• 제목/요약/키워드: Absorption spectroscopy

검색결과 1,067건 처리시간 0.029초

태양 직달광 관측 자료로부터 포름알데히드 연직 농도 산출 시 흡수단면적이 미치는 영향 연구 (Investigation of Absorption Cross-Section Effects on the Formaldehyde Column Density Retrieval from Direct Sun Measurement)

  • 박경;박정현;이한림
    • 대한원격탐사학회지
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    • 제39권5_1호
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    • pp.551-561
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    • 2023
  • 본 연구에서는 Pandora spectrometer system의 태양 직달광 관측 자료로부터 차등흡수분광법(differential optical absorption spectroscopy, DOAS)을 이용하여 포름알데히드(formaldehyde)의 경사칼럼농도(slant column density, SCD)를 산출할 때 스펙트럼 피팅(spectrum fitting) 파장 구간 및 흡수단면적이 산출에 미치는 영향을 조사하였다. 2022년 10월 12일에서 31일까지 서울 연세대학교에서 관측한 Pandora Level 1 자료를 사용하였다. The second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2)에서 사용하는 스펙트럼 피팅 파장 구간을 포함한 8가지 범위 및 흡수단면적 구성 7종을 기반으로 포름알데히드 칼럼농도를 산출하였다. 스펙트럼 피팅 파장 구간은 8가지 범위 중 336.5-359.0 nm 구간에서 피팅 후 잔여 신호와 포름알데히드 산출 오차가 최소로 확인되었다. 흡수단면적 구성 7종 중 CINDI-2 캠페인에서 사용하는 흡수단면적에 이산화질소 흡수단면적(220 K)을 추가하여 사용한 경우에 피팅 후 잔여 신호와 포름알데히드 산출 오차가 가장 작았으며 포름알데히드 농도가 안정적으로 산출되었다. 산출 정확도가 가장 높은 경우의 평균 포름알데히드 경사칼럼농도와 그 외 조건들에서 산출된 값들은 최소 4%에서 최대 40%까지 차이를 보였다.

A PRELIMINARY STUDY ON THE CHARACTERIZATION OF HONEY BY NEAR INFRARED SPECTROSCOPY

  • Davies, Anthony M.C.;Radovic, Branka;Fearn, Tom;Anklam, Elke
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1052-1052
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    • 2001
  • Hear infrared (NIR) spectra were measured, at five temperatures, for forty-eight samples of honey, from a variety of geographical and botanical sources, and the data has been used to explore the possibility of using NIR spectroscopy for testing label claims concerning the geographical and botanical source of honey being offered for sale to the public. These results demonstrate that the successful characterization of the botanical source of a honey may be obtained by NIR spectroscopy. Further work with large numbers of samples and groups will be required to realized this potential. Additional analysis of these data suggest that research into new ways of obtaining information on the change of absorption with temperature might be beneficial for a range of technologies.

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Synthesis and spectroscopic characterization of zinc ferrite nanoparticles

  • Arora, Shefali;Nandy, Subhajit;Latwal, Mamta;Pandey, Ganesh;Singh, Jitendra P.;Chae, Keun H.
    • Advances in nano research
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    • 제13권5호
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    • pp.437-451
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    • 2022
  • Synthesis approaches usually affect the physical and chemical properties of ferrites. This helps ferrite materials to design them for desired applications. Some of these methods are mechanical milling, ultrasonic method, micro-emulsion, co-precipitation, thermal decomposition, hydrothermal, microwave-assisted, sol-gel, etc. These methods are extensively reviewed by taking example of ZnFe2O4. These methods also affect the microstructure and local structure of ferrite which ultimately affect the physical and chemical properties of ferrites. Various spectroscopic techniques such as Raman spectroscopy, Fourier Transform Infrared spectroscopy, Ultra Violet-Visible spectroscopy, Mossbauer spectroscopy, extended x-ray absorption fine structure, and electron paramagnetic resonance are found helpful to reveal this information. Hence, the basic principle and the usefulness of these techniques to find out appropriate information in ZnFe2O4 nanoparticles is elaborated in this review.

Measurement of Hydroxyl Radical Density at Bio-Solutions Generated from the Atmospheric Pressure Non-Thermal Plasma Jet

  • Kim, Yong Hee;Hong, Young June;Uhm, Han Sub;Choi, Eun Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.494-494
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    • 2013
  • Atmospheric pressure non-thermal plasma of the needle-typed interaction with aqueous solutions has received increasing attention for their biomedical applications [1]. In this context, surface discharges at bio-solutions were investigated experimentally. We have generated the non-thermal plasma jet bombarding the bio-solution surface by using an Ar gas flow and investigated the emission lines by OES (optical emission spectroscopy) [2]. Moreover, The non-thermal plasma interaction with bio-solutions has received increasing attention for their biomedical applications. So we researched, the OH radical density of various biological solutions in the surface by non-thermal plasma were investigated by Ar gases. The OH radical density of DI water; deionized water, DMEM Dulbecco's modified eagle medium, and PBS; 1x phosphate buffered saline by non-thermal plasma jet. It is noted that the OH radical density of DI water and DMEM are measured to be about $4.33{\times}1016cm-3$ and $2.18{\times}1016cm-3$, respectively, under Ar gas flow 250 sccm (standard cubic centimeter per minute) in this experiment. The OH radical density of buffer solution such as PBS has also been investigated and measured to be value of about $2.18{\times}1016cm-3$ by the ultraviolet optical absorption spectroscopy.

