• Korean Chemical Engineering Research
• /
• v.61 no.3
• /
• pp.356-361
• /
• 2023

In order to improve the durability of the proton exchange membrane fuel cell (PEMFC), it is important to accurately evaluate the durability of the polymer membrane in a short time. The test conditions for chemically accelerated durability evaluation of membranes are high voltage, high temperature, low humidity, and high gas pressure. It can be said that the protocol is developed by changing these conditions. However, the relative influence of each test condition on the degradation of the membrane has not been studied. In chemical accelerated degradation experiment of the membrane, the influence of 4 factors (conditions) was examined through the factor experiment method. The degree of degradation of the membrane after accelerated degradation was determined by measuring the hydrogen permeability and effluent fluoride ion concentration, and it was possible to determine the degradation order of the polymer membrane under 8 conditions by the difference in fluoride ion concentration. It was shown that the influence of the membrane degradation factor was in the order of voltage > temperature > oxygen pressure > humidity. It was confirmed that the degradation of the electrode catalyst had an effect on the chemical degradation of the membrane.

• Nuclear Engineering and Technology
• /
• v.30 no.2
• /
• pp.148-163
• /
• 1998

Flow Induced Material Degradation (FIMD) is reviewed focusing on Flow Accelerated Corrosion (FAC) models. Several examples of FAC related incidents are described, which include nuclear and fossile power plants. Lastly, mitigation techniques such as inspection, material selection, water chemistry, temperature, and hydrodynamic factor are discussed.

• Journal of the Korean Society for Railway
• /
• v.16 no.6
• /
• pp.466-472
• /
• 2013

The use of a concrete track is gradually growing in urban and high-speed railways in many part of the world. The resilient pad, which is essentially when concrete tracks are used, plays the important role of relieving the impact caused by train loads. The simple fatigue test[1] to estimate the variable stiffness of resilient pads is usually performed, but it differs depending on the practical conditions of different railways. In this study, the static stiffness levels of used resilient pads according to passing tonnages levels were measured in laboratory tests. Also, the simple fatigue test and the multi-stress accelerated degradation test for new resilient pads were performed in a laboratory. The static stiffness of the used pad was compared with the results of tests of usage times and cycles. The results of the comparison showed that the variable static stiffness levels of the used pad were similar to results of the multi-stress accelerated degradation test considering the fatigue and heat load. With a T-NT equation related to the degree of the multi-stress accelerated degradation, a model of multi-stress accelerated degradation for a resilient pad was devised. It was found through this effort that the total acceleration factor was approximately 2.62. Finally, this study proposes an equation for a multi-stress accelerated degradation model for polyurethane resilient pads.

• Journal of the Korea Concrete Institute
• /
• v.25 no.2
• /
• pp.137-144
• /
• 2013

The use of fiber-reinforced polymer (FRP) reinforcing bars in concrete structures has been increased as an alternative of steel reinforcement which has shown greater vulnerability to corrosion problem. However, the long-term performance of concrete members with FRP reinforcement is still questioned in comparison to the used of steel reinforcement. This study presents the results of an experimental study on the long-term behaviors of GFRP (glass fiber reinforced polymer) bar reinforced concrete beams after exposed to accelerated aging in an environmental chamber with temperature of $46^{\circ}C$ ($115^{\circ}F$) and 80% of relative humidity up to 300 days. The objectives of this research was to compare strength degradation and change of ductility between GFRP reinforced concrete beams and steel reinforcement beams after accelerated aging. Two types (wrapped and sand-coated surface) of GFRP bars and steel were reinforced. in concrete beams. Test results show that the failure modes of GFRP bar reinforced concrete beams are very similar with traditional RC beams, and the change of load-carrying capacity of steel reinforcing concrete beam is greater than that of GFRP bar reinforcing concrete beam under the accelerated aging. Test result also shows that the use of GFRP reinforcing in concrete could be introduced more brittle failure than that of steel reinforcing for practical application. The deformability factor up to compression failures indicates no significant variation before and after exposure of accelerated aging.

• International Journal of Highway Engineering
• /
• v.10 no.4
• /
• pp.79-89
• /
• 2008

The pavement performance model is the most important factor to determine the pavement life in the mechanistic-empirical pavement design guide (MEPDG). As part of Korean Pavement Research Program (KPRP), the Korean Pavement Design Guide (KPDG) is currently being developed based on mechanistic-empirical principle. In this paper, the rutting prediction model of asphalt mixtures, one of the pavement performance model, has been developed using triaxial repeated loading testing data. This test was conducted on various types of asphalt mixtures for investigating the rutting characteristics by varying with the temperature and air void. The calibration process was made for the coefficients of rutting prediction model using the accelerated pavement testing data. The accuracy of prediction model can be increased when by considering the effect of individual rutting properties of materials rather than shear stresses with depths.

