• Title/Summary/Keyword: Accumulation mode

Search Result 143, Processing Time 0.024 seconds

Effect of Air Stagnation Conditions on Mass Size Distributions of Water-soluble Aerosol Particles (대기 정체와 수용성 에어로졸 입자의 질량크기분포의 관계)

  • Park, Seungshik;Yu, Geun-Hye
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.34 no.3
    • /
    • pp.418-429
    • /
    • 2018
  • Measurements of 24-hr size-segregated ambient particles were made at an urban site of Gwangju under high pressure conditions occurred in the Korean Peninsula late in March 2018. The aim of this study was to understand the effect of air stagnation on mass size distributions and formation pathways of water-soluble organic and inorganic components. During the study period, the $NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$, water-soluble organic carbon (WSOC), and humic-like substances(HULIS) exhibited mostly bi-modal size distributions peaking at 1.0 and $6.2{\mu}m$, with predominant droplet modes. In particular, outstanding droplet mode size distributions were observed on March 25 when a severe haze occurred due to stable air conditions and long range transport of aerosol particles from northeastern regions of China. Air stagnation conditions and high relative humidity during the study period resulted in accumulation of primary aerosol particles from local emission sources and enhanced formation of secondary ionic and organic aerosols through aqueous-phase oxidations of $SO_2$, $NO_2$, $NH_3$, and volatile organic compounds, leading to their dominant droplet mode size distributions at particle size of $1.0{\mu}m$. From the size distribution of $K^+$ in accumulation mode, it can be inferred that in addition to the secondary organic aerosol formations, accumulation mode WSOC and HULIS could be partly attributed to biomass burning emissions.

Characteristics of Formation and Growth of Aerosol Particles in an Indoor Smog Chamber (스모그 챔버 실험에 의한 에어로졸의 생성과 성장 현상의 관찰)

  • 김민철;배귀남;이승복;진현철;문길주;박주연;김용표
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2003.05b
    • /
    • pp.43-44
    • /
    • 2003
  • 스모그 챔버는 대기화학 반응을 물리적 변수를 제어할 수 있는 공간 내에서 재현하여 스모그 현상을 체계적으로 규명하기 위해 가장 많이 사용되는 방법이다(Dodge, 2000). 대기화학 반응을 통해 생성된 입자상 물질(secondary particles) 또는 초미세 입자(ultrafine particle, 〈0.1 $\mu\textrm{m}$)는 연속된 물리화학 반응을 통해 accumulation mode(0.1~l.0 $\mu\textrm{m}$) 입자로 성장한다. 특히, 대도시의 시정(visibility)은 accumulation mode 입자의 산란(scattering)과 흡수(adsorption)가 주요한 원인이기 때문에 이러한 물질의 생성에 영향을 주는 가스상 물질의 전화(gas-to-particle conversion) 반응과 초미세 입자의 성장 현상을 규명하는 것은 매우 중요하다. (중략)

  • PDF

Analysis of fatigue crack growth using fictitious crack model (가상균열 모델을 이용한 피로균열 진전 해석)

  • Yang Seung-Yong;Goo Byeong-choon
    • Proceedings of the KSR Conference
    • /
    • 2003.10c
    • /
    • pp.79-84
    • /
    • 2003
  • A fictitious crack model was used to analyze fatigue crack growth under the influence of residual stress. In the fictitious crack model, crack is represented in terms of the separation of two adjacent interfaces and the constitutive equation between the separation and traction is assumed. The effect of fatigue loading was included in the constitutive equation by considering damage accumulation in the cohesive zone. To investigate the effect of the residual stress on the fatigue crack growth, we calculated the residual stress distribution due to transient heat flux to the specimen by finite element method. Fatigue crack growth was simulated by the fictitious crack model with repeated loading. The mode-I crack growth rates were compared for the cases with and without the compressive residual stress around the crack tip. It was observed that the mode-I crack growth can be suppressed by compressive residual stress.

