• Journal of Environmental Health Sciences
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• v.35 no.3
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• pp.191-200
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• 2009

We investigated a trait of odor and the relationship between odor unit and odorous compounds using multiple regression analysis based on data compiled from Sihwa (SIC), Banwol (BIC), Banwol plating (BPIC) and Poseung industrial complex (PIC). These areas are odor control areas in Gyeonggi province. It was revealed that $NH_3$ and styrene concentrations in SIC and BPIC were relatively higher and $H_2S$ concentration especially in mc was more than five times higher than other areas. As a result of regression analysis using SAS, intensity of odor unit was highly related to concentrations of $H_2S$, TMA, styrene and n-valeraldehyde in SIC, $H_2S$, acetaldehyde, and butyraldehyde in BPIC and $NH_3$ in BIC.

• Journal of the Korean Society of Tobacco Science
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• v.6 no.1
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• pp.51-62
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• 1984

The chemical components of non-blended and blended cigarettes and their smoke have been analyzed to investigate the correlation between them. Some regression of linear equations were obtained based on the simple correlation data(r), for the various smoke components such as tar, nicotine, nitrogen dioxide, steam volatile phenols, formaldehyde, acetaldehyde, acrolein and hydrogen cyanide. Chi-square tests were carried out to observe the probabilities of the values estimated by the regression of linear equations. The probabilities of the greater values were 0.900-0.999 to tar, nicotine, formaldehyde, acetal dehyde, acrolein, steam volatile phenols, nitrogen dioxide and hydrogen cyanide of the non-blended cigarettes, and 0.900-0.999 to tar, nicotine, nitrogen dioxide, steam volatile phenols and static burning rate (SBR) of the blended cigarettes.

• Proceedings of the Korean Society of Toxicology Conference
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• 2002.11b
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• pp.204-204
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• 2002

Alcohol drinking during pregnancy can result in abnormal fetal development including fetal alcohol syndrome (FAS). The molecular mechanisms of FAS, however, is not completely elucidated. In the present study, we evaluated the developmental toxicity of ethanol and its metabolite, acetaldehyde using post implantation whole embryo culture and determined changes of gene expression by ethanol treatment by cDNA microarray.(omitted)

• Bulletin of the Korean Chemical Society
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• v.8 no.1
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• pp.15-19
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• 1987

Preparation of optically pure (3R, 4R)-4-acetoxy-3-[(1R)-1-hydroxyethyl]azetidin-2-o ne derivatives, which can be employed as starting materials for synthesis of carbapenem and penem antibiotics, was established in high efficiency from 6-amino-penicillanic acid (6-APA). 6-APA was diazotized and brominated to give 6, 6-dibromopenicillanic acid and its methyl ester was metalated with methylmagnesium bromide and condensed with acetaldehyde. The product, methyl 6-bromo-6-(1-hydroxyethyl)penicillanate was reduced with Zn-$NH_4Cl-NH_4OH$-acetone efficiently to give methyl 6-(l-hydroxyethyl)-penicillanate, which was protected either with ${\beta},{\beta},{\beta}$ -trichloroethoxycarbonyl group or with t-butyldimethylsilyl group. The thiazolidine rings of these compounds were cleaved by treatment of mercury(II) acetate in acetic acid and permangante in acetone in sequence to afford the desired optically pure final products.

• Food Science and Preservation
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• v.4 no.1
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• pp.1-10
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• 1997

This study was performed to determine chemical compositions of dried persimmons stored with plastic film at low temperature and the effect of film packaging on dried persimmons during storage. The moisture contents of dried persimmons were 30 to 36% and alcohol contents were 264 to 318 mg/100g and acetaldehyde contents were 25 to 40mg/100g. Total lipid contents of dried persimmon were 626 to 869mg/100g and oleic, palmitic, linolenic, and palmitoleic acid were major fatty acids in total lipids. Major amino acids were glutamic acid, arginine, cystine and aspartic acid. From the result of storage experiment, non-packed group was that hardness was high as decreased in moisture content. In case of film packed groups stored at 5$^{\circ}C$, self life was longer than non-packed and packed groups stored at room temperature. But, it need to develop available packing material and storage method.

