• 제목/요약/키워드: Acid dyeing

검색결과 273건 처리시간 0.023초

모발(毛髮)의 Carotinoid계(係) 색소(色素) 염색(染色)에서 Chitosan 처리순서(處理順序)가 모발(毛髮)의 염색성(染色性)과 역학적(力學的) 특성(特性)에 미치는 영향(影響)

  • 김경선;전동원;김종준;안병태
    • 패션비즈니스
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    • 제11권5호
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    • pp.79-89
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    • 2007
  • The effect of chitosan treatment on the dyeing and dye fastness, and mechanical properties of hair was investigated in this study when the carotinoid dyestuffs extracted from African Marigold(Tagetes erecta L.) were applied to the hair. The sequences of the chitosan treatment were changed in dyeing and mordanting procedures, i.e., pre-treatment, mid-treatment, and post-treatment. While the effect of chitosan application on the color shade change was not significant, the pre-treatment of the chitosan increased the dye uptake. Discoloration and fading was observed in the lightfastness test when chitosan was mid-treated. Alkali perspiration and acid perspiration fastness test results showed that chitosan post-treatment gave lower tendency. Washing fastness results showed that chitosan post-treatment and mid-treatment gave lower values, which indicates that chitosan deters the direct formation of insoluble complex among fiber-dyestuff-mordant. In the mechanical characteristics results, however, initial modulus and breaking strength increased significantly in the post-treatment and pre-treatment of chitosan.

세피아 멜라닌에 의한 양모 염색 (Wool Dyeing with Sepia Melanin)

  • 김수진;권혜륜;유정화;장진호
    • 한국염색가공학회지
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    • 제22권1호
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    • pp.14-20
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    • 2010
  • Squid ink was purified to melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions. The exhaustion dyeing conditions of melanin to wool fabrics were investigated in relation with pH, melanin concentration, dyeing temperature and time. The melanin was dyeable to cotton and wool fabrics but higher dyeability of the wool was observed. A K/S of 7 was obtained on the optimally dyed wool fabrics with 5 % owf melanin under pH 4 at $100^{\circ}C$ for 60 minutes. Color fastness to both washing and rubbing was excellent and color fastness to light was also very good probably due to the polymeric nature of the extracted sepia melanin.

Synthesis, Structure Investigation and Dyeing Assessment of Novel Bisazo Disperse Dyes Derived from 3-(2'-Hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones

  • Metwally, M.A.;Bondock, S.;El-Desouky, S.I.;Abdou, M.M.
    • 대한화학회지
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    • 제56권3호
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    • pp.348-356
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    • 2012
  • In an attempt to find a new class of bisazo disperse dyes with better dyeing properties, a series of novel bisazo dyestuffs based on 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones $\mathbf{3a-f}$ were prepared by diazocoupling of p-nitrophenyl diazonium chloride with 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones $\mathbf{2a-f}$. Compounds $\mathbf{3a-f}$ were subsequently reacted with acetic anhydride in the presence of p-toluenesulfonic acid afford the corresponding O-acetyl derivatives $\mathbf{4a-f}$. The latter products as well as spectral data indicated that compounds $\mathbf{3a-f}$ exist predominantly in the azo-hydrazone tautomeric form (H) as the ZE-configuration. Additionally, two series of the synthesized dyes $\mathbf{3a-f}$ and $\mathbf{4a-f}$ were applied as disperse dyes for dyeing polyester fabrics and their fastness properties were evaluated. Also the position of color in CIELAB coordinates ($L^*$, $a^*$, $b^*$, $H^*$, $C^*$*) was assessed.