  • PDF

Surface damage accumulation in alumina under the repeated Inclined contact forces (수직-수평 반복하중을 받는 알루미나 표면에서의 피로손상 누적)

  • 이권용;최성종
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 1999.06a
    • /
    • pp.61-66
    • /
    • 1999
  • 반복 응력 상태 아래서 알루미나 세라믹의 피로 표면손상 누적현상이 분석되었다. 연속 미끄럼 접촉 시에 발생하는 응력 상태를 재현하기 위해서 동시에 작용하는 수직-수평 반복 압축하중 기법이 사용되었다. 알루미나 구와 평판의 접촉면에서 알루미나 미세 결정의 피로 파손에 의한 마모 입자 형성 기구가 관찰되었고, 반복하중의 횟수와 수직-수평 하중비가 커질수록 마모량은 증가하였다. 반복 접촉하중에 의한 표면손상 누적이 접촉 수직 변위 측정으로 정량화 되었다. 두 접촉 구조물의 강성 (하중-변위 선도의 기울기) 변화가 두 재질의 탄성계수의 변화로 표현되었다.

  • PDF

Effect of the Intake Valve Opening Timings and Fuel Injection Pressures on the Exhaust Emission Characteristics of a Gasoline Engine at Part Load Condition

  • Lee, Hyung-Min;Jeong, Yeon-Hwan
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.35 no.3
    • /
    • pp.317-322
    • /
    • 2011
  • This work has investigated the exhaust emissions such as Total Hydrocarbon (THC), Nitrogen Oxides(NOx), and Particulate Matter (PM) characteristics emitted from the tail-pipe of a continuously variable valve timing (CVVT) gasoline-fueled engine with different intake valve opening timings and injection pressures at the part load condition. Valve overlap period was varied from $40^{\circ}CA$ to $10^{\circ}CA$ and fuel injection pressure was increased from 3.5 bar to 5.0 bar. THC and NOx emissions decreased as intake valve opening timing was advanced regardless of fuel injection pressure. When the fuel was injected with the condition of 5.0 bar at all of valve overlap ranges, THC levels were reduced by 55%. NOx concentrations were diminished about 75% as valve overlap increased. PM size distributions were analyzed as bi-modal type of the nucleation and accumulation mode. Comparing with fuel injection pressures, PM emission levels were decreased at high pressure injection of 5.0 bar condition.

Major factors determining the size distributions of atmospheric water-soluble aerosol particles at an urban site during winter (겨울철 도시지역 대기 수용성 에어로졸 입자의 크기 분포를 결정하는 주요 인자)

  • Park, Seungshik
    • Particle and aerosol research
    • /
    • v.17 no.3
    • /
    • pp.43-54
    • /
    • 2021
  • Size distributions of atmospheric particulate matter (PM) and its water-soluble organic and inorganic components were measured between January and February 2021 at an urban site in Gwangju in order to identify the major factors that determine their size distributions. Their size distributions during the study period were mainly divided into two groups. In the first group, PM, NO3-, SO42-, NH4+ and water-soluble organic carbon (WSOC) exhibited bi-modal size distributions with a dominant condensation mode at a particle size of 0.32 ㎛. This group was dominated by local production of secondary water-soluble components under atmospheric stagnation and low relative humidity (RH) conditions, rather than long-range transportation of aerosol particles from China. On the other hand, in the second group, they showed tri-modal size distributions with a very pronounced droplet mode at a diameter of 1.0 ㎛. These size distributions were attributable to the local generation and accumulation of secondary aerosol particles under atmospheric conditions such as atmospheric stagnation and high RH, and an increase in the influx of atmospheric aerosol particles by long-distance transportation abroad. Contributions of droplet mode NO3-, SO42-, NH4+ and WSOC to fine particles in the second group were significantly higher than those in the first group period. However, their condensation mode contributions were about two-fold higher in the first group than in the second group. The significant difference in the size distribution of the accumulation mode of the WSOC and secondary ionic components between the two groups was due to the influx of aerosol particles with a long residence time by long-distance transport from China and local weather conditions (e.g., RH).

