• Title/Summary/Keyword: Acid dyeing

검색결과 273건 처리시간 0.023초

나일론의 천연염색과 염색포의 항균성 (Natural Dyeing & Antimicrobiology of Nylon Fabrics)

  • 이혜자;유혜자;김정희;한영숙
    • 대한가정학회지
    • /
    • 제40권11호
    • /
    • pp.93-105
    • /
    • 2002
  • Nylon fabrics and stocking were dyed with artemisia dyeing solution, dyed with the natural dyestuffs that were manufactured from chestnut hulls by boiling in 0.5% NaOH solution and powdering in freeze dryer, and dyed with gromwell dyeing solution. Dyeabilities on nylon fabrics and stocking were good because of being amine group. All the dyed fabrics & stocking showed excellent in color fastness to laundering, and as poor as grade 1 to light fastness. But Light fastness of them could be improved to grade 3 or 4-5 by treatment with gallic acid and by repeated dyeing. Antimicrobial activities of the fabrics dyed with artemisia and gromwell against Staphylococcus aureus and Candida albicans were excellent in the aspect of bacteriostatic and fungistatic. There were not any distinct differences between mordant and non-mordant fabrics.

검정콩 함유 천연 안토시아닌의 염색성 연구 (Studies on the Dyeing Properties of Black Soybean Anthocyanin)

  • 김성연;염선경;이경남
    • 한국의류산업학회지
    • /
    • 제9권1호
    • /
    • pp.103-112
    • /
    • 2007
  • The purpose of this study was to investgate dyeing, moradnting properties and colorfastness activities of silk, polyamide, acetate treated black soybean extracts. The color of extract by buffer solution (pH=1) red, but the higher pH of extracted black soybean solution the paler of color strength. Black soybean extracts was approved anthocyanin of 3type(Delphinidin3-glucoside, Cyanidin 3-glucoside, Petunidin 3-glucoside) by chemiclal analysis. This anthocynin, in acid condition, is oxinium structure (red color, soluable) but, in alkali condition quinoid structure(dark brown, in soluable). The optimum dyeing condition of black soybean anthocynin was 10min at $30^{\circ}C$, pH -1. Colorfastness to washing and light showed generally low but crocking fastness was excellent.

$\alpha$-Bromoacrylamide계 반응염료에 의한 키토산 섬유의 염색 및 가교 (Dyeing and Crosslinking of Chitosan Fibers with $\alpha$-Bromoacrylamide Reactive Dyes)

  • 박병기;박봉수;정용식;이근완
    • 한국염색가공학회지
    • /
    • 제14권3호
    • /
    • pp.26-33
    • /
    • 2002
  • Dyeing properties and crosslinking effect of bifunctional reactive dyes on chitosan fiber were investigated to improve the stability of chitosan fiber against the mild acidic solution and the wet processing. Chitosan fibers were crosslinked with epichlorohydrin for comparing purpose, and dyed with C. I. Reactive Red 194, C. I. Reactive Blue 50, and the reactive dye having two $\alpha$-bromoacrylamide groups at various concentrations. The initial dyeing rates of reactive dyes are rapid and chitosan fibers absorb the relatively large amount of dyes. The chitosan fibers dyed with these dyes show the low degree of swelling and the low solubility in 1 % acetic acid solution and also represent the higher thermal stability The reactive dye with two $\alpha$-bromoacrylamide groups shows higher crosslinking effect than other dyes.