• Archives of Pharmacal Research
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• v.23 no.3
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• pp.202-205
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• 2000

A convenient pathway for synthesis of trans-metanicotine analogues was developed. trans-Metanicotine, a subtype(${\alpha}4{\beta}2$)-selective ligand for neuronal nicotinic acetylcholine receptor, is under clinical phase for Alzheimer's disease. Zn-mediated allylation of allyl bromide and acetaldehyde followed by Heck reaction with 3-bromopyridine gave 5-pyridin-3-yl-pent-4-en-3-ol (2). Tosylation of 5-pyridin-3-yl-pent-4-en-3-ol followed by substitution reaction with methylamine in sealed tube gave methyl-(1-methyl-4-pyridin-3-yl-but-3-enyl)-amine (4) in good yields. Thus, trans-metanicotine analogues modified at the $\alpha$-position of the methylamino group with various functional groups can be obtained in 4 steps.

• Bulletin of the Korean Chemical Society
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• v.5 no.5
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• pp.191-193
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• 1984

6, 6-Diiodopenicillanic acid was prepared from 6-aminopenicillanic acid using iodine-sodium iodide systems in good yield (60%). Enolates derived from 6-chloro-6-iodo-, 6,6-diiodo-penicillanate have been generated in situ by a metal-halogen exchange process at -$78^{\circ}C$ using methylmangnesium iodide and reacted with acetaldehyde to yield aldols. As the size of remaining halogen atom increases, the proportion of ${\beta}$-face attack was increased. In the case of 6,6-diiodopenicillanate, only ${\beta}$-face attack was observed yielding a single isomer (6S, 8R).

• Bulletin of the Korean Chemical Society
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• v.20 no.2
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• pp.203-210
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• 1999

Structural characteristics of isotactic p-alkylphenol acetaldehyde novolak resins with methyl, t-butyl, and t-octyl as the p-substituent and p-t-butylphenol aldehyde novolak resins with methylene, ethylidene, and propylidene as the linkage were calculated using molecular mechanics and molecular dynamics. The five p-alkylphenol aldehyde resins were found to have common structural characteristics that hydroxyl groups of the p-alkylphenols cluster in the center of the molecule by intramolecular hydrogen bonds of hydroxyl groups of the adjacent p-alkylphenols and the alkyl groups are extended out. Distances between oxygen atoms and between p-carbon atoms of the adjacent p-alkylphenols become longer as the size of the p-substituent increases from methyl to toctyl. Bond angles of the linkage built between the adjacent p-alkylphenols become wider by increasing the p-substituent size and by decreasing the linkage size.

• Proceedings of the PSK Conference
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• 2003.10b
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• pp.106.2-106.2
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• 2003

Hangover is associated with alcohol metabolism in body after the ingestion of an alcoholic beverage. It has been known that hangover is caused by increasing blood acetaldehyde concentration. This study was carried out to evaluate effect against blood ethanol(EtOH) and acetaidehyde(AcH) on the seven natural products samples(Lotus seed, Sweet chest nut rose, Kohki, Gurume-K, Gurume-J, Phytic acid and Chlorophyll). Also, samples which were selected as good products were mixed. Then, effect against blood EtOH and AcH formulas were tested in vivo. (omitted)

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.323-324
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• 2023

The properties of cement mortar mixed with manganese-doped titanium dioxide nanowires (TiO₂(Mn)-NWs) were investigated in this study. The TiO₂(Mn)-NWs were synthesized using solvo-thermal synthesis and electro-spinning techniques. The TiO₂(Mn)-NWs at weights of 1%, ₂%, and 3% of the cement were respectively mixed into the cement mortar. The results showed that as the amount of TiO₂(Mn)-NWs increased, the flow value of the cement mortar was decreased and the setting time of cement mortar was accelerated. Moreover, as the amount of TiO₂(Mn)-NWs increased, the compressive strength of cement mortar was increased and the efficiency of acetaldehyde removal was improved.