• KSBB Journal
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• v.9 no.5
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• pp.469-474
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• 1994

The purpose of the work was to evaluate the feasibility of a biological treatment process for the phenoxy alkanoic herbicide 2,4-D(2,4-dichlorophenoxyacetic acid) as a commercial pesticide. The phenoxy herbicide was 2,4-D amine salts which contained 40%(vol/vol) 2,4-D and 60%(vol/vol) solvent. A microbial consortium has been derived by enrichment with 2,4-D. The consortium utilized 2,4-D as the sole source of carbon and energy. Optimal pH on the 2,4-D degradation was 7.0 in this experiment. As concentrations of 2,4-D were increased, the degradation by microbial consontium became inhibited. The amendment with yeast extract and ascorbic acid accelerated the degradation of 2,4-D. High performance liquid chromatography methodology was used to measure 2,4-D and it also resolved 2,4-DCP(2,4-dichlorophenol), the corresponding phenol as intermediate. Gas chromatography-mass spectrometry was used for preliminary identification of the intermediate 2,4-DCP. UV scans of spent cultures showed that the maximum absorption of 2,4-D at the wavelength of 283 nm was decreased toward the end of incubation, but the consortium displayed no detectable spectral changes or peak shifts in the UV absorbance.

• Korean Journal of Soil Science and Fertilizer
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• v.21 no.2
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• pp.169-175
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• 1988

A laboratory experiment was conducted to investigate the effects of pH, organic matters and anion on the adsorption and degradation of surfactant by different soils; Anmi series (limestone region), Gangseo series (alluvial soil). For this study, Alkyl Benzene Sulfonate (ABS ; Sodium Dodecylbenzenesulfonate) was used as a surfactant. The results were as follows: 1. Adsorption of ABS by soils was correlated positively with the equilibrium concentration of ABS in a soil suspension. (Anmi seris : r=0.9855, Gangseo series : r=0.9931). 2. Adsorption rate of ABS by soils was about 70% of the treated concentration ($600{\mu}g$ ABS/g soil) in a range of pH 4 to pH 5, and about 20% for pH 8. 3. Addition of electrolytes increased ABS adsorption by soils in a soil suspension; the higher concentration, the higher adsorption. But the influence among electrolytes was not significant. 4. Adsorption of ABS by soils was not affected by soil organic matter content in this experiment. 5. Degradation rate of ABS in a soil suspension was about 85% at $30^{\circ}C$, and about 10 to 15% at $10^{\circ}C$. Addition of sewage accelerated the degradation rate regardless of temperature and reached about 85% in a week.

• Korean Journal of Environmental Biology
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• v.19 no.1
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• pp.59-69
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• 2001

Among the biodegradability tests, TOC-HANDAI and OECD method were utilized to examine the degree of biodegradation of endocrine disruptors, Bisphenol A (BPA) and Nonylphenol. Both methods used natural water microcosms and measured their biodegrada-bilities of BPA and Nonylphenol, in terms of TOC or DOC degradation with time for 28 days. Biodegradabilities for BPA, 73-78% with TOC-HANDAI method and 77-81% with OECD method were obtained respectively at the end of experiment. There was no difference in BPA degradation between two methods. BPA degradation was described by two distinct first order decay rates (k$_1$ and k$_2$) which could be separated by a simple visual fitting. Most of the initial decay reaction accelerated within 1-7 days with k$_1$of 0.24-0.34 $day^{-1}$. And the following another long term first order decay coefficient (k$_2$) showed 0.02-0.05 day$^{-1}$ with much flat slope. About 20-25% of initial BPA remained at the end of experiment. It suggests that the remaining TOC components in BPA biodegradation considered to be refractory metabolites of BPA. Nonylphenol at each sampling point was appeared to be mineralized 20-48% of initial TOC concentration. Consequently Nonylphenol seems more recalcitrant against biodegradation. BPA was not detected in the detection limit of ppb in the watershed of Daechung reservoir and Kum river. However 25 ppb concentration of BPA was detected at the influent of industrial wastewater treatment plant in Taejon.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.26-31
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• 2023

For durability improvement of polymer electrolyte membrane fuel cell (PEMFC) polymer membrane, accelerated durability evaluation methods that can evaluate durability in a short time have been researched and developed. However, the lifespan of fuel cells for large commercial vehicles such as trucks and buses is more than three times that of passenger cars, and the chemical accelerated stress test (AST) time is also longer, reaching 1,500 hours or more. Therefore, in this study, as a method to evaluate the chemical durability of a membrane within a short time, it was examined whether the durability could be predicted by the pristine membrane characteristics. Hydrogen crossover current density (HCCD) and short resistance (SR) were estimated as initial characteristics, and AST time was predicted through the Fenton experiment, which was possible as an out-of-cell experiment for 3 hours. As the HCCD and fluoride ion emission concentration increased, the AST time tended to be linearly shortened, but there was a deviation (R² ≒0.65). When the SR decreased, the AST time showed a linear increase, and the accuracy was high (R² =0.93), so the AST time could be predicted with the initial SR of the membrane.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.1-6
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• 2024

As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.

