• Title/Summary/Keyword: Accelerated Weathering

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Effect of Accelerated Weathering on the Leaching of Copper from Preservative Treated Wood (기상열화가 방부처리재의 구리성분 용탈에 미치는 영향)

  • Lee, Myung-Jae;Lee, Dong-Heub;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.4
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    • pp.38-43
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    • 2003
  • This is the second in a series of reports on the evaluation of weathering durability of waterborne preservative treated wood by accelerated weathering. The leaching of copper from ACQ-, CCA-, and CuAz-treated samples during weathering was increased by UV irradiation, when compared between full weathering and water-only weathering. The FTIR spectra of the weathered ACQ-, CCA, CuAz-treated samples at 1731 cm-1, 1625 cm-1, 1510 cm-1, which are related to the fixation of copper, were different from those of unweathered controls. This result means that UV irradiation can weaken the chemical bond between lignin and copper and/or extraction of lignin-copper complex can be occured when lignin erode away by weathering.

Artificial Accelerated Weathering of Volcanic Rocks from Ulleungdo Island (인공풍화가속실험을 통한 울릉도에 분포하는 화산암의 풍화특성 고찰)

  • Woo, Ik
    • The Journal of Engineering Geology
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    • v.25 no.4
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    • pp.499-510
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    • 2015
  • Artificial accelerated weathering test evaluated rocks from near the circuit road of Ulleungdo island, approximately 120 km from east of the Korean Peninsula. The tests subjected rock specimens to conditions based on the climate of the island. The specimens (such as basaltic breccia, trachyte, volcanic breccia) were preliminarily classified using a TAS diagram (XRF data) and based on the constituent minerals (XRD data); they were further classified by weathering degree according to their absorption ratios. During the artificial accelerated weathering, the absorption ratio of most of the specimens increased, but the point-load strength did not decrease in most cases, except for the volcanic breccia. The greater initial absorption ratio of trachyte rock specimen in comparison with the other specimens led to a greater increase of its absorption ratio during the artificial accelerated weathering test. The volcanic breccia specimens showed the greatest increase of absorption ratio and the biggest reduction ratio of the point- load strength during the tests. These results could aid prediction of the weathering rate of rocks in Ulleungdo island subjected to weathering processes; trachyte which appears to accelerate with time, and volcanic breccia whose mechanical strength can largely decrease in a relative short period of time. Proper measures therefore appear necessary for the prevention of natural disaster such as rock fall and landslide around the circuit road.

Accelerated Laboratory Experiments Investigating Weathering of Volcanic Rocks from Yuchon Group Exposed to Seawater and Acidified Distilled Water (실내인공풍화가속실험을 통한 해수와 산성증류수에 대한 유천층군 화산암의 풍화 특성 연구)

  • Ik Woo
    • The Journal of Engineering Geology
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    • v.34 no.1
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    • pp.25-38
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    • 2024
  • Laboratory tests of accelerated artificial weathering compared the effects of seawater and acidified distilled water on rock weathering. The experiments simulated chemical and physical weathering of five different types of volcanic rock by applying 45 freeze-thaw cycles using seawater and acidified distilled water (pH 3), both at 70℃. The physical properties and uniaxial compressive strength (UCS) of the rocks were measured after 15 and 45 cycles of artificial weathering. Most of degradation of physical properties appeared within the first 15 cycles, and acidified distilled water had a greater effect than seawater. Analysis of variance (ANOVA) statistically evaluated the differences in UCS of the different rock types during the tests. The rate of UCS reduction after 45 cycles was similar across the samples, being independent of the rock type and the trend of changes in physical properties. In contrast to the changes in the physical properties, the UCS was more affected by seawater than by acidified distilled water.

