• Title/Summary/Keyword: Acid and Alkali

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Surface Reflectance Reduction of Multicrystalline Silicon Wafers for Solar Cells by Acid Texturing (Acid Texturing에 의한 태양전지용 다결정 실리콘 기판의 표면 반사율 감소)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Soo-Hong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.99-103
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    • 2008
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controlling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400 nm to 1000 nm) reflectance with acid texturing is 4.64 % less than alkali texturing.

Investigation of Surface Reflectance Reduction for Multicrystalline Silicon Solar Cells with Acid Texturing (Acid Texturing에 의한 다결정 실리콘 태양전지의 표면 반사율 감소에 대한 연구)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Eun-Joo;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.16-17
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    • 2007
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400nm to 1000nm) reflectance with acid texturing is 4.64% less than alkali texturing.

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Effects of Acid and Alkali Treatment for Chestnut Peeling and Its Physical Properties (밤의 박피를 위한 산 및 알카리 처리 효과와 물리적 특성)

  • 김영찬;홍순기;최종욱;이주백;정신교
    • Food Science and Preservation
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    • v.6 no.3
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    • pp.308-312
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    • 1999
  • To develop the effective method for chestnut peeling, we examined the effect of peeling by acid and alkali treatment on their concentration, immersion temperature and time. Furthermore the physical properties of chestnut were investigated. In alkali treatment, 9% NaOH treated at 40$^{\circ}C$ for 9min was the most efficient for peeling outer peel, while acid treatment was less effective. But in the peeling of inner peel, acid treatment was more effective than alkali, especially, 3% HCIO$_4$ treated at 50$^{\circ}C$ for 30 min was the most effective. The correalation coefficient between weight and inner(outer) peel weight was higher than other physical properties, and multiple regression equation was established for predicting inner(outer) peel weight.

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Ion Exchange Characteristics of Novel HDBPDA and Dowex Ion Exchange Resins (새로운 HDBPDA와 Dowex 이온교환수지의 이온교환 특성)

  • Kim, Dong Won;Kim, Chang Suk;Choi, Ki Young;Jeon, Young Shin;Jeong, Young Kyu;Yoon, Yeo Hag;Hon, Choon Pyo
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.463-469
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    • 1993
  • HDBPDA ion exchange resin, {(4, 5) : (13, 14)-Dibenzo-6, 9, 12-trioxa-3, 15, 21, -triazabicyclo [15. 3. 1]heneicosa-(1, 17, 19)(18, 20, 21) triene ion exchange resin : HDBPDA ion exchange resin} had a capacity of 3.8meq/g dry resin. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA and strongly acidic cation exchange resin, Dowex 50W-X8(200-400mesh) in water, and the various concentrations of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions for the HDBPDA ion exchange resin, but generally the distribution coefficient slightly increased with decreasing concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those in various hydrochloric acid concentration. The distribution coefficients of alkali and alkaline earth metal ions for the Dowex 50W-X8 ion exchange resin increased with decreasing hydrochloric acid concentration. Especially, the distribution coefficients of alkaline earth metal ions increased rapidly compared to those for alkali metal ions. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA ion exchange resin increased in a linear manner with decreasing acid concentration, and the slope, d log Kd/d log $M_{HCl}$ is about -0.2. Of the distribution cofficients of alkali metal ions on Dowex 50W-X8, at range of moderate hydrochloric acid concentration, the slope is about -1, while the slope for alkaline earth metal ions is about -2. However, at very low hydrochloric acid concentration, the linear variation between distribution coefficient and acid concentration was not occurred, but the slope was deviated from above values at low acid concentration.

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The Acid-Resistance Properties of Hardened Alkali-Activated Slag Composites (황산의 침해를 받은 슬래그 경화체의 특성)

  • 김원기;소정섭;배동인
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.313-317
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    • 2003
  • The study is the results of accelerated tests and the specimens, mortars, are submerged in a 5% sulfuric acid solution. The deterioration of specimens is followed up by investigating the change in weight and compressive strength of the specimens and techniques such as XRD and XRF are used to examine the chemical changes. Sulfuric acid is a very aggressive acid that reacts with the free lime [$Ca(OH)_2$] in the concrete forming gypsum($CaSO_{4}.2H_{2}O$). This reaction is associated with an increase in volume of the concrete, and the corroded surface becomes soft and white. The results showed that the OPC mortar caused an decrease in weight above 18% and strength loss about 57%. On the other hand, AASC(alkali-activated slag composites) did not cause any decrease in weight and in the case of strength caused an decrease below 10%. In addition, this mechanical results was verified to XRD and XRF.

