• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.534-538
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• 1991

A procedure for spectrophotometric determination of traces of boron in high-purity trichlorosilane (TCS) is proposed utilizing an adsorptive separation. NaCl is chosen as an Lewis base adsorbent which forms a complex with boron compounds in TCS, and is well dissolved in sulfuric acid-quinalizarin color-forming agent without causing an interference in colorimetric measurements. The proposed adsorptive separation method is free from the formation of silica gel and gas bubbles during the analysis of TCS. The method reveals that the boron concentration in a semiconductor grade TCS is 6.1 ${\mu}$g/l within the standard deviation of ${\pm}$20%. On the other hand, the boron concentration of the purified TCS which is separated from NaCl-boron compounds complex is reduced to 0.2 ${\mu}$g/l, showing the efficient applicability of NaCl to the adsorptive separation. The effectiveness of NaCl for the removal of boron in TCS purification is also described in comparison with other well-known adsorbents.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.868-874
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• 2008

The Ni based adsorbent was prepared by co-precipitation method and its performance for removing carbon monoxide was investigated. Here, silica, aluminium silicate and ${\gamma}$-alumina were used for carriers of catalyst. $Ni(NO_3)_2{\cdot}6H_2O$ and $Ni(CH_3COO)_2{\cdot}4H_2O$ were utilized for Ni precursors. Precipitants were urea and citric acid. After precipitation of Ni salt on the carrier and following reduction using $H_2$ gas, adsorbent was prepared and its performance was analyzed based on EDS, TPR and XRD experiments. In accordance with change of precipitation agents, Ni salts on carrier, carriers and reduction condition. Adsorbent performance for removing carbon monoxide was investigated. The adsorbent with 54.8 wt% Ni prepared using urea precipitant under reduction condition at $500^{\circ}C$ for 3 h exhibited the best CO removal performance.

• Journal of Physiology & Pathology in Korean Medicine
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• v.25 no.2
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• pp.246-256
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• 2011

To compare the medical efficacy of original Socheongyong-tang with fermented Socheongyong-tang, we've studied the two medicines according to the search for optimal bacteria and optimal conditions, component analysis, assessment of medical efficacy and toxicity, and have the result below. The results were obtained as follows: Considering bacterial growth, $CO_2$ gas emission and pH, we examined that using 3 kinds of bacteria(S. cerevisiae KCTC 7913, L. casei KCTC 3109, L. brevis KCTC 3102) is desirable. There is no main difference in optimum conditions between incubator and shaking incubator. And it is considered that ideal fermentation time is 2 days after vaccination. As the result of componential analysis of before and after fermentation, there's a noticeable decrease of total sugar and protein. But there's no alterations in total phenolics compounds and in total flavonoid compounds that influence on medical effect. The result was interpreted that it can promote the assimilation of herbal decoction after fermentation. As the result of medical efficacy assessment, we can check out that there is more anti-oxidating effects in fermented Socheongyong-tang, whereas anti-inflammatory effects and obesity-preventing effects were favorable in original Socheongyong-tang. And there is no main difference of whitening and COX-2 removing effects between before and after the fermentation. As a result of assessing weight change, hepatotoxicity and nephrotoxicity, we can not notice any unusual difference between before and after the fermentation. According to the results above, it is considered that we checked out the optimal bacteria and optimal conditions, advantages and disadvantages of the medical efficacy of original Socheongyong-tang and fermented Socheongyong-tang. And we suggest that there will have to be a following in-depth and systematic research on this subject in the future.

• Journal of Wetlands Research
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• v.17 no.1
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• pp.45-52
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• 2015