• Biomedical Science Letters
• /
• v.20 no.2
• /
• pp.56-61
• /
• 2014

This study attempted to confirm the antioxidative potential of luteolin against tert-butyl hydroperoxide (t-BHP) induced oxidative damage and to investigate its molecular mechanism related to glutathione (GSH)-dependent enzymes in HepG2 cells. Treatment with luteolin resulted in attenuation of t-BHP induced generation of reactive oxygen species (ROS) and oxidative stress-mediated cell death. In addition, accelerated expression of GSH-dependent antioxidative enzymes, glutathione peroxidase (GPx) and glutathione reductase (GR), and heme oxygenase (HO)-1, as well as strengthened GSH content was induced by treatment with luteolin, which was in accordance with increased nuclear translocation of nuclear factor-erythroid 2 p45-related factor 2 (Nrf2), a transcription factor for phase 2 enzymes, in a dose-dependent manner. These results suggest that the cytoprotective potential of luteolin against oxidative damage can be attributed to fortified GSH-mediated antioxidative pathway and HO-1 expression through regulation of Nrf2 in HepG2 cells.

• Journal of the Korean Geosynthetics Society
• /
• v.3 no.2
• /
• pp.31-38
• /
• 2004

Long-term stability of two type geogrids were evaluated. Membrane drawn type geogrid showed the exponential type tensile property and textile type geogrid showed the rapid increase of tensile property closer toward the break point. Accelerated creep test was done for textile type geogrid but not done for membrane drawn type geogrid because of its thermal property. Creep strain for membrane drawn type geogrid was larger than the ultimate tensile strain by tensile test and reduction factor by creep deformation of textile type geogrid was smaller than that of membrane type geogrid.

• Steel and Composite Structures
• /
• v.17 no.2
• /
• pp.145-157
• /
• 2014

This study aimed to investigate the fatigue crack growth behavior of a kind of fiber metal laminates (FML) under four different stress levels. The FML specimen consists of three 2024-T3 aluminum alloy sheets and two layers of glass/epoxy composite lamina. Tensile-tensile cyclic fatigue tests were conducted on centrally notched specimen at four stress levels with various maximum values. A digital camera system was used to take photos of the propagating cracks on both sides of the specimens. Image processing software was adopted to accurately measure the length of the cracks on each photo. The test results show that: (1) a-N and da/dN-a curves of FML specimens can be divided into transient crack growth segment, steady state crack growth segment and accelerated crack growth segment; (2) compared to 2024-T3 aluminum alloy, the fatigue properties of FML are much better; (3) da/dN-${\Delta}K$ curves of FML specimens can be divided into fatigue crack growth rate decrease segment and fatigue crack growth rate increase segment; (3) the maximum stress level has a large influence on a-N, da/dN-a and da/dN-${\Delta}K$ curves of FML specimens; (4) the fatigue crack growth rate da/dN presents a nonlinear accelerated increasing trend to the maximum stress level; (5) the maximum stress level has an almost linear relationship with the stress intensity factor ${\Delta}K$.

• Advances in concrete construction
• /
• v.7 no.2
• /
• pp.75-85
• /
• 2019

The present study is focused on the mechanical and durability properties of ternary blended cement concrete mix of different grades 30 MPa, 50 MPa and 70 MPa. Three mineral admixtures (fly ash, silica fume and lime sludge) were used as a partial replacement of cement in the preparation of blended concrete mix. The durability of ternary blended cement concrete mix was studied by exposing it to acids HCl and $H_2SO_4$ at 5% concentration. Acid mass loss factors (AMLF), acid strength loss factor (ASLF) and acid durability factor (ADF) were determined, and the results were compared with the control mix. Chloride ions penetration was investigated by conducting rapid chlorination penetration test and accelerated corrosion penetration test on control mix and ternary blended cement concrete. From the results, it was evident that the usage of these mineral admixtures is having a beneficiary role on the strength as well as durability properties. The results inferred that the utilization of these materials as a partial replacement of cement have significantly enhanced the compressive strength of blended concrete mix in 30 MPa, 50 MPa and 70 MPa by 42.95%, 32.48% and 22.79%. The blended concrete mix shown greater resistance to acid attack compared to control mix concrete. Chloride ion ingress of the blended cement concrete mix was low compared to control mix implying the beneficiary role of mineral admixtures.

• Elastomers and Composites
• /
• v.52 no.4
• /
• pp.237-241
• /
• 2017

The tensile strength (TS) and elongation-at-break (EB) loss of a CR/CB rubber composite sample prepared for the automotive parts were measured after accelerated thermal ageing at temperatures of 100, 120, 140, and $150^{\circ}C$. The change in TS was observed to be linear from the master curve prepared using the time-temperature superposition-principle (TTSP). An Arrhenius type of shift factor, $a_T$ was used to predict the life time of the sample, and a plot of ln $a_T$ vs. 1/T was also shown to be linear. The activation energy ($E_a$) of the sample was calculated as 70.30 kJ/mole from the Arrhenius plot. The expected life time of the sample was predicted at the given operating conditions by applying Arrhenius analysis. Assuming the $E_a$ value was constant at lower operating condition, life time of the sample was calculated as 2.3 years when the life limit was set as time to reach the 20% decrease of the initial TS value at operating temperature of $40^{\circ}C$.