Effect of Enzymatic Hydrolysis on Polylactic Acid Fabrics by Lipases from Different Origins

  • Lee, So-Hee;Song, Wha-Soon
    • 한국의류학회지
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    • 제36권6호
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    • pp.653-662
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    • 2012
  • This study measured the effect of general pre-treatment on PLA fabrics to confirm the benefits of enzymatic processing on PLA fabrics in the textile industry as well as evaluated the hydrolytic activities of three lipases. The effects of lipase hydrolysis were analyzed through moisture regain, dyeing ability, tensile strength, and surface morphology. As a result, PLA fibers were easily damaged by a low concentration of sodium hydroxide and a low treatment temperature. The optimal treatment conditions of Lipase from Candida cylindracea were pH 8.0, $40^{\circ}C$, and 1,000 U. The optimal treatment conditions for Lipase from Candida rugosa were pH 7.2, $37^{\circ}C$, and 1,000 U. The optimal treatment conditions for Lipase from Porcine pancreas were pH 8.0, $37^{\circ}C$, and 2,000 U. The moisture regain and dyeing ability of PLA fabrics increased and the tensile strength of PLA fabrics decreased. The results of surface morphology revealed that there were some cracks due to hydrolysis on the surface of the fiber.

BTCA처리 면직물의 질소계양이온화제 첨가에 의한 염색성 향상에 관한 연구 (A study on Improving the Dyeability of BTCA treated Cotton Fabrics Containing Nitrogenous Cationic Additives)

  • 박은경;유효선
    • 한국의류학회지
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    • 제24권6호
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    • pp.819-827
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    • 2000
  • The purpose of this study is to produce cotton fabric having improved dyeability and colorfastness as well as retaining the desirable durable press property. When cotton fabric was treated with additives, nitrogen content was increased as the additive concentration was increased. DP ratings and wrinkle recovery properties of BTCA treated cotton fabrics were greatly increased. But DP rating was lowered slightly by adding additives and wrinkle recovery property was decreased with the increase of additive concentration. Tensile strength was decreased by BTCA treatment but increased as additive concentration was increased. Various BTCA/additive treatments produced great affinity for reactive and acid dyes when dyebaths were adjusted at pH 3. It was showed that dyeability was increased as additive concentration was increased. The most effective additive for improving the dyeing properties of the crosslinked cotton was TEAㆍHCl. In case of reactive dye, there was almost no improvement on the dyeability of finished cotton by adding salt. Color fastness to washing and light of finished and dyed cotton were low except for the washfastness of reactive dye. Dyeing the BTCA/additive treated cotton fabrics with reactive dye had no effect on the physical properties.

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상압 저온 플라즈마 전처리한 폴리아미드계 직물의 색농도 (Color Depth of Polyamide Fabrics Pretreated with Low-Temperature Plasma under Atmospheric Pressure)

  • 이문철
    • 한국염색가공학회지
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    • 제5권2호
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    • pp.134-138
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    • 1993
  • Wool, silk and nylon 6 fabrics were treated with low-temperature plasma under atmospheric pressure of acetone/argon or helium/argon for 30 and 180 sec, and then dyed with leveling type acid dye, C.I. Acid Red 18 and milling type acid dye, C.I. Acid Blue 83. In spite of short time of the plasma treatment for thirty seconds, the color depth of wool fabrics was increased remarkably with both of the plasma gases, aceton/argon or helium/argon and with the kinds of dyes i.e., levelin type or milling type. But the atmosperic low-temperature plasmas did not increase the depth of silk and nylon 6 fabrics dyed with both of the acid dyes regardless of the teated time and plasma gases. It seems that low-temperature plasma by atmospheric-pressure discharge is effective for improvement of dyeing of wools as is the same way with the low-temperature plasma by glow discharge. The kinds of plasma gases and treated time did not influnce the depth of wool fabric pretreted with the atmosperic low-temperature plasmas.

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UV조사에 의한 양모직물의 염색성 개질 (Modification of Dyeing Property of Wool Fabrics by UV Irradiation)

  • 전영실;남성우;김인회
    • 한국염색가공학회지
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    • 제16권1호
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    • pp.10-17
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    • 2004
  • Wool fabrics were treated with deep UV for 10 to 30min and then dyed with C.I. Acid Yellow 99, C.I, Acid Red 57 and C.I. Acid Blue 62. FT-IR and XPS have been used to prove the chemical composition of wool fiber surfaces. The mechanical property and colorfastness were also studied. The intencities of the peaks of C=O group at $1700^cm^{-1}$ were increased with increasing irradiation time. Relative $O_{1s},\; N_{1s}\; and\; S_{2p}$ intensities increased considerably and oxygen was incorporated in the form of CO and COO on the fiber surface. The dye uptakes of wool fabrics dyed with three acid dyes were proportional to irradiation times and in inversely proportional to irradiation distances. It was found that the tensile strength of wool fabrics were gradually deteriorated with the UV irradiation times. The colorfastness, such as washing, light and rubbing, of UV irradiated wool fabrics dyed with acid dyes were good.