Abrief study on the corrosion of bronze roofing tile (납(Pb)도금(동개와)의 부식 연구)

  • Kim, Sa-Dug
    • 보존과학연구
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    • s.15
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    • pp.52-58
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    • 1994
  • To protect corrosion of bronze roofing tile for Choson Royal Historic Museum, lead coating on tile was performed by electroplating method with thickness of $35\mum$. Lead coated tile samples were inverstigated what corrosion products were formed with color changes on them by testing Accelerated Weathering. No sulfides were formed on samples contacting with 300ppm sulfur dioxide and any color changes were not found. In Accelerated Weathering test, White hydrocerussite, basic lead carbonate($2PbCO_3Pb(OH)_2$) having protective structure made of compact adhering crystals.

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Effects of salt crystallization on stone durability (염분의 결정화 현상이 석재 내구성에 끼치는 영향)

  • 김성수
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.203-208
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    • 1999
  • The main objective of this study is to suggest a new assessment method of the influence of weathering due to salt crystallization on the engineering property of rock. For this purpose, various sources of salt and salt crystallization were investigated, and artificially accelerated weathering tests were carried out. In natural envionment, weathering rate is very slow and weathering process involves complex mechanisms. Therefore artificial weathering test is essential for systematic analysis. Arificial weathering test is defined as test which controls weathering rate and agents by controlling arificial environmental condition. In this study, salt crystallization test was selected among various artificial weathering test methods, for its important role in weathering. Change of various stone properties were detexted. The change of physical properties by salt crystallization were observed as follows : 72% in Brazilian tensile strength and 72% in Slake durability. These results explain the importance of salt crystallization in the mechanical behaviour and properties of stone.

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Engineering Geological Characteristics of Freeze-Thaw Weathered Gneiss in the Wonju Area, Korea

  • Um, Jeong-Gi;Woo, Ik;Park, Hyuck Jin
    • The Journal of Engineering Geology
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    • v.24 no.2
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    • pp.161-169
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    • 2014
  • We present the results of an experimental physical weathering study that focuses on fresh and slightly weathered gneiss samples from the Wonju area of Korea. The study investigated changes in the physico-mechanical properties of these samples during accelerated laboratory-based weathering, including analyses of microfracture formation. The deteriorated samples used in the study were subjected to 100-150 freeze-thaw cycles, with index properties and microfracture geometries measured between each cycle. Each complete freeze-thaw cycle lasted 24 hours, and consisted of 2 hours of saturation in a vacuum chamber, 8 hours of freezing at $-21^{\circ}C{\pm}1^{\circ}C$, and 14 hours of thawing at room temperature. Specific gravity and seismic velocity values were negatively correlated with the number of freeze-thaw cycles, whereas absorption values tended to increase. The amount of deterioration of the rock samples was dependent on the degree of weathering of the rock prior to the start of the analysis. Absorption, specific gravity, and seismic velocity values can be used to infer the amount of physical weathering experienced by a gneiss in the study area. The sizes and density of microfracture in the rock specimens varied with the number of freeze-thaw cycles. We found that box fractal dimensions can be used to quantify the formation and propagation of microfracture in the samples. In addition, these box fractal dimensions can be used as a weathering index for the mid-and long-term prediction of rock weathering. The present results indicate that accelerated-weathering analysis can provide a detailed overview of the weathering characteristics of deteriorated rocks.

Study on the Change of Physical and Anatomical Properties in the Pine Wood by Accelerated Weathering Test (촉진열화실험에 의한 소나무의 물성 및 조직 변화에 대한 연구)

  • Kim, Gwang-Chul
    • Journal of the Korea Furniture Society
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    • v.23 no.3
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    • pp.324-331
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    • 2012
  • The domestic pine was used to investigate the change of specific gravity, moisture contents, color and anatomical structure by accelerated weathering test (AWT). According to visual inspection, a few knot separation and looseness as well as considerable surface discoloration was found out. However, the crack and split of surface texture have been never occurred till the last step of AWT. On the whole, as the time of accelerated weathering test has increased, the specific gravity has decreased. Finally, after the 9th week of AWT, the specific gravity was 0.38 that reached to 82% compared to the control specimen. In case of moisture content (MC), it showed rising trend in its early stages, however, after 3th week of AWT it have displayed steady state. A deterioration of cell-wall components was not remarkably observed by scanning electron microscope (SEM), however the ray fractures of AWT specimen were observed more than those of control specimen. The full fracture of epithelial cell around resin canal was observed by optical microscope. The fracture of ray of 2th cycle AWT specimen was first, followed by 1th week and control group. A distortion of tracheid for early spring wood and fracture of epithelial cell were generally observed by a similar level, regardless of duration time of AWT. Therefore, it is obvious that increasing duration time of AWT does not affect the deterioration of micro-structure for wood members from this study. Although a considerable change of anatomical properties was not found, there is a need of further research to understand how will the changes of specific gravity and MC on the physical properties of wood member.

