• Title/Summary/Keyword: Acid and Alkali

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The Antimutagenic Activity of Sulfated Alginate and Its Effect on the Growth of Lactobacillus acidophillus (황 흡착 알긴산의 Lactobacillus acidophillus 성장에 미치는 영향 및 항 돌연변이 작용)

  • 강경금;박난희;김정목
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.4
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    • pp.757-761
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    • 2004
  • The alginate extracted from Hizikia fusiform by the acid alkali soluble alginate (AASA) extraction method was reacted with Na$_2$SO$_4$. The amount of sulfate absorbed in the 3% alginate solution was determined about 18,435 ppm by inductively coupled plasma-atomic emission spectrometry. Both alginate and S-alginate stimulated the growth of Lactobacillus acidophilus in MRS broth and peptone water medium. The addition of S-alginate to the media showed the higher bacterial numbers than alginate supplement. There was no mutagenic activity of S-alginate in the Ames test using the Salmonella Typhimurium TA98 and TA100 strains. The S-alginate showed suppressive effect against 2-NF and MMS of mutagens.

Biodiesel Production from Waste Oils Mixed with Animal Tallows and Vegetable Oil by Transesterification Using Ultrasonic Irradiation (초음파를 이용한 동식물성 혼합 폐유지로부터 바이오디젤 제조)

  • Chung, Kyong-Hwan;Park, Byung-Geon
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.487-492
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    • 2013
  • Transesterifications of waste oils mixed with animal tallows and vegetable oil by ultrasonic energy were examined over various catalysts for biodiesel production. Reaction activities of the transesterification were evaluated to the ultrasonic energy and thermal energy. The physicochemical properties of feedstock and products were also investigated to the biodiesels produced from the oils in the reaction using ultrasonic energy. The highest fatty acid methyl ester (FAME) yield was obtained on the potassium hydroxide catalyst in the transesterification by ultrasonic irradiation. The effective reaction conditions by ultrasonic energy were 0.5 wt% catalyst loading and 6:1 molar ratio of methanol to the mixed oils. The reaction rate of the transesterification by ultrasonic energy was faster than that by thermal energy. The highest yields of FAME were obtained as 80% in 5 min and the reaction equilibrium reached at that time.

The Treatment Characteristics of Intermittent Aeration and Conventional Activated Sludge Processes According to the Changes of Temperature and pH (온도 및 pH 변화에 따른 연속 및 간헐 포기식 활성슬러지법의 처리 특성)

  • Lee, Jeoung-Su;Lee, Tae-Kyoo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1001-1009
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    • 2000
  • This study is to find the utilization of intermittent aeration system, around S-COD, T-COD, SS, timewise changes of treatment performance, sludge conversion yield, changes of temperature and pH, etc. In consequence of this study, factors of temperature correction showed 1.052 on continuous aeration, and 1.056 on intermittent aeration which is more sensitive to temperature through a minute degree. Meanwhile, sludge conversion yield on intermittent aeration showed lower and more economical than that on continuous aeration. In case of changing pH, treatment water of both reactors worsened slightly in acid but improved in alkali. In general. considering the quality of effluent water, variation pH of effluent water, etc. the case of intermittent aeration was more favorable than that of continuous aeration.

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AN EXPERIMENTAL STUDY OF THE EFFECT OF ION EXCHANGE ON STRENGTHENING OF DENTAL PORCELAIN (이온교환법에 의한 치과용도재의 강도증진 효과에 관한 실험적 연구)