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Utilization of Pine Bark(I) -Chemical Compositions and Characterization of Ca-base Acid Sulfite Cooking of Pine Bark- (소나무 수피(樹皮)의 총합적(總合的) 이용(利用)(I) -수피(樹皮)의 화학적(化學的) 조성(組成)과 Ca-base 산성(酸性) 아황산염(亞黃酸鹽) 증해(蒸解) 특성(特性)-)

  • Mun, Sung-Phil;Kim, Jae-Phil
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.1
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    • pp.28-33
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    • 1994
  • The chemical compositions of pine bark from mechanical pulp industry were determined, and effect of Ca base acid sulfite on bark cooking was investigated under various conditions. The pine bark was composed of 39.5 % alkali extractives, 50.3 % lignin, and a small amount of carbohydrate. The contents of alkali extractives and lignin were remarkably higher than those of pine wood. The bark was composed of high content of arabinose and xylose, while the wood was composed of high content of mannose. When pine bark was cooked with 75 % free acid at 145 $^{\circ}C$, the rate of cooking and delignification was improved with the increase of total acid, but it was very difficult to delignify the bark by 50 % and over under these conditions. In the presence of 60~65 % free acid and at 155~165 $^{\circ}C$, initial cooking rate, delignification, and delignification selectivity were considerably increased, but condensation reaction of lignin was considerable at the end of cooking. Therefore, it was shown that pine bark was very difficult to delignify by the Ca-base acid sulfite cooking.

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Investigation on the spectroscopic characteristics for Pu oxidation state in acid and alkali medium (산 및 알칼리 매질에서 Pu 산화수에 대한 분광학적 특성 조사)

  • Lee, Myung-Ho;Kim, Jong-Yun;Kim, Won-Ho;Jung, Euo-Chang;Jee, Kwang-Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.2
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    • pp.103-108
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    • 2007
  • The absorption spectra of Pu in stock solution were measured using a UV-Vis-NIR spectrophotometer after dissolving $PuO_2\;with\;HNO_3$, HF and $HClO_4$. The spectroscopic characteristics of Pu (III, IV, VI) in acidic, neutral and alkali media were investigated. Also, the intensities and position of major peaks for Pu(VI) were observed with increasing acidic and alkali concentration. The variation of oxidation states of Pu(VI) with an adding reducing reactant was investigated in HCl and NaOH medium.

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Effects of Ultra High Molecular Weight Poly-${\gamma}$-glutamic Acid from Bacillus subtilis (chungkookjang) on Corneal Wound Healing

  • Bae, Sun-Ryang;Park, Chung;Choi, Jae-Chul;Poo, Ha-Ryoung;Kim, Chul-Joong;Sung, Moon-Hee
    • Journal of Microbiology and Biotechnology
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    • v.20 no.4
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    • pp.803-808
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    • 2010
  • Poly-${\gamma}$-glutamic acid (${\gamma}$-PGA) is a natural edible polypeptide in which glutamate is polymerized via ${\gamma}$-amide linkages. First, we assessed the eye irritancy potential of ${\gamma}$-PGA in rabbits. Additionally, we studied the effects of ${\gamma}$-PGA on corneal wound healing, due to the anti-inflammatory properties and water retaining abilities of ${\gamma}$-PGA. In this study, the effects of ${\gamma}$-PGA on corneal wound healing after an alkali burn were evaluated. Thirty eyes wounded by alkali burning in 30 white rabbits were divided into three groups: group A was treated with 0.1% 5,000 kDa ${\gamma}$-PGA for 2 days; group B was treated with 0.1% hyaluronic acid; and group C was not treated, as a control. The area of corneal epithelial defect was examined at 12, 24, 30, 36, 42, and 48 h after corneal alkali wounding to determine initial wound healing. We found that ${\gamma}$-PGA promoted corneal wound healing, compared with controls, and showed similar effects to hyaluronic acid. These results indicate that ${\gamma}$-PGA stimulates corneal wound healing by an anti-inflammatory effect and enhancing cell migration and cell proliferation. ${\gamma}$-PGA is a promising biomaterial that may be a substitute for hyaluronic acid in corneal wound healing treatment.

Removal Effect of Residue Pesticide of Organic Acid Salt in Alkali Aqueous Solution (알칼리 수용액상에서 유기산염의 잔류농약 제거효과)

  • Lee, Jae-duk;Lee, Man-Ho
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.907-912
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    • 1999
  • In this study, removal effect of residue pesticides on vegetable and fruit using organic acid salt in alkali solution were investigated by gas chromatography and measurement of detergency. Generally, for the removal methods of residue pesticides and oily pollution were used chemical detergent or organic solvent. Specially, in our experiment, we only used material of food additives and trisodium citrate were superior to other organic acid salt. It was investigated that removal effect of pesticides was superior to chemical detergent.

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Recovery of Gallium and Indium from Zinc Residues by Acid Leaching (산침출에 의한 아연제련잔사로부터 갈륨 및 인디움의 회수)

  • 이화영;김성규;오종기
    • Resources Recycling
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    • v.2 no.2
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    • pp.22-26
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    • 1993
  • The flowsheet for the recovery of gallium and indium from zinc residues has been established based on the sulfuric acid treatment. In comparison with the alkali treatment, the method proposed in this work allowed the recovery of indium together with gallium. The majority of iron contained in leach liquor could be removed through the two-stage neutrallization under oxidative or reductive atmosphere. Crude gallium and indium could be obtained through the alkali and/or acid leaching of the products generated from the above treatment. In addition, cementation of indium with zinc powders could also be used for the concentration of it from weak acid solutions.

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