양파 외피에서 추출한 수용성 색소의 분석 (Analysis and Dyeing of Natural Pigments Extracted from Onion Shell(Allium cepa))

  • 배순이;신인수
    • 한국염색가공학회지
    • /
    • 제10권6호
    • /
    • pp.27-32
    • /
    • 1998
  • 도시 Traditionally, dyes extracted from onion shells have been used as natural pigments but dyeing methods with reproducibility have not been developed. In this study, the dyes were analyzed by high performance thin layer chromatography(HPTLC) to obtain the ratio of pigments in water and ethyl acetate extract. Furthermore, the present study was also carried out to obtain the information characteristic of wavelength which proportionally decrease for continuous dyeing reaction. Scanning of water extract showed 4 peaks by the mobile phase of benzene/ethyl acetate/acetic acid(40/10/5) and the peak 1 exhibited yellow color with the maximal absorption spectra of 306nm and 309nm while ethyl acetate extract showed 9 peaks in the same mobile phase. The water extract after ethyl acetate extraction was adjusted to 0.5 of O.D.(optical density) at 550nm by adding of water and compared wavelength of the pigments from 200 to 600nm to find the proportional decrease of wavelength. As the result, it showed that wavelength of 306nm could be the standard of dyeing monitoring points.

  • PDF

중금속 산폐수 처리 후의 상등액을 이용한 염색폐수처리 연구 (A Study on the Treatment of Dyeing Wastewater Using the Supernatant after Treatment of Acidic Metal Wastewater)

  • 신진명;박장진;김미자;주소영
    • 환경위생공학
    • /
    • 제18권1호
    • /
    • pp.41-50
    • /
    • 2003
  • Traditionally the supernatant after chemical treatment of metal acid wastewater is discharged in environment. The supernatant can be used as a coagulant as it contains effective metals. The aim of this study is to investigate the feasibility of treatment of dyeing wastewater using the supernatant after treatment by magnesium hydroxide and dolomite($Ca{\cdot}Mg(CO_3)_2$), of acidic metal wastewater. In dyeing wastewater treatment with the supernatant, optimum pH and dosage were determined. COD, turbidity and color were analyzed to evaluate the performance of treatment. In the case of magnesium hydroxide, the optimum dosage was 10%(v/v) for supernatant A and 3%(v/v) for supernatant B. Color, turbidity and COD removal was 99~100%, 85~97% and 43~53%, respectively. In the case of dolomite, the optimum dosage was 10%(v/v) for supernatant A and 3% for supernatant B. Color, turbidity and COD removal was 96~99%, 62~9l% and 52~53%, respectively.

효소처리에 의한 양모섬유의 개질 (I) (Modification of Wool Fiber by Enzymatic Treatment (I))

  • Park, Jung-A;Park, Jeoung-Young;Lim, Yong-Jin
    • 한국염색가공학회지
    • /
    • 제3권4호
    • /
    • pp.7-12
    • /
    • 1991
  • Wool gabardines were treated with alkaline proteases, and their tensile strerigth and dyeing behavior were obtained. Enzylon ASA 30 and Alcalase 2.5L DX did not show much effect on the weight loss of wool, but Esperase 8.0L decreased the weight of wool to a great extent. Pretreatment of wool with dichloroisocyarturic acid before protease-treatment increased the weight loss of wool considerably. Weight loss was accompanied by serious strength decrease and the use of sodium sulfate in the protease-treatment had not effect on the strength retention, only lowering the weight loss of wool. Protease-treatment of wool increased dyeability considerably, which may be due to the change in the inner structure of wool fiber by protease.

  • PDF

포도과피의 안토이안 색소를 이용한 직물 염색 (Fabric Dyeing Using Anthocyan Pigment from Grape Skin)

  • 고영실;이혜자;유혜자
    • 대한가정학회지
    • /
    • 제38권11호
    • /
    • pp.127-135
    • /
    • 2000
  • The natural dyestuff, grape skin dye was manufactured from grape skin by boiling in 0.1% HCI solution, eliminating the sugar and powdering in freeze dryer. Cotton, wool, silk and nylon fabrics were dyed under several conditions using the manufactured grape skin dye to investigate the dyeability and color fastness. Dyeing was operated in acidic dyebath of pH 4 because the grape skin is anionic. The color of dyed fabrics were affected on temperature of dyeing solution. Under 80$\^{C}$, the color of dyed fabrics were red or violet, but changed to brown in laundering. Above 100$\^{C}$, the color were brown and safe in laundering. Dyeabilities on wool, silk, and nylon fabrics were good, especially silk fabrics were dyed deeper than others. Dyeability was developed with concenturation of dyeing solution. All the dyed fabrics were excellent in color fastness to crocking and laundering. Light fastness was low to moderate. The light fastness of dyed nylon fabrics were as poor as grade 1, but they could be improved to grade 3∼4 by aftertreatment with gallic acid.

