• Textile Coloration and Finishing
• /
• v.4 no.2
• /
• pp.55-63
• /
• 1992

The effects of benzyl alcohol on the properties of dyeing kinetic of silk fibroin were studied. The acid dye used was C.I. Acid Red 114. The half dyeing time is shorten by addition of benzyl alcohol. The diffusion activation energy is higher with the increase of the solvent. The rate of dyeing at benzyl alcohol addition to the purified silk fibroin is faster than that of the unpurified one.

• Textile Coloration and Finishing
• /
• v.24 no.1
• /
• pp.8-17
• /
• 2012

In order to dye nylon/cotton blended fabrics in solid colors with only acid dyes, a hetero-bifunctional bridge compound (DBDCBS) was examined. The bridge compound was designed to react only onto cotton fabrics first, on which amino-containing acid dyes react later by covalent bonding. By the effect of DBDCBS, amino-containing acid dyes exhibited high affinity toward the cotton fabrics. From the dyeing properties examined at various conditions, the optimum dyeing was decided at pH 4 and $100^{\circ}C$. Consequently, the solid color was obtained on nylon/cotton blended fabrics in one bath dyeing process using only acid dyes. The DBDCBS did not show any negative effect on nylon side in terms of dyeing and physical properties.

• Textile Coloration and Finishing
• /
• v.11 no.2
• /
• pp.46-54
• /
• 1999

The conventional dyeing of wool/cotton blends involves a two bath two step method, i.e., after dyeing of the wool component with acid dyes in an acidic dyebath at $100^\circ{C}$, the dyeing of the cotton component with reactive dyes in an alkaline dyebath is performed. In order to overcome the disadvantage of the conventional two bath two step dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in time, energy and water usage. To improve dyeing property of wool/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of wool/cationized cotton blends with acid dye/reactive dye by one bath two step method.

• Textile Coloration and Finishing
• /
• v.16 no.5
• /
• pp.1-7
• /
• 2004

Because acid dyes and reactive dyes require acidic condition for adsorption and alkaline condition for fixation respectively, it is difficult to dye nylon/cotton blends in one-bath one-step dyeing method. In this paper we tried to find out the suitable dye and dyeing condition for one-bath one-step dyeing of nylon/cotton blends. MNT type reactive dyes showed higher exhaustion on cotton as compared with MCT type dyes at neutral pH, which means that the MNT type reactive dyes are preferable for one-bath one-step dyeing method. The optimum condition for one-bath one-step dyeing of nylon/cotton blends was found to be pH 7. Wash fastness of fabrics dyed with half-milling type acid dyes was superior to that of fabrics dyed with levelling type acid dyes, when MNT type reactive dyes were used together.

• Textile Coloration and Finishing
• /
• v.1 no.1
• /
• pp.47-53
• /
• 1989

The effect of organic solvent in the dyeing of silk fiber by acid dye was investigated. Acetophenone and benzyl alcohol were shown to be the most effective for the rate of dyeing of silk fiber by Milling Cyanine 5R (C.I. Acid Blue 113), a milling type acid dye, but, with benzyl alcohol, the equilibrium dye uptake was much lower than that in the absence of it. In the presence of solvent, maximum dye uptake shifted to lower temperature than 6$0^{\circ}C$, while without solvent, it was shown at about $60^\circ{C}$. When dyed by Orange II (C.I. acid Orange 7) under same condition equilibrium dye uptake of silk fiber was lower than that for milling type acid dye, and in the presence of benzyl alcohol, still much lower uptake resulted. All these fact reveals that organic solvents in the solvent-assisted dyeing of silk fiber broaden micelle spacings too much, resulting in increased rate of dyeing, and decreased equilibrium dye uptake, contrary to wool.

• Textile Coloration and Finishing
• /
• v.23 no.4
• /
• pp.250-256
• /
• 2011

In this work, the effects of surfactant and solvents, such as benzyl alcohol and n-propyl alcohol, on the human hair dyeing with acid dye was investigated including the amount of dyes in hair according to dyeing time, temperature, and pH. And the damage of dyed hair was assessed by water retention, protein release, and SEM images of the dyed hairs. By adding benzyl alcohol in acid dyeing, the dyeing rate was increased and the dyeing equilibrium was established at early stage. The water retention of the dyed hair was increased and the protein release of the dyed hair was decreased. Therefore the hair was damaged less during the dyeing.

• Textile Coloration and Finishing
• /
• v.16 no.4
• /
• pp.1-9
• /
• 2004

In recent, development of nano fiber has been one of the most active subjects in the world. Nano fiber is defined as a ultra fine yarn with a diameter unit of $10-100\times10^{-9}meter$, which is possible to be produced by an electro-spinning technology. In this study, physical characteristics and dyeing properties of nylon 66 nano fiber were investigated. Nylon 66 nano fiber was dyed with levelling type acid dyes. X-ray diffraction method and DSC analysis were used for the measurement of the degree of crystallization. Analysis of amino end groups was also performed in order to examine a relationship between number of amino groups and its dyeing property as well as water absorption behavior. The maximum exhaustion % of dyes and dyeing rate under various dyeing conditions, such as dyeing temperature and pH in dye bath, along with build-up properties for 2 acid dyes were evaluated. It was found that the degree of crystallization of nano fiber was smaller than that of regular fiber, and amino end groups of nano fiber were less than regular fiber. Half dyeing time of nano fiber was shorter than regular fiber because of the bigger specific surface area. Effect of pH on exhaustion % was small in case of nano fiber. Exhaustion of nano fiber increased with higher concentration of dye.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2008.10a
• /
• pp.45-46
• /
• 2008

Dyeing and fastness properties of acid dyeable polyurethane have been compared with those of regular polyurethane. The Exhaustion and color strength on acid dyeable polyurethane was relatively better than regular polyurethane at heavy depth dyeing. The washing fastness properties of acid dyes on acid dyeable polyurethane were similar to those of regular polyurethane.

• Textile Coloration and Finishing
• /
• v.20 no.1
• /
• pp.22-27
• /
• 2008

Sulfadiazine and silver sulfadiazine are well-known bactericidal agent routinely used clinical settings. Antimicrobial acid dyes were synthesized by introducing sulfadiazine or silver sulfadiazine and applied on nylon fabric. The Chemical Structure of the Synthesized dyes was identified by HPLC-mass. The dyeability of synthesized acid dyes for nylon fabric was similar to commercial acid dyes. Resistance to washing, rubbing and lightfastness were good. Nylon fabrics dyed with synthesized acid dyes had good antimicrobial properties. Durable antimicrobial properties after 20 times washing have shown good result that reduction ratio of colonies, is 99.9 %. Mixed dyeing were carried out using commercial acid dyes(leveling type) and synthesized dyes. The mixed dyeings have also shown good antimicrobial properties.

• Textile Coloration and Finishing
• /
• v.6 no.3
• /
• pp.67-73
• /
• 1994

The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.