• Title/Summary/Keyword: Acid dyeing

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Study on the Removal of Fluorescent Whitening Agent by Pretreatment Ozone Oxidation for MBR Process Application (MBR 공정 적용을 위한 전처리 오존산화에 의한 형광증백제 제거 연구)

  • Choi, Jang-Seung;Ryu, Seung-Han;Shin, Dong-Hun;Lee, Jae-Hun;Lee, Soo-Chol;Kim, Sung-Gi;Ryu, Jae-Young;Shin, Won-Sik;Lee, Seul-Ki;Park, Min-Soo
    • Textile Coloration and Finishing
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    • v.29 no.1
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    • pp.11-17
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    • 2017
  • In this study, ozone oxidation experiment was carried out for the removal of fluorescent whitening agent which is widely used in textile dyeing and paper industry. The stilbene fluorescent whitening agent has been industrialized since the earliest, and the amount of current production is the highest. Due to the characteristics of the fluorescent whitening agent that can not be removed by conventional wastewater treatment methods, the fluorescent whitening agent in wastewater treatment has difficulty in using as recycled water in the process. Pre-treatment ozone oxidation experiment was conducted prior to the introduction of Membrane Bio Reactor(MBR) treatment process by converting biodegradable materials into biodegradable materials. The removal efficiencies of fluorescent whitening agents, a diaminostilbenedisulfonic acid derivative by ozone oxidation were evaluated by $UV_{254}$ Scan, $COD_{Mn}$, T-N and color using a synthetic wastewater sample ($COD_{Mn}=433.0mg/{\ell}$) and paper and paper mill wastewater ($COD_{Mn}=157.2mg/{\ell}$).

Dyeing Properties of Silk Fabrics with Pteridium aquilinum Extract (고사리잎 추출액을 이용한 견직물 염색성)

  • 정진순;설정화;장정대
    • Journal of the Korean Society of Clothing and Textiles
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    • v.27 no.3_4
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    • pp.364-372
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    • 2003
  • In this study, the characteristics of catechol tannin and pyrogallol tannin contained in Pteridium aquilinum were analysed by It spectrum. Silk fabrics were dyed with Pteridium aquilinum extracts using various mordants, and their dyeing properties were discussed. Additionally the fastness the water digestion, perspiration liquid digestion and light irradiation were investigated. IR spectrum of catechol tannin showed bands of O-H at $3417cm^{-1}$, C-H at $2930cm^{-1}$, C=0 at $1722cm^{-1}$, C=C at $1644cm^{-1},\;CH_2\;at\;1402cm^{-1}$. And IR spectrum of pyrogallol tannin showed bands of O-H at $3409cm^{-1}$, C-H at $3003cm^{-1}\;and\;2933cm^{-11}$, C=0 at $1701cm^{-1}$, C=C at $1582cm^{-11},\;CH_2\;at\;1410cm^{-1}$, CO at carboxylic acid and carboxylic acid ester at $1287cm^{-1}\;and\;1135cm^{-1}$. The maximum absorption wavelength of the extracts appeared at 270.0nm and 311.5nm. The optimum conditions for dyeing silk fabric with Pteridium aquilinum extracts were $80^{\circ}C$, 60min. Surface color of the silk fabric dyed with Pteridium aquilinum extracts was 2.7Y Surface color of the pre-mordanted fabrics with Al, Cu and Fe were 4.3Y, 2.5Y and 4.7Y, respectively. And Surface color of the post-mordanted fabrics with Al, Cu and Fe were 3.7Y, 2.8Y and 0.2GY. The water fastness and the alkaline perspiration fastness were improved in the Al-mordanted silk fabrics. By acidic and alkaline perspiration treatment, ${\Delta}E of the unmordanted fabrics was lower than hat of pre- and post- mordanted fabrics. Also after 40hour irradiation, ${\Delta}E of the unmordanted fabrics was lower than that of pre- and post- mordanted fabrics.

Construction of Dyeing Condition System for Lithospermum erythrorhizon by Applying Natural Dye and Mordants (천연 염료와 매염제의 응용에 의한 Lithospermum erythrorhizon의 염색 조건 시스템 구축)

  • Jung, Suk-Yul
    • Journal of Internet of Things and Convergence
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    • v.6 no.4
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    • pp.33-38
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    • 2020
  • It was reported that a mobile application was designed to easily provide natural dyeing information such as natural dye related resources, colors and dyed fabrics in 2007. Since studies on the linkage, application, etc. between natural dye dyeing and IoT are still lacking, diversity of information on the change of dyeing pattern by natural dye dyeing is required. In this study, it was to construct dyeing information by natural dyes, e.g., Lithospermum erythrorhizon, on silk, which has been traditionally used as many fibers in Korea. The extraction of the dye from L. erythrorhizon was carried out under pH4. The dried root of L. erythrorhizon showed dark brownish purple. Silk fabric by a without a mordant typically showed a purple dyed pattern. In the staining by sodium tartrate plus citric acid, silk fabric was stained clear brown. Interestingly, the mordant of iron (II) sulfate, the silk fabric was dyed in a light gray color rather than black. When the mordant of aluminum potassium sulfate was treated with L. erythrorhizon-extracted dye, the results were almost the same as when the mordant was not treated. When the degree of dyeing was evaluated numerically, the treatment of the mordant of potassium dichromate was about 50% darker, and the dyeing by iron (II) sulfate was about 75% darker. These results will be helpful in the study of applying various dye colors using L. erythrorhizon, and it will provide information on dyeing controller and database system construction by dyeing parameters such as dyeing degree, pH concentration, and chromaticity change.