• Journal of the Korea Institute of Building Construction
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• v.17 no.2
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• pp.157-166
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• 2017

In general, carbonation and chlorine ions are the most harmful causes of deterioration of concrete structures. Recently, a method has been developed to control the corrosion of rebar in concrete containing chloride by impregnating a Surface coating material with a inhibitor. In this study, accelerated carbonation and differential thermogravimetric analysis (TG-DTA) and CASS tests were carried out to evaluate the characteristics of Surface coatings containing Organic Corrosion inhibitors which are excellent in corrosion inhibition and fix degradation causes $CO_2$ and $Cl^-$. As a result of the experiment, TG-DTA analysis and accelerated carbonation showed that $CO_2$ was directly reacted with amine derivative in concrete by the incorporation of Organic Corrosion inhibitor. In other words, $CO_2$ was immobilized and carbonation inhibition effect was confirmed. In addition, in the CASS test, the specimen coated with the Surface coating material containing the Organic Corrosion inhibitor with $Cl^-$ fixing property showed no corrosion until the 28th day and had excellent performance in preventing corrosion of a rebar by the chloride ion.

• Journal of the Korean Electrochemical Society
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• v.19 no.2
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• pp.45-49
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• 2016

In order to mitigate oxidative degradation of polymer membrane during fuel cell operation, an organic radical quencher was introduced. Rutin was selected as a radical quencher and mixed with sulfonated poly(arylene ether sulfone) to prepare composite membrane. Physicochemical properties of the composite membranes such as water uptake and proton conductivity were characterized. Hydrogen peroxide exposure experiment, which can mimic accelerated oxidative stability test during fuel cell operation, was adopted to evaluate the oxidative stability of the membranes. The composite membranes containing Rutin showed similar proton conductivity and enhanced oxidative stability compared to pristine ones.

• Earthquakes and Structures
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• v.22 no.2
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• pp.203-218
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• 2022

In this paper, quasi-static tests were carried out on three prefabricated reinforced concrete column-steel beam (RCS) sub-assemblages with floor slabs and one comparison specimen without floor slab. The effects of axial compression and floor slab on the seismic performance were studied, and finite element simulations were conducted using ABAQUS. The results showed that the failure of prefabricated RCS sub-assemblages with floor occurred as a joint beam and column failure mode, while failure of sub-assemblages without floor occurred due to beam plastic hinge formation. Compared to the prefabricated RCS sub-assemblages without floor slab, the overall stiffness of the sub-assemblages with floor slab was between 19.2% and 45.4% higher, and the maximum load bearing capacity increased by 26.8%. However, the equivalent viscosity coefficient was essentially unchanged. When the axial compression ratio increased from 0.24 to 0.36, the hysteretic loops of the sub-assemblages with floor became fuller, and the load bearing capacity, ductility, and energy dissipation capacity increased by 12.1%, 12.9% and 8.9%, respectively. Also, the initial stiffness increased by 10.2%, but the stiffness degradation accelerated. The proportion of column drift caused by beam end plastic bending and column end bending changed from 35% and 46% to 47% and 36%, respectively. Comparative finite element analyses indicated that the numerical simulation outcomes agreed well with the experimental results.

• Journal of Electrical Engineering and Technology
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• v.10 no.3
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• pp.1114-1123
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• 2015

Bushing is the key link to connect outer and inner insulating systems and also the essential electric accessory in electric power system, especially in the high voltage engineering (AC 1000kV, DC 800kV). This paper presented the experimental research of thermal aging characteristic of oil-paper insulation used in bushing. A thermally accelerated aging experiment at 90℃ was performed. The bushing models containing five layers of paper were sealed into the aging vessels and further aged for 250 days. Then several important parameters associated with the aging were observed and evaluated. The results showed that the degree of polymerization (DP) of papers gradually decreased. The DP values of outermost layer and middle layer fit well into the second-order kinematic model and first-order kinematic model, respectively. Less deterioration speed of the inter-layer paper than outer layer was confirmed by the variation of DP. Hydrolysis was considered as the main cause to this phenomenon. In addition, the logarithm of the furfural concentrations in insulation oil was found to have good linear relationship with DP of papers. Interestingly, when the aging time is about 250 days and DP is 419, the aging process reaches an inflection point at which the DP approaches the leveling off degree of polymerization (LODP) value. Both tanδ and acid number of oils increased, while surface and volume resistivity of papers decreased. The obtained results demonstrated that thermal aging and moisture absorbed in papers brought great influence to the degradation of insulating paper, leading to rapid decrease of DP and increase of the tanδ. Thus, the bushing should be avoided from damp and real-time monitoring to the variation of tanδ and DP values of paper is an effective way to evaluate the insulation status of bushing.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.9 s.180
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• pp.2183-2190
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• 2000

A thermal aging is observed in a primary reactor cooling system(RCS) made of a casting stainless steel when the RCS is exposed for long period at the reactor operating temperature, 290~3300C An investigation of effects of thermal aging on a low cycle fatigue characteristics included a stress variations caused by a reactor operation and trip, is required. The purpose of the present investigation is to find an effect of a thermal aging of the CF8M on a low cycle fatigue life. The specimen of CF8M are prepared by an artificially accelerated aging technique holding 300 and 1800hr at 4300C respectively. The low cycle fatigue tests for the virgin and two aged specimens are performed at the room temperature for various strain amplitudes($\varepsilon$ta), 0.3, 0.5, 0.8, 1.0, 1.2 and 1.5% strain. Through the experiment, it is found that the fatigue life is rapidly reduced with an creasing of the aging time. The experimental fatigue life estimation formulas between the virgin and two aged specimen are obtained and are proposed to a analysis purpose.