• Journal of the Korean Wood Science and Technology
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• v.12 no.3
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• pp.35-40
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• 1984

The ultraviolet absorption spectra of AcBr lignin (Acetyl Bromide lignin) from 10 species grown in Mt. Jiri were determined. There were 3 peak positions, at 249nm (max peak), at 267-268 nm (shallow min. peak) and at 280 nm (lower max. peak). The Bjorkman lignin and lignin sulfonic acid spectra had shoulders, but the AcBr lignin had not them. Average absorbances and absorptivities of the AcBr lignins at peak positions were $0.367{\pm}0.0015$, $24.56{\pm}0.0535$, at 249 nm, $0.278{\pm}0.0016$, $18.50{\pm}0.0569$, at 267-268 nm and $0.306{\pm}0.0016$, $20.42{\pm}0.0627$ at 280 nm, respectively.

• Journal of the Korean Wood Science and Technology
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• v.14 no.4
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• pp.14-20
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• 1986

These experiments were carried out to determine the ultraviolet absorption spectra of AcBr lignins(acetyl bromide lignin) from 10 hardwood species grown in Mt. Jiri. 1. There were 3 peak positions, at 249nm(max. peak), at 262-266nm(shallow min. peak) and at 270-280nm(lower max. peak). The Bj$\ddot{o}$rkman lignin and lignin sulfonatic acid spectra had shoulders, but the AcBr lignin didn't. 2. Average absorbances of the AcBr lignin at peak positions were 0.457${\pm}$0.0077 at 249nm, 0.297${\pm}$0.0029 at 262-266nm and 0.309${\pm}$0.0067 at 270-280nm. 3. Average absorptivities of the AcBr lignin at peak positions were 25.005${\pm}$0.3825 at 249nm, 16.264${\pm}$0.2347 at 262-266nm and 16.863${\pm}$0.3444 at 270-280nm. 4. AcBr lignin absorptivities in each species were as follows: 16.939${\pm}$0.3735 in Acer pseudo-sieboldianum var. koreanum, 17.411${\pm}$0.2937 in Carpinus laxiflora, 16.579${\pm}$0.4348 in Comus controversa, 16.385${\pm}$0.4140 in Fraxinus rhynchophylla, 16.287${\pm}$0.4156 in Meliosma myriantha, 16.492${\pm}$0.1432 in Platycarya strobilacea, 16.343${\pm}$0.3177 in Prunus sargentii, 17.549${\pm}$0.3253 in Sophora japanica, 18.400${\pm}$0.2925 in Stewartia koreana, 16.245${\pm}$0.4339 in Styrax obassia. 5. As the spectra of AcBr lignin from hardwood showed the unpromounced peak from 270nm to 280nm, it was supposed that thes hardwood lignins were the guaiacyl-syringyl copolymers.