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Mechanical and durability properties of fly ash and slag based geopolymer concrete

  • Kurtoglu, Ahmet Emin;Alzeebaree, Radhwan;Aljumaili, Omar;Nis, Anil;Gulsan, Mehmet Eren;Humur, Ghassan;Cevik, Abdulkadir
    • Advances in concrete construction
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    • v.6 no.4
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    • pp.345-362
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    • 2018
  • In this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid ($H_2SO_4$), magnesium sulfate ($MgSO_4$) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid ($H_2SO_4$) was most dangerous environment for all concrete types.

Performance of self-compacting geopolymer concrete with and without GGBFS and steel fiber

  • Al-Rawi, Saad;Taysi, Nildem
    • Advances in concrete construction
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    • v.6 no.4
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    • pp.323-344
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    • 2018
  • The study herein reports the impact of Steel Fiber (SF) and Ground Granulated Blast Furnaces slag (GGBFS) content on the fresh and hardened properties of fly ash (FA) based Self-Compacting Geopolymer Concrete (SCGC). Two series of self-compacting geopolymer concrete (SCGC) were formulated with a constant binder content of $450kg/m^3$ and at an alkaline-to-binder (a/b) ratio of 0.50. Fly ash (FA) was substituted with GGBFS with the replacement levels being 0%, 25%, 50%, 75%, and 100% by weight in each SCGC series. Steel fiber (SF) wasn't employed in the assembly of the initial concrete series whereas, within the second concrete series, an SF combination was achieved by a constant additional level of 1% by volume. Fresh properties of mixtures were through an experiment investigated in terms of slump flow diameter, T50 slump flow time, V-funnel flow time, and L-box height ratio. Moreover, the mechanical performance of the SCGCs was evaluated in terms of compressive strength, splitting tensile strength, and fracture toughness. Furthermore, a statistical analysis was applied in order to judge the importance of the experimental parameters, like GGBFS and SF contents. The experimental results indicated that the incorporation of SF had no vital impact on the fresh characteristics of the SCGC mixtures whereas GGBFS aggravated them. However, the incorporation of GGBFS was considerably improved the mechanical properties of SCGCs. Moreover, the incorporation of SF with the total different quantity of GGBFS replacement has considerably increased the mechanical properties of SCGCs, by close to (65%) for the splitting strength and (200%) for compressive strength.

Experimental investigation of the stress-strain behavior of FRP confined concrete prisms

  • Hosseinpour, F.;Abbasnia, R.
    • Advances in concrete construction
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    • v.2 no.3
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    • pp.177-192
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    • 2014
  • One of the main applications of FRP composites is confining concrete columns. Hence identifying the cyclic and monotonic stress-strain behavior of confined concrete columns and the parameters influencing this behavior is inevitable. Two significant parameters affecting the stress-strain behavior are aspect ratio and corner radius. The present study aims to scrutinize the effects of corner radius and aspect ratio on different aspects of stress-strain behavior of FRP confined concrete specimens (rectangular, square and circular). Hence 44 FRP confined concrete specimens were tested and the results of the tests were investigated. The findings indicated that for specimens with different aspect ratios, the relationship between the ultimate stress and the corner radius is linear and the variations of the ultimate stress versus the corner radius decreases as a result of an increase in aspect ratio. It was also observed that increase of the corner radius results in increase of the compressive strength and ultimate axial strain and increase of the aspect ratio causes an increase of the ultimate axial strain but a decrease of the compressive strength. Investigation of the ultimate condition showed that the FRP hoop rupture strain is smaller in comparison with the one obtained from the tensile coupon test and also the ultimate axial strain and confined concrete strength are smaller when a prism is under monotonic loading. Other important results of this study were, an increase in the axial strain during the early stage of unloading paths and increase of the confining effect of FRP jacket with the increase and decrease of the corner radius and aspect ratio respectively, a decrease in the slope of reloading branches with cycle repetitions and the independence of this trend from the variations of the aspect ratio and corner radius and also quadric relationship between the number of each cycle and the plastic strain of the same cycle as well as the independence of this relationship from the aspect ratio and corner radius.

Treatment Results for Adenoid Cystic Carcinoma of the Major Salivary Gland (주타액선에서 발생한 선양낭세포암종의 방사선치료성적)

  • Lee Sang-Wook;Kim Gwi-Eon;Park Cheong-Soo;Choi Eun-Chang;Lee Kang-Kyoo;Park Won;Suh Chang-Ok
    • Korean Journal of Head & Neck Oncology
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    • v.18 no.2
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    • pp.197-202
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    • 2002
  • Purpose: This study was to investigate clinical feature of adenoid cystic carcinoma (ACC) in the major salivary gland. Materials and Methods: A retrospective analysis was undertaken for 23 patients with adenoid cystic carcinoma of the major salivary gland, who completed postoperative radiotherapy at the Yonsei Cancer Center, Yonsei University Hospital between May 1981 and December 1999. The male to female ratio was 1.1:1. Median age was 50. Follow up periods were 12-180 months with the median follow-up time of 59 months. Results: Parotid gland, submandibular gland and sublingual gland were 17, 5 and 1 respectively. Overall failure rate was 26%. Local failure was observed in two patients with parotid gland origin. Five cases showed distant failure. Overall and disease free survival rate were 68% and 72% respectively. Conclusion: Major pattern of failure was distant failure. Resection margin status had not prognostic significance. Postoperative radiation treatment is an effective to control in the adenoid cystic carcinoma of the major salivary gland.