A Study on Glass-Infiltrated Alumina and Spinel Composite I. Effect of Microstructure and Glass Content on Contant Damage and Strength (유리침윤 알루미나 및 스핀넬 복합체에 관한 연구 I. 미세구조 및 유리함량이 접촉손상 및 강동에 미치는 영향)

  • 정연길;최성철
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.7
    • /
    • pp.671-678
    • /
    • 1998
  • Hertzian indentation tests with sphere indenters were used to study the mechanical properties of glass-in-filtrated alumina and spinel composites and evaluated the effect of preform microstructure and evaluated the effect of preform microstructure and glass con-tents on contanct damage and strength. The spinel composite showed more brittle behavior than the alumina composite which is verified from indentation stress-strain curve cone cracks and quasi-plastic deformation developed at subsurface. Failure originated from either cone cracks(brittle mode) or deformation zone(quasi-plastic mode) above critical load for cracking(Pc) and yield ({{{{ {P }_{Y } }}) with the brittle mode more dominant in the spinels and the quasi-plastic mode more dominant in the aluminas. Even though brittle mode was dominant in the spinel composites the strength degradation from accumulation of damage above these critical loads was conspicuously small suggesting that the glass-infiltrated composites should be highly damage tolerant to the blunt contacts.

  • PDF

Design and performance of Low-Volume PM10/2.5/1.0 Trichotomous Sampler Inlet (PM10/2.5/1/0 Trichotomous 도입부 설계 밀 성능평가)

  • Song Chang-Byeong;Kim Hyeon-Tae;Lee Gyu-Won
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2002.11a
    • /
    • pp.358-359
    • /
    • 2002
  • Particulate matter smaller than $10{\mu}textrm{m}$ in aerodynamic diameter (PM10) is known as thoracic particles that are capable of reaching the thoracic region of humans. PM10 is further divided into two size ranges, which are fine particles (nuclei mode plus accumulation mode) and coarse particles, based on different sources and chemical composition. Fine particles can penetrate deep into the alveolar region of the human lungs, while coarse particles be deposited in the upper respiratory system. (omitted)

  • PDF

Determination of Ultratraces of Rhodium by Adsorptive Stripping Voltammetry of Formaldehyde Complex

  • Hong Tae-Kee;Czae Myung-Zoon;Lee Chul;Kwon Young-Soon;Hong Mi-Jeong
    • Bulletin of the Korean Chemical Society
    • /
    • v.15 no.12
    • /
    • pp.1035-1037
    • /
    • 1994
  • An ultrasensitive and selective stripping voltammetric scheme for the determination of rhodium is described. By the use of combined accumulation and catalytic effects in formaldehyde-hydrochloric acid medium, substantial improvement in the limit of detection can be obtained. Optimal experimental conditions were found to be 0.42 M hydrochloric acid solution containing 0.008${\%}$ formaldehyde, an accumulation potential of -0.70 V (vs. Ag/AgCl) and an accumulation time of 20 s. The stripping mode was differential pulse voltammetry. In these conditions the limit of detection lies at 2 ${\times}$ l0$^{-12}$ M (0.21 ppt). The relative standard deviation at 5 ${\times}$ l0$^{-11}$ M was 4.9${\%}$ (n=5). There were no serious interferences from other platinum group metal ions being the tolerable amounts more than 500 times that of rhodium.

Evaluation of Diagnosis-based Control Strategy for NH4-N and NOX-N Removal of a Full-scale Wastewater Treatment Process (하수처리시설의 질산화 진단기반 제어 방법의 개발 및 실규모 플랜트 적용을 통한 평가)

  • Kim, Yejin;Kim, Hyosoo
    • Journal of Environmental Science International
    • /
    • v.27 no.6
    • /
    • pp.447-456
    • /
    • 2018
  • In this research, the target process was a modified type of a conventional aeration tank with four different influent feeding points and alternated aeration to obtain nitrogen removal. For more accurate switching of influent feeding, the process was operated under a designed control strategy based on monitoring of $NH_4-N$ and $NO_X-N$ concentrations in the tank. However, the strategy did have some limitations. For example, it was not sensitive to detecting the end of each reaction when losing the balance between nitrification and denitrification of each opposite part of biological tank. To overcome the limitations of the existing control strategy, a diagnosis-based control strategy was suggested in this research using the diagnosis results classified as normal (N), ammonia accumulation (AA) and nitrate accumulation (NA). Using the pre-designed rules for control actions, the aeration and volume of the aerated part of the reactor could be increased or decreased at a fixed mode time. In simulations of the suggested diagnosis-based control strategy, the $NH_4-N$ and $NO_X-N$ removal rates in the reactor were maintained at higher levels than those of the existing control strategy.