  • Lee Young-Kook;Lee Sun-Hyung;Yang Jae-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.29 no.3
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    • pp.75-86
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    • 1991
  • Ion exchange strengthening is a chemical process whereby large alkali ions(such as potassium) are substituted for smaller ions(sodium) within the surfaces of glasses and ceramics, thereby reducing the thermal expansion coefficient of this surface region, and creating beneficial state of compressive stress within the near surface region. The purpose of this study was to determine the effects of ion exchange and etching treatments on the strength of some dental porcelains. Two feldspathic dental porcelains(Vitadur-N, G-Cera) were used in this study. A commercial ion exchange paste and etching gel containing 8% hydrofluoric acid were used for surface conditioning. Transverse strength was measured using a universal testing machine and the technique of EPMA(electron probe micro analysis) was used to access the potassium contents. The results were as follows: 1. Improvement in strength was only obtained by treating the surface placed in tension. 2. No changes in the dimensions of the treated specimens were detected when samples were measured with a micrometer. 3. There was significant increase in transverse strength of G-Cera IV group treated with etching and ion exchange, compared with G-Cera II group only treated with ion exchange. 4. From the results of EPMA test, increase in potassium contents was observed on the surface treated with ion exchange paste.

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Corrosion Characteristics of Reinforced Steel Bar Emedded in Multiple Mortar Specimen(W/C:0.5) Aged 5 Years in Seawater

  • Moon, Kyung-Man;Takeo, Oki;Won, Jong-Pil;Park, Dong-Hyun;Kim, Yun-Hae
    • International Journal of Ocean System Engineering
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    • v.3 no.1
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    • pp.33-37
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    • 2013
  • Reinforced concrete structures have been increasingly widely used in numerous industrial fields. These structures are often exposed to severely corrosive environments such as seawater, contaminated water, acid rain, and the seashore. Thus, the corrosion problems that occur with the steel bars embedded in concrete are very important from the safety and economic points of view. In this study, the effects of the cover thickness on the corrosion properties of reinforced steel bars embedded in multiple mortar test specimens immersed in seawater for 5 years were investigated using electrochemical methods such as the corrosion potentials, polarization curves, cyclic voltammograms, galvanostat, and potentiostat. The corrosion potentials shifted in the noble direction, and the value of the AC impedance also exhibited a higher value with increasing cover thickness. Furthermore, the polarization resistance increased with increasing cover thickness, which means that the oxide film that is deposited on the surface of a steel bar surrounded by alkali environment exhibits better corrosion resistance because the water, chloride ions and dissolved oxygen have difficulty penerating to the surface of the steel bar with increasing cover thickness. Consequently, it is considered that the corrosion resistance of reinforced steel can be improved by increasing the cover thickness. However, the corrosion resistance values of a steel bar estimated by measuring the corrosion potential, impedance and polarization resistance were not in good agreement with its corrosion resistance obtained by polarization curves.

A review on thermochemical pretreatment in Lignocellulosic bioethanol production (목질계 바이오에탄올 제조공정에서 열화학적 전처리에 관한 고찰)

  • Ko, Jae-Jung;Yun, Sang-Leen;Kang, Sung-Won;Kim, Seog-Ku
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.1
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    • pp.79-88
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    • 2008
  • The production of bioethanol, which is one of the alternative fuel, cause the various problem such as agflation in human society. As a substitute for the feedstock, lignocellulosic biomass have a big potential. However, bioethanol production with cellulosic material is not commercialized due to high cost. Thermochemical pretreatment to improve the rate of enzyme hydrolysis and increase the recovery of fermentable sugar, is required in order to achieve the cost down in bioethanol production. In this study, various problems and technologies for pretreatment is introduced. Acid hydrolysis, alkali hydrolysis, steam explosion, organosolv process, ammonia explosion, and wet oxidation pretreatment remove lignin and hemicellulose, and reduce cellulose crystallinity. Optimization of pretreatment process on various sources of lignocellulosic biomass such as softwood, hardwood, and straw should be performed.