ACCELERATION OF COSMIC RAYS AT COSMIC SHOCKS

  • KANG HYESUNG
    • Journal of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.1-12
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    • 2003
  • Nonthermal particles can be produced due to incomplete thermalization at collisionless shocks and further accelerated to very high energies via diffusive shock acceleration. In a previous study we explored the cosmic ray (CR) acceleration at cosmic shocks through numerical simulations of CR modified, quasi-parallel shocks in 1D plane-parallel geometry with the physical parameters relevant for the shocks emerging in the large scale structure formation of the universe (Kang & Jones 2002). Specifically we considered pancake shocks driven by accretion flows with $U_o = 1500 km\;s^{-l}$ and the preshock gas temperature of $T_o = 10^4 - 10^8K$. In order to consider the CR acceleration at shocks with a broader range of physical properties, in this contribution we present additional simulations with accretion flows with $U_o = 75 - 1500 km\;s^{-l}$ and $T_o = 10^4K$. We also compare the new simulation results with those reported in the previous study. For a given Mach number, shocks with higher speeds accelerate CRs faster with a greater number of particles, since the acceleration time scale is $t_{acc}\;{\propto}\;U_o^{-2}$. However, two shocks with a same Mach number but with different shock speeds evolve qualitatively similarly when the results are presented in terms of diffusion length and time scales. Therefore, the time asymptotic value for the fraction of shock kinetic energy transferred to CRs is mainly controlled by shock Mach number rather than shock speed. Although the CR acceleration efficiency depends weakly on a well-constrained injection parameter, $\epsilon$, and on shock speed for low shock Mach numbers, the dependence disappears for high shock Mach numbers. We present the 'CR energy ratio', ${\phi}(M_s)$, for a wide range of shock parameters and for $\epsilon$ = 0.2 - 0.3 at terminal time of our simulations. We suggest that these values can be considered as time-asymptotic values for the CR acceleration efficiency, since the time-dependent evolution of CR modified shocks has become approximately self-similar before the terminal time.

Effect of Triple Compared to Dual Antiplatelet Therapy After Drug-Eluting Stent Implantation in Percutaneous Coronary Intervention (관상동맥 약물 용출 스텐트 삽입 후 항혈소판제제 3제요법과 2제요법의 임상적 효과 비교)

  • Ye, Kyong-Nam;Kim, Jeong-Tae;Lee, Suk-Hyang
    • Korean Journal of Clinical Pharmacy
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    • v.22 no.2
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    • pp.113-122
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    • 2012
  • ACC/AHA/SCAI Guideline recommends for administration dual antiplatelet therapy after drug-eluting stent (DES) to prevent restenosis and stent thrombosis in patients with percutaneous coronary intervention (PCI). Recently triple antiplatelet therapy including cilostazol is known to reduce restenosis and stent thrombosis significantly after DES implantation. However, there is lack of data providing the efficacy of triple antiplatelet therapy. The purpose of this study is to evaluate the clinical effects of the triple therapy after DES implantation compared with the dual therapy. This retrospective study collected data from medical charts of 251 patients who received DES implantation between Jul 2006 and Jun 2008. They received either dual antiplatelet therapy (N = 154 clopidogrel and aspirin; Dual group) or triple antiplatelet therapy (N = 97 cliostazol, clopidogrel and aspirin; Triple group). Major adverse cardiac event rates (MACE, included total death, myocardial infarction, target lesion revascularization) at 12 months, 24 months, stent thrombosis, rates of bleeding complications and adverse drug reactions were compared between these two groups. Compared with the dual group, the triple group had a similar incidence of the MACE rates at 24months (12.3% vs. 12.4%, p = 0.99). There is no difference in overall stent thrombosis between two groups (Dual group 2.6% vs. Triple group 4.1%, p = 0.5). Subgroup analysis showed that diabetic patients got more benefit in reducing MACE rates but, there is no statistical difference. Bleeding complications and adverse drug effects were not different significantly. As compared with dual antiplatelet therapy, triple antiplatelet therapy did not reduce the 12-months, 24-months MACE rates and stent thrombosis. Bleeding complications and adverse drug effects were not different.

