not yet been found in Korea, declines of Korean red pine (Pinus densiflora Sieb. et Zucc.), the most common coniferous species, have been locally reported. To evaluate the effect of air pollution and acid deposition on the forests, SO$_2$ concentration, acid load, soil pH and tree decline were monitored for 13 years from 1988 to 2001 in Namsan, Doowang and Gyebangsan with the gradient of air pollution. During the study period, annual mean SO$_2$ concentration in Namsan, Doowang and Gyebangsan were 14 ppb, 13 ppb and 6 ppb, respectively. Annual mean acid loads in Namsan and Doowang were three to four times more than that in Gyebangsan. As respected, forest surface soils in Namsan and Doowang were acidified to pH 4.1 and 4.3, whereas that in Gyebangsan showed normal value as pH 5.4. On the other hand, decline degrees of Korean red pines in Namsan and Doowang in both 1996 and 2001 were higher than those in Gyebangsan. It is reasonable that the severer tree declines in Namsan and Doowang could be closely related with the higher air pollution, acid load, and the effects (possibly Ca deficit and Al toxicity) of soil acidification.

• Korean Journal of Soil Science and Fertilizer
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• v.33 no.5
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• pp.311-317
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• 2000

Acid sulfate soil and potential acid sulfate soil material are worldwide in distribution and are problematic in agriculture and environment due to their present and potential acidity developed by the oxidation of sulfides. Most of them are sedimentary origin and a few cases are reported as volcanic or metamorphic origin. We report a potential acid sulfate soil material originated from volcanic activity during Mesozoic. A profile of Bongsan series-weathered nonpyritic andesite-hydrothermally altered pyrite rich andesite was studied with field examination, chemistry, and mineralogy. Once, the pyrite rich andesite was exposed to atmosphere by excavation and leveling works for a residential area and the lay out site had subsequent acidification problem of soil and surface water. The parent material and soil profile of Bongsan series had no signs of presence of pyrite and acid sulfate weathering such as yellow mottles. However, the hydrothermally altered andesite substrata contained significant amount of pyrite showing characteristics of hydrothermal origin such as cubic and pyritohedron morphology and occurrence along cracks.

• Environmental Analysis Health and Toxicology
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• v.18 no.1
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• pp.63-67
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• 2003

Benzoic acid is produced about 700 tons/year in Korea as of 1998 survey. Most is used as a stabilizer in the processes of synthesis of pharmaceuticals and dyes. It is also used for ingradient of paint, disinfections, and antifungals. Due to the antioxidant activity of benzoic acid, the chemical is also used as food preservatives. Although the chemical is widely used in Korea, exposure levels in air, water, soil or sediment have not been monitored or estimated so that risk evaluation of benzoic acid was not possible. In this study, distribution of the chemical among environmental media was estimated using EQC model based on the chemical-physical properties. In Level I and II of which the chemical are hypothesized in equilibrium and no transfer through the media, more than 93％ of benzoic acid are estimated to be distributed in water. However, in Level III of which non-equilibrium and intermedia transfer could be occurred, the chemical is estimated to distributed to soil, 64％ and water,35% as of total amount.