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A Study on the Change of Strength of FRP Member Immersed in Chemical Solution (화학약품용액에 침지한 FRP 부재의 강도 변화에 대한 연구)

  • Kim, Ho-Sun;Kim, Woo-Jong;Jang, Hwa-Sup;Kwak, Kae-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.6
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    • pp.117-123
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    • 2010
  • If FRP materials that have been known as high durability materials are exposed to harmful environmental factors, deterioration and characteristics of materials can be reduced due to chemical reaction such as hydrolysis. Therefore, to use FRP materials as building major materials, it is important to exactly grasp dynamic properties by use condition. Accordingly, this study stored FRP materials in a strong acid and alkali compound solution for a certain period to conduct simulation for acute or chronic, extreme changes by chemicals, and conducted a test for compressive, tensile, shear and bending strength to analyze changes in strength by kinds and storage days of chemicals. In conclusion, the study findings indicate excellent chemical resistance of FRP materials.

Changes on the Cell Wall Components of Jujube Fruits during Drying (대추 천일건조 중 세포벽 구성성분의 변화)

  • 손미애;김미현;신승렬;송준희;김광수
    • Food Science and Preservation
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    • v.5 no.4
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    • pp.350-354
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    • 1998
  • This paper was investigated to changes of cell components during drying for studies on the softening of jujube fruits. The contents of alcohol-insoluble material, cell wall and water-soluble material were not changed at 6 days of drying, but alcohol-insoluble materials and cell wall were decreased at 9 days of drying, however water-soluble materials were increased. Pectin and hemicellulose were not changed at 6 days of drying. Pectin and alkali-soluble hemicellulose were remarkable decreased at 9 days of drying, but acid-soluble hemicellulose was increased. Water-soluble pectin was not changed at 6 days of drying, but increased at 9 days of drying. EDTA-soluble and insoluble pectin were decreased after 6 days of drying. The non-cellulosic neutral sugars were not changed at 6 days of drying. The contents of arabinose, galactose and total neutral suger were decreased at 9 days of drying.

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Characteristic Evaluation of FA-Based Geopolymer with PLA Fiber (PLA 섬유를 가진 다공성 플라이애시 기반 지오폴리머의 특성 평가)

  • Kwon, Seung-Jun;Hwang, Sang-Hyeon;Cho, Young-Keun;Kim, Tae-Sang;Moon, Eun-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.187-193
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    • 2019
  • Regarding physical absorption mechanism for fine particles(Dust), internal pore-bridging is a major parameter in porous media. In this paper, internal bridging pore system is invented through FA-based geopolymer and incorporated PLA (Polylactic Acid) fiber with biodegradability. With various mix proportions, compressive strength over 20MPa is obtained but PLA is little dissolved in the condition of NaOH 5mole and $30^{\circ}C$ of temperature, which was found that temperature rising accelerates PLA solubility. Within 24hours, beads type PLA is completely dissolved under $90{\sim}130^{\circ}C$ and NaOH 5~12mole of alkali. In room condition, geo-polymerization is limitedly occurs so that the internal pore after PLA dissolution is thought to be effective to absorption and storage of fine particles.

Incubational Characteristics of Bacillus polymyxa 'HB26-5' Antagonistic to Ginger Rhizome Rot and Its Formulation (생강 근경썩음병 길항균 Bacillus polymyxa 'HB26-5' 균주의 배양적 특성 및 제형화)

  • 이두구;심재성;심형권;이용훈;박홍규
    • Korean Journal of Plant Resources
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    • v.12 no.4
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    • pp.289-296
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    • 1999
  • The availability of Bacillus polimyxa 'HB 26-5' as a biological control agent was investigated. The antagonistic bacteria Bacillus polymyxa 'HB 26-5' grew well on the media at pH 7.0 and the optimum growth temperature was $25^{\circ}C$. The pH of the media changed to weak acid(pH 6.1~6.5) at the beginning of incubation, but to weak alkali(pH 7.8~8.2) at 7days after incubation. The best carrier to enhance colonization of the bacteria were the mixture of rice bran and peat, or rice bran and kaoline, in those formulation the density of the bacteria was changed slightly, though the density was beginning to decrease 3 weeks after application at field. In view of the physical characteristics of the formulation for the density maintenance during storage such as the hardness and the size, the best one was the formulation consisted of sodium alginate 2%, kaolin 15% and rice bran 3%.

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