Improvement of Light Fastness of Berberine Colorant by Natural Antioxidants

  • Kim, Tae-Kyeong;Kim, Eun-Kyung;Jeong, Jong-Seok
    • 한국염색가공학회지
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    • 제19권2호
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    • pp.1-6
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    • 2007
  • In order to improve the light fastness of a natural colorant berberine, several natural antioxidants such as gallic acid, L-ascorbic acid, and ${\alpha}-tocopherol$ were applied by aftertreatment method. Even though the increase in light fastness of berberine colorant was not substantial, L-ascorbic acid was the most effective. It was considered that this improvement of the light fastness was due to high antioxidation action of L-ascorbic acid to colorant, which led very highly excited species of the colorant formed by photo-energy to return to the original stable state without being decomposed.

감초추출물에 의한 면직물의 염색성과 기능성(I) - 머서화, 탄닌산처리에 의한 면직물의 농색화 - (Dyeing and Functional Property of Cotton Fabrics dyed with Glycyrrhizae Radix Extract(I) - The Color Depth of Cotton Fabrics by Mercerization & Tannic Acid Treatment -)

  • 이영숙;장정대
    • 한국의류산업학회지
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    • 제12권4호
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    • pp.523-530
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    • 2010
  • The purpose of this research was to raise K/S value by mercerization and tannic acid treatment in cotton fabrics. K/S value was 2.84-3.56 in mercerized none-mordant fabrics and it is 5.12-5.36 in tannic acid treatment. As the result, it showed higher in processed cotton fabrics than in unprocessed ones. Processed cotton fabrics had high K/S value in pH 3, pre-mordant. Antibacterial activity showed 99.9% in tannic acid and Cu mordanted fabrics. Deodorization and UV-cut effect were showed a higher effect in dyed fabrics than in undyed ones.

선인장 열매의 색소 추출물에 의한 양모섬유의 염색 (Dyeing of Wool Fabric by the Pigment Extracted from Opuntia Ficus-indica)

  • 이세희;조용석;최순화
    • 한국염색가공학회지
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    • 제18권2호
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    • pp.8-14
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    • 2006
  • The pigment extraction of Opuntia ficus-indica has been conducted to develop useful natural dyes in place of synthetic dyes which are suspected to bring serious environmental pollutions. The dyeing ability on wool fabric by addition of ascorbic acid and several mordants were investigated by means of color measurement. In addition, the fastness of washing, perspiration, rubbing, light, dry cleaning, effect on bacterial reduction and UV-B protection were also investigated. From these investigation, it is suggested that the pigment extracted from Opuntia ficus-indica can be used as a source of natural dyes and the obtained result are as follows. 1. Maximum absorption band (${\lambda}max$) of Opuntia ficus-indica extract is 533nm. 2. The wool fabric dyed with Opuntia ficus-indica extract has stable color by the addition of ascorbic acid and is achieved with addition of 0.1% ascorbic acid, 0.5% several mordant, and three repeated dying at $50^{\circ}C$ for 1.5hr. 3. The wash fastness of the dyed wool fabric when it is washed with neutral detergent is more effective than alkaline detergent. The dry cleaning fastness of the dyed wool fabric is more excellent. In addition, the perspiration fastness of the dyed wool fabric is increased by mordanting method. And than the rubbing fastness of the dyed wool fabric is showed excellent under dryness and wetness. Light fastness of the dyed wool fabric, however is showed inferiority. 4. The wool fabric dyed with Opuntia ficus-indica extract is showed effective bacterial reduction and UV-B protection is increased remarkably.