Establishment of Dyeing Data for Silk Fabrics and Cells Using Diospyros kaki Thunb (감나무 열매를 이용한 실크 및 세포에 대한 염색 데이터 확립)

  • Suk-Yul Jung
    • Journal of Internet of Things and Convergence
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    • v.9 no.3
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    • pp.27-33
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    • 2023
  • In this study, it was analyzed with the dyeing pattern of Diospyros kaki Thunb (persimmon) and was tried to numerically evaluate how the dyeing pattern in silk fabrics and cells was changed by different mordants. When the dyed silk fabrics were sufficiently dried, the silk fabrics were found to have a pale yellow color. Interestingly, iron II sulfate mordant changed the color change the most, silk fabrics were dyed with a color close to brown or dark purple. For numerical analysis, 19% and 62.5% color changes could be induced by sodium tartrate plus citric acid and copper acetate, respectively. Iron II sulfate induced the greatest difference than that of untreated mordants at 88%. About 5% and 10% of Chinese hamster ovary (CHO) cells were stained by sodium tartrate plus citric acid and copper acetate, respectively. The staining effect induced by iron II sulfate was about 2.4 times higher than the staining effect by sodium tartrate plus citric acid. In previous studies, staining results have been visually confirmed. However, this results not only visually confirmed the dyeing, but also quantified the color change. In particular, if numerical results are continuously integrated into big data, any researcher will be able to easily obtain similar results even if the method, time, volume, etc. are changed. In addition, the numerical data of this study is considered to be an important basis for building a database for IoT construction and computer analysis.

The study of Phellodendron amurense Rupr. Dyeing (황벽의 염색성에 관한연구)

  • 소황옥
    • Journal of the Korean Society of Costume
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    • v.27
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    • pp.121-132
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    • 1996
  • This study showed the proper pigment extract in the Phe. Dyeing which is the basic dye of the natural plants dyeing,. Also it compared and examined the K/S the promotion of the color fastness and the effect of color difference change were attended by mordants and method of mordanting. 1. The most absorbance of Phellodendron. sol-ution is 330nm berberine is 430nm. 2. The best and proper temperature to extrat Phe,. was 80 and dyeing solution for 24 hours. 3. The pH effect was stable in the absorbances and color differences change. 4. Mordanted group increased the absorbances compared to non-mordanted sample. In case depth the most absorbance of Al. Sn. K. Cu and C. A solution were in 3% Fe and Cr were in 5%. In the color difference change they became dark reduced greenish and increased yellowish when their absorbances were in 3% 5. K./S was recoginzed by tainnin and fe, K/S was more increased pre-mordants than post-mordants. 6. Fe is the unchangable mordant in the color difference change and pre-mordants is more stable than post-mordants in the difference color. 7. Generally light C. F indicated more than grade 2 and light C. F, was much improved in post-mordanted by alumium potassium potass-ium dichromate. Washing C.F was improved in mordanted by tainnin and ferrous suulfate mordanted group was better than non-mordanted sample. Perspir-ation C,F was more stable in acid than alkali. Dry cleaning C.F indicated more than grade. 4.

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Effect of Treating Conditions on Dyeing Property of Anti-Shrinkage Wool Fabric Treated with Chlorination and Monoethanol Aminesulpbite Resin (염소화/Monoethanol Aminesulphite 방축가공의 처리조건이 양모직물의 염색성에 미치는 영향)

  • Hwang, Back-Soon;Lee, Ja-Ho;Park, Jung-Whan;Kim, Duk-Ly
    • Fashion & Textile Research Journal
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    • v.3 no.3
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    • pp.283-289
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    • 2001
  • Shrink resist finishing of wool fabric was carried out with Monoethanol aminesulphite (MONAMIN BTN) shrink resist agent after chlorination with Dichloro isocyanuric acid (DCCA). The purpose of this study is to investigate the effect of treating conditions, such as concentrations of DCCA and MONAMIN BTN, pH of treating bath, dyeing times, curing times and temperatures, on dyeing property of wool fabrics. K/S values and fastness properties of dyed wool fabrics were measured. The K/S values of dyed fabrics were increased gradually with increasing concentration, and decreased with increasing curing time. The optimum dyeing time and curing temperature were 60 min and $140^{\circ}C$, respectively. Also it seems likely that the shrink resist finishing carried out at 3% (o.w.f.) of MONAMIN BTN and pH 7 of resin treating bath is effective in increasing K/S values. Light fastness of fabric dyed was very poor and the fastness of fabric dyed was not influenced by the treatment conditions.