We obtained the following results from investigation on vegetation damage from 5 to 6 August, 2013, about one year after an accident that hydrofluoric acid leaked from a chemical maker, Hube Globe in Gumi. Pinus densiflora and Pinus strobus showed very severe damage. Ginko biloba, Quercus acutissima, Pinus rigida, Salix glandulosa, Hibiscus syriacus, and Lagerstroemia indica showed severe damage. Quercus variabilis, Lespedeza cyrtobotrya, and Miscanthus sinensis showed moderate damage. Quercus aliena, Smilax china, Arundidinella hirta, Ailanthus altissima, Robinia pseudoacacia, and Paulowinia coreana showed slight damage. We did not find any plants without leaf damage around there. This result means that fluoride damage still persists in this area as was known that fluoride remains for a long time in air, soil and water and exerts negative effects at all levels of an ecosystem. In addition, fluoride content contained in plant leaf depended on the distance from a fertilizer producing factory and vegetation damage tended to proportionate to the concentration in the Yeocheon industrial complex. In these respects, a measure for removal or detoxification of the remaining fluoride is urgently required around the hydrofluoric acid leak spot. Fertilizing of dolomite containing Ca and Mg, which can trap fluoride, was prepared as one of the restoration plans. In addition, phosphate fertilizing was added in order to enhance soil ameliorating effects. Furthermore, we recommend the introduction of tolerant plants as the second measure to mitigate fluoride damage. As the tolerant plants to make a new forest by replacing trees died due to hydrofluoric acid gas damage, we recommended Q. aliena and S. china, A. hirta, etc. were recommended as plant species to add mantle vegetation to the forest margin to ensure stable interior environment of the forest.

• Plant Journal
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• v.9 no.3
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• pp.38-42
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• 2013

Submarine gas fields have focused because of the increasing fuel cost, the environmental regulations, and the safety & NIMBY problems. LNG-FPSO which is available for acid gas removal, recovery of the condensate & LPG and Liquefaction in topside process is one of high technology offshore structures. On the other hands, it is necessary to verify the pre-treatment efficiency by the ship motion and to apply to the design for LNG-FPSO. This study is to develop the pre-treatment technology for LNG-FPSO as taking account to the process efficiency by ship motion effects and the area optimization. Based on the simulation results, it founds that hybrid process shows the low circulate rate, the low heat duty and the small size of column dimensions compared to typical amine process. It will be verified the process efficiency in the various conditions by sea states as performing the 6-DOF motion test and CFD simulation.

• Journal of the Korean Wood Science and Technology
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• v.44 no.5
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• pp.629-638
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• 2016

In this study, the effect of inorganic constituents on the physicochemical properties of pyrolytic products produced from empty fruit bunch (EFB) by fast pyrolysis were investigated. Inorganic constituents were removed from the EFB by means of washing treatment with hydrofluoric acid (HF) and distilled water (D.I water). Ash content decreased from 6.2 wt% (EFB) to 2.4 wt% (HF-EFB) and 3.5 wt% (D.I-EFB), respectively. As a result of the inorganic component, a quantity of potassium in EFB has showed the highest removal efficiency in both HF and D.I water (HF: 80.3%, D.I water: 72.8%). Fast pyrolysis was performed with demineralized EFB in the fluidized bed reactor under the temperature of $500^{\circ}C$ at the residence time of 1.3 sec. The yield of bio-oil was determined to 57.3 wt% for HF-EFB and 52.1 wt% for D.I-EFB, respectively. Biochar yield decreased whereas yield of non-condensable gas increased with decreasing inorganic content of EFB. Water content decreased from 26.9% (EFB) to 9.9% (HF-EFB) and viscosity increased from 16.1 cSt (EFB) to 334 cSt (HF-EFB).

• Clean Technology
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• v.28 no.1
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• pp.38-45
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• 2022

CuCl₂-loaded V₂O₅-WO₃/TiO₂ catalyst showed excellent activity in the catalytic oxidation of elemental mercury to oxidized mercury even under SCR condition in the presence of NH₃, which is well known to significantly inhibit the oxidation activity of elemental mercury by HCl. Moreover, it was confirmed that, when SO₂ was present in the reaction gas together with HCl, excellent elemental mercury oxidation activity was maintained even though CuCl₂ supported on the catalyst surface was converted to CuSO₄. This is thought to be because not only HCl but also the SO₄ component generated on the catalyst surface promotes the oxidation of elemental mercury. However, in the presence of SO₂, the total mercury balance before and after the catalytic reaction was not matched, especially as the concentration of SO₂ increased. In order to understand the cause of this, further studies are needed to investigate the effect of SO₂ in the SnCl₂ aqueous solution employed for mercury species analysis and the effect of sulfate ions generated on elemental mercury oxidation. It was confirmed that SO₂ also promotes NO_x removal activity, which is thought to be because the increase in acid sites by SO₄ generated on the catalyst surface by SO₂ facilitates NH₃ adsorption. The composition change and structure of the components present on the catalyst surface under various reaction conditions were measured by XRD and XRF. These measurement results were presented as a rational explanation for the results that SO₂ enhances the oxidation activity of elemental mercury and the NO_x removal activity in this catalyst system.