Improvement of Strength Characteristics in ALC added Silica Powder and Gypsum (규석 분말 및 석고 혼입에 따른 경량기포콘크리트의 강도특성 개선)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.128-135
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    • 2012
  • Autoclaved lightweight concrete, also known as autoclaved aerated concrete(AAC) or autoclaved cellular concrete (ACC), is made with fine silica powder, quik lime, cement, and an Al powder. ALC contains 70~80% air. The lightweight material offers excellent sound and thermal insulation, and like all cement-based materials, is strong and fire resistant. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. These properties make troubles under construction such as cracking and popout. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures, gypsum and silica powder size. Admixtures make use of metakaolin and silica fume. From the test result, the ALC using admixture have a good fundamental properties compared with plain ALC. Compressive strength, specific strength and abrasion's ratio were improved depending on increasing admixtures ratio's, gypsum and silica powder size.

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Acupuncture Effects of Fatty Mice Induced by High Fat Diet (침 자극이 고지방식이로 유발된 비만 백서에 미치는 영향)

  • Woo, Chang-Hoon;Lee, Yong-Eun;Roh, Sung-Soo;Kim, Jae-Soo
    • Journal of Korean Medicine Rehabilitation
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    • v.24 no.3
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    • pp.1-9
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    • 2014
  • Objectives The aim of this study was to investigate the effects of acupuncture on weight loss, food intake, lipid metabolism, adipogenesis. Methods Four week-old C57BL/6J mice acclimatized to the laboratory environment for 1 week were allocated into four groups of 6~8 mice each: normal diet group, high fat diet group, high fat diet group and treated with acupuncture at HT7, high fat diet group and treated with acupuncture at ST36 for 90days. High fat diet group was used to control group. Results 1) Body weight, food intake of the ST36, HT7 groups decreased compared with those of control group. ST36 group was more effective with body weight decrease, and HT7 group was more effective with food intake decrease. 2) NEFA, TG, TC, ALT, AST of the ST36, HT7 groups decreased compared with those of control group. ST36 group was more effective. 3) The expression of SREP-1c, SREBP-2 of the ST36 group decreased compared with those of control group. These decreased rates were statistically significant. SREBP-2 of the HT7 group decreased significantly compared to the control group. 4) LXR, FAS, SCD of the ST36 group decreased significantly compared with control group. 5) p-ACC, HMGCR of the ST36 group decreased significantly compared with those of control group. HMGCR of the HT7 group decreased significantly compared with control group. Conclusions These results suggest that ST36, HT7 acupuncture may be used prevent or treat the obesity induced by high fat diet.

DNA Polymorphism in SLC11A1 Gene and its Association with Brucellosis Resistance in Indian Zebu (Bos indicus) and Crossbred (Bos indicus×Bos taurus) Cattle

  • Kumar, Nishant;Ganguly, Indrajit;Singh, Rajendra;Deb, Sitangsu M.;Kumar, Subodh;Sharma, Arjava;Mitra, Abhijit
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.7
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    • pp.898-904
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    • 2011
  • The PCR- restriction fragment length polymorphism (RFLP) in and around TM4 of SLC11A1 gene and its association with the incidences of brucellosis in Hariana breed (Bos indicus) and Holstein Friesian crossbred (Bos indicus${\times}$Bos taurus) cattle was examined. A fragment of 954 bp encoding the TM4 was amplified, and RFLP was identified by digestion of the amplicon independently with AluI and TaqI. The amplicon (GenBank Acc. No. AY338470 and AY338471) comprised of a part of exon V (<59 bp) and VII (62>), and entire intron 5 (423 bp), exon VI (71 bp) and intron 6 (339 bp). Digestion with AluI revealed the presence of two alleles viz, A (281, 255, 79 and 51 bp) and B (541, 255, 79 and 51 bp). The frequency of A allele was estimated as 0.80 and 0.73 in Hariana and crossbred cattle, respectively. Due to presence of a polymorphic TaqI site at intron 5, two alleles: T (552 and 402 bp) and Q (231, 321 and 402 bp) were identified. The frequency of T allele was estimated as 0.96 and 0.97, respectively. For association study, on the basis of serological tests and history of abortion, the animals were grouped into "affected" and "non-affected". However, no association could be established with the observed RFLPs.

Radical Scavenging and Anti-Obesity Effects of 50% Ethanol Extract from Fermented Curcuma longa L. (발효울금 50% 에탄올 추출물의 라디칼 소거능 및 지방형성 억제 효과)

  • Kim, Jihye;Jun, Woojin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.2
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    • pp.281-286
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    • 2015
  • In this study, free radical scavenging activities (ABTS, DPPH, NBT, TBARS, and ORAC) and anti-obesity potential were evaluated using 50% ethanol extract from fermented Curcuma longa L. (FCE50). FCE50 showed free radical scavenging activities and anti-oxidant potential. Lipid accumulation and intracellular TG content were significantly reduced by 25.8% and 28.6%, respectively, by $250{\mu}g/mL$ of FCE50 compared to adipocytes. Glucose uptake was significantly reduced by 12.0%. FCE50 significantly reduced mRNA expression of acetyl-CoA carboxylase in 3T3-L1 cells. These results indicate that the anti-adipogenic effect of FCE50 might be due to its radical scavenging activity and anti-oxidant potential.