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PCM/Nylon6 복합사 염착특성

  • Lee, Jun-Hee;Kim, Hyung-Joo;Yim, Sang-Hyun;Im, Jung-Nam;Son, Young-A
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.35-35
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    • 2011
  • Phase change material(PCM) has thermal energy storage and been attracted attention. Latent heat of the organic PCM can keep maintaining temperature when the change of outside energy conditions influence to PCM. Thus, many researchers have interested to thermal energy storage ability and investigated to applications such as thermal storage of solar energy, bioclimatic building, icebank, medical application, clothing industry and so on. Among the many applications, investigation of the PCM in clothing industry is also important because the people has interest functional factor called health-care in the clothing. In addition, PCM can give them mild environment condition such suitable temperature control or humidity. To fabrics, the PCM has various methods such as microcapsule, padding and modified cross-section formation(Sheath/core). Sheath core PCM fabric has a better benefit of durability than other method. However, PCM sheath/core spinning is difficult. In addition, dyeing property is important to use clothing industry due to visual images. In this study, we investigated dyeing properties of Nylon/PCM sheath/core fabrics. Especially, we observed the relation between dyeing property and PCM including ratio. Various temperature and pH conditions were also studied to optimize dyeing properties as acid dye.

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Correlation Relationship between Personal Exposure and Biological Monitoring for Airborne Toluene in an Industrial Complex and General Environments (산업단지 및 일반생활 지역의 공기 중 톨루엔에 대한 개인노출 및 생체시료의 상관성 분석)

  • Lee, Byoungjun;Heo, Jung;Jung, Dayoung;Kim, Sunshin;Ryu, Hyeon-Su;Choi, Min-Ji;Shuai, Jian-Fei;Im, Sung-Guk;Yang, Wonho
    • Journal of Environmental Health Sciences
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    • v.43 no.4
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    • pp.324-333
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    • 2017
  • Objectives: The purpose of this study was to assess the correlation relationship between personal exposure and urinary hippuric acid in biological monitoring for airborne toluene in an industrial complex and in general environments. Methods: Personal exposure to toluene and its metabolite, hippuric acid, in urine were simultaneously measured in occupational environments area near an industrial complex and in general environments. The study subjects were divided into three types: 137 workers who use organic solvents in the workplace, 210 residents living near a dyeing industrial complex, and 379 residents living in general environments. The toluene exposures of workers and residents were measured by a passive sampler for four days. The urine of participants was sampled when the passive samplers of personal exposure were collected. Results: The toluene and hippuric acid concentrations of workers were the highest, followed by the concentrations of residents living near a dyeing industrial complex and residents living in general environments. The coefficient of correlation between the concentrations of toluene and hippuric acid among workers was 0.749 (p<0.01) in the workplace. On the contrary, correlations between the concentrations of toluene and hippuric acid among residents living near a dyeing industrial complex and residents living in general environments were all not significant. The relationship between the concentrations of hippuric acid and toluene in three types could be described by the exponential growth model. Conclusions: This study analyzed the relationships between toluene exposure and the concentrations of hippuric acid in urine in high, middle, and low exposure environments, and could be described by the exponential growth model.

Effect of Post-treatment Using Acidic Amino Acids during Hair Coloring on Hair Condition (산성 아미노산 후처리가 헤어컬러링 시 모발에 미치는 영향)

  • Lee, Jin Young;Lee, Sang Hyun
    • Journal of the Korea Convergence Society
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    • v.12 no.11
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    • pp.427-434
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    • 2021
  • Modern people express their beauty through hair coloring, but hair can be damaged by repeated chemical treatments. In order to increase the durability of dyeing and minimize the hair damage, in this study, the acidic amino acids including aspartic acid (Asp) and glutamic acid (Glu) were used to post-treat hair during hair coloring. The post-treatment with 0.75% Asp and Glu solution was carried out at room temperature for 20 minutes after dyeing bleached hair with cherry red and blue silver colors. After repeated shampooing of 1, 5, 10, 15, 20, and 25 times, L*a*b* value of dyed hair was measured to confirm the dyeing durability, and the changes in tensile strength, porosity, and surface properties of the hair were also analyzed to determine the condition of the hair. In the case of cherry red and blue silver staining, the Asp and Glu experimental group showed higher color persistence than the control group, and the Asp and Glu experimental group showed higher tensile strength, lower porosity and smooth surface properties than the control group. In particular, the Asp test group showed superior color persistence and lower hair damage than the Glu test group. This study, therefore, if damaged in dyeing and bleaching in the field of hair after treatment with asp glu a combination of hair cosmetics in the development of basic data look forward to be.