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Evaluation on Physical and Mechanical Properties of Wood Plastic Composites Treated under Ultraviolet Irradiation (자외선을 처리한 목재 플라스틱 복합재의 물리 및 역학적 성질 평가)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.26 no.4
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    • pp.428-434
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    • 2015
  • In this study, we received each wood plastic composites (WPC) from three manufacturers. These WPCs were evaluated regarding their physical and mechanical properties of both before and after accelerated weathering by ultraviolet (UV) irradiation. The total time of exposure of the WPCs to UV irradiation was 1800 h. The water absorption, volumetric swelling and shrinkage of WPCs did not affected by UV irradiation. Among the mechanical properties, there was no significant differences in bending strength and screw withdrawal resistance of UV treated WPCs compared with those of reference WPCs. However, surface hardness of WPCs showed decrease under UV irradiation. Stereoscopic microscopy observation revealed deterioration of the surface layer polymer in all weathered WPCs by UV. Exposure of the WPCs to UV irradiation caused decomposition and disappearance of the polymer layer. From this result, we can estimate that damage of polymer by UV led to a decrease in the surface hardness of the WPCs. The wood flours retained original shape after accelerated weathering by UV irradiation.

Variation of Geomechanical Characteristics of Granite and Orthogneiss in Wonju Area due to Accelerated Artificial Chemical Weathering Tests (강원도 원주일대에 분포하는 화강암 및 화강편마암의 화학풍화실험에 의한 물성 변화 연구)

  • Woo, Ik;Um, Jeong-Gi;Park, Hyuck-Jin
    • Tunnel and Underground Space
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    • v.19 no.3
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    • pp.213-225
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    • 2009
  • The purpose of the study is to evaluate the effects of chemical weathering on the granite and orthogneiss in Wonju area based on accelerated artificial chemical weathering. The rock samples were scrutinized the variation of index properties and ion exchanges caused by artificial chemical weathering which was implemented with leaching test for 170 days using double soxhlet extractor. The differential weathering and decrease of p wave velocity were obtained by weathering process without significant changes of porosity. In case of granite samples, the uniaxial compression strength was reduced by 20% and 16% for the F-grade and SW-grade, respectively. For MW-grade granite, however, was not able to examine the effect of strength reduction due to lack of sample number. Also, for orthogneiss, it is difficult to compare the values of uniaxial compressive strength between before and after the test because of its strong anisotropy.

Analysis of Rock Surface Roughness and Chemical Species Generation by Freeze-Thaw Experiments (동결융해 실험을 통한 암석 표면 거칠기 및 화학종 생성에 관한 분석)

  • Choi, Junghae
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.299-311
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    • 2022
  • Rocks exposed to the surface are subject to long-term weathering, and such effects weaken their engineering stability. Especially as weathering progresses, the surface of rocks will be changed by weathering, and such surface changes will affect the engineering safety of the rock mass. In addition, the chemical species produced in the weathered rock have a direct effect on the surrounding environment or on the structure. In areas where rocks are exposed, such as mining areas, chemical species produced by weathering can have a serious impact on the surrounding natural environment. In this study, accelerated weathering experiments using freeze/thaw system were conducted on rocks that had already been weathered and fresh rocks, and surface changes of each rock were observed with confocal laser scanning microscope (CLSM), and chemical species were analyzed using IC/ICP-MS. As the weathering progressed, the surface roughness decreased, and the amount of chemical species produced increased. The results of this study can be used as basic data for evaluating engineering/environmental safety in areas where rocks are exposed.