• Journal of Korea Foresty Energy
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• v.25 no.1
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• pp.9-17
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• 2006

Properties of wood charcoal made from the domestic wood species at $300-900^{\circ}C$ have investigated to understand the correlation between carbonization temperature and chemical and physical characteristics of wood charcoal. In terms of charcoal yield at particular carbonization temperatures, it was drastically decreased until the temperature reaches up to $600^{\circ}C$ and the decrease ratio of yield was reduced at higher temperatures. As the carbonization temperature increased, pH of the wood charcoal increased so that it became basic at last. The wood charcoal prepared at $600{\sim}700^{\circ}C$ showed the highest caloric value and those of wood charcoals made at higher temperature became plateau at a little lower level than the peak. The caloric value of Japanese larch charcoal was a bit higher than that of Red oak charcoal. The carbon content in the wood charcoal was increased as the carbonization temperature increased, whereas the hydrogen content was decreased. Specific surface area of the wood charcoal became larger with increase in temperature up to $600^{\circ}C$ but it was decreased or reduced in the increasing ratio after, and then it rose again at higher temperature than $800^{\circ}C$. Absorption capacity of the wood charcoal against iodine and gaseous acetic acid became greater as the carbonization temperature increased. Japanese larch charcoal presented higher absorption capacity than Red oak charcoal. As the above results, it is revealed that carbonization temperature affects the chemical and physical properties of wood charcoal. Therefore, to use wood charcoal with maximum effect it should be prepared at optimum temperature for proper use.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.40 no.2
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• pp.163-170
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• 2014

Lipid membranes composed of phosphatidylcholine (PC) are used in biophysical study to mimic cellular membranes and interactions between the membrane and chemicals, where organics solvents are used in dissolving lipids or chemicals. Later, solvents are removed from the solution under nitrogen gas at room temperature, followed by the further removal of the solvent at vacuum condition for several hours. In this process, some solvents are easily removed under described conditions above and others are required more severe conditions. In this study, $^{31}P$ solid-state nuclear magnetic resonance (SSNMR) techniques and differential scanning calorimetry (DSC) were used to see any changes in the line shapes of $^{31}P$ NMR spectra of multilamellar vesicles (MLVs) samples of POPC and in the phase change temperature of multilamellar vesicles (MLVs) of DPPC in DSC thermogram with or without any residual solvents. The thermodynamic parameters associated with the solvents did exhibit noticeable changes depending on solvent types. Thus, it is concluded that solvents should be carefully chosen and removed completely and experimental results should also be interpreted with caution particularly for the experiments investigating lipid phase changes and related topics.

• Applied Biological Chemistry
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• v.34 no.4
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• pp.373-378
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• 1991

The skin and fleshy substance on the net fiber of sponge-gourd fruit pressed mechanically was removed with 0.2% NaOH solution in $3{\sim}5$ hours. The treatment of 0.2% NaOH with 0.02% Monopol(non-ionogenic polyoxethylen derivative) as surfactnat and with 0.1% $Ca(OCl)_2$ as bleaching agent enhanced the effect to remove the fleshy substance and improve the quality of net fiber. Also, the wet hardness and tensile strength of net fiber were controlled by the crosslinkage of the fiber with glu tardialdehyde, glyoxal, and formalin, respectively. The net fiber was stable on the acid and alkaline solutions. Also the range of temperature to degradate the fiber was $338{\sim}385^{\circ}C$. These values indicated a fair stability. The improved net fiber can be used for raw material of bath, dish washing, oil and gas filter, and many kinds of decorations.