  • PDF

자외선조사에 의한 Cation화 면직물의 문양염색 (Pattern Dyeing of Cationized Cotton Fabrics by Ultra Violet Rays Irradiation)

  • 김인희;이인석;남성우
    • 한국염색가공학회지
    • /
    • 제14권2호
    • /
    • pp.77-77
    • /
    • 2002
  • Cotton fabrics dipped in cationic agent(3-chloro-2-hydroxypropyl trimethyl ammonium chloride) were irradiated with deep Ultra Violet Rays(UV), in the region of UV-C using the low pressure mercury lamp. The chemical changes of cationized cotton fabric surfaces were investigated by FT-IR analysis. The dyeabilities of the irradiated portions were investigated by dyeing with acid dyes. Deep UV(UV-C) irradiation broke O-H bonds in cotton fiber and oxidized the fibers. The dyeability of the UV irradiated portion were different from that of the portion not irradiated. Various pattern were gained from one bath dig dyeing by pattern mask. The tensile strengths of cotton fabrics were decreased in the UV irradiated portion. Washing fastness of cotton dyeings were good about 3∼4 grade and light fastness were fair about 2∼3 grade.

자외선조사에 의한 Cation화 면직물의 문양염색 (Pattern Dyeing of Cationized Cotton Fabrics by Ultra Violet Rays Irradiation)

  • 김인회;이인석;남성우
    • 한국염색가공학회지
    • /
    • 제14권2호
    • /
    • pp.1-8
    • /
    • 2002
  • Cotton fabrics dipped in cationic agent(3-chloro-2-hydroxypropyl trimethyl ammonium chloride) were irradiated with deep Ultra Violet Rays(UV), in the region of UV-C using the low pressure mercury lamp. The chemical changes of cationized cotton fabric surfaces were investigated by FT-IR analysis. The dyeabilities of the irradiated portions were investigated by dyeing with acid dyes. Deep UV(UV-C) irradiation broke O-H bonds in cotton fiber and oxidized the fibers. The dyeability of the UV irradiated portion were different from that of the portion not irradiated. Various pattern were gained from one bath dig dyeing by pattern mask. The tensile strengths of cotton fabrics were decreased in the UV irradiated portion. Washing fastness of cotton dyeings were good about 3∼4 grade and light fastness were fair about 2∼3 grade.

Glyoxal/Hydrogen peroxide-Redox System을 사용한 견직물의 저온염색 (Low-temperature Dyeing of Silk Fabrics using a Glyoxal/Hydrogen peroxide Redox System)

  • 이내연;백두현;임종열;임영훈
    • 한국염색가공학회지
    • /
    • 제6권1호
    • /
    • pp.1-7
    • /
    • 1994
  • A low-temperature dyeing system for silk fabrics based on a redox system has been investigated. Some factors affecting dyeing of silk fabrics with levelling acid dyes in the absence and presence of certain redox system were investigated under different conditions. The variables studied were; type and concentration of redox system, dyeing conditions, i. e. temperature and time, dye concentration, material-to-liquor ration(LR) and colour fastness. The colour strength(K/S value) is outstandingly higher in the presence than in the absence of redox system. A comparison between the colour strength values of such dyeings abtained the three redox system would call for the following order ; Glyoxal/hydrogen peroxide>thiourea/hydrogen peroxide>glucose/hydrgen peroxide> nothing. In the presence of redox system, free radicals are supposed to be formed in both the fiber and the dye and the interaction between these free radicals bring about covalent fixation beside the usual electrostatic bonds, hydrogen bonds and Van der Waals forces.

  • PDF