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초분광 광학가시화 기술을 활용한 인공지능 산소온도 측정기술 개발 (Development of AI oxygen temperature measurement technology using hyperspectral optical visualization technology)

  • 이정훈;김보라;이승훈;김준식;윤민;조경래
    • 한국가시화정보학회지
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    • 제21권1호
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    • pp.103-109
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    • 2023
  • This research developed a measurement technique that can measure the oxygen temperature inside a high temperature furnace. Instead of measuring only changes in frequency components within a small range used in the existing variable laser absorption spectroscopy, laser spectroscopy technology was used to spread out wavelength of the light source passing through the gas Based on a total of 20,000 image data, research was conducted to predict the temperature of a high-temperature furnace using CNN with black and white images in the form of spectral bands by temperature of 25 to 800 degrees. The optimal model was found through Hyper parameter optimization, R2 score is 0.89, and the accuracy of the test data is 88.73%. Based on this research, it is expected that concentration measurement and air-fuel ratio control technology can be applied.

NEAR-INFRARED HIGH-RESOLUTION SPECTROSCOPY OF THE OBSCURED AGN IRAS 01250+2832

  • Shirahata, M.;Usuda, T.;Oyabu, S.;Nakagawa, T.;Yamamura, I.
    • 천문학논총
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    • 제27권4호
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    • pp.295-296
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    • 2012
  • We provide a new physical insight on the hot molecular clouds near the nucleus of the heavily obscured AGN IRAS 01250+2832, based on the results of near-infrared high-resolution spectroscopy of gaseous CO ro-vibrational absorption lines with Subaru/IRCS. The detected CO absorption lines up to highly excited rotational levels reveal that hot dense molecular clouds exist around the AGN under the peculiar physical conditions.

Simple fabrication route for vertically-aligned CZTS nanorod arrays for photoelectrochemical application based on AAO template

  • 김지민;양우석;오윤정;문주호
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.402.2-402.2
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    • 2016
  • In photoelectrochemical (PEC) water splitting, Cu2ZnSnS4 (CZTS) compound has attracted intense attention as a photocathode due to not only large optical absorption coefficient, but also earth-abundance of constituent elements and suitable band alignment. With rapid development of nanotechnology, one-dimensional nanostructures of CZTS have been investigated as a potential form to achieve high efficiency because the nanostructures are expected to be capable of capturing more light and enhancing charge separation and transport. Here, we report a well-controlled fabrication route for vertically-aligned CZTS nanorod arrays on anodic aluminium oxide (AAO) template via simple sol-gel process followed by deposition of ZnS or CdS buffer layers on the CZTS nanorod to enhance charge separation. The structure, morphology, composition, optical absorption, and PEC properties of the resulting CZTS nanorod samples were characterized using X-ray diffraction, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray spectrometry, scanning electron microscopy, and UV-vis spectroscopy.

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Trace elements analysis in some medicinal plants using graphite furnace-atomic absorption spectroscopy

  • Anal, Jasha Momo H.;Chase, Petevino
    • Environmental Engineering Research
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    • 제21권3호
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    • pp.247-255
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    • 2016
  • Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

Spatiotemporal Behavior of the Excited Xe Atom Density in the $1s_5$ Metastable State According to the Hoof-type Electrode Structure in an Alternating-current Plasma Display Pane

  • Kim, Yong-Hee;Hong, Young-June;Choi, Joon-Ho;Cho, Byeong-Seong;Uhm, Han-Sub;Choi, Eun-Ha
    • Journal of Information Display
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    • 제11권4호
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    • pp.149-153
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    • 2010
  • To improve the luminescence characteristics of high-efficiency alternating-current plasma display panels (AC-PDPs), we developed a new hoof-type electrode structure, and we studied the spatiotemporal behavior of the density of the excited Xenon atom in the $1s_5$ metastable state via laser absorption spectroscopy. Using this structure, the maximum density of the excited Xenon atom per cell was improved by 2.4 times that when the conventional electrode structure was used.

Photoisomerization and Photo-induced Optical Anisotropy of Polymethacrylate Containing Aminonitroazobenzene

  • Park, Dong-Hoon;Cho, Kang-Jin
    • Fibers and Polymers
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    • 제2권1호
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    • pp.123-130
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    • 2001
  • Photoresponsive side chain copolymer and homopolymer containing an aminonitroazobenzene were synthesized for studying photoisomerization behavior and photo-induced anisotropy. Trans-to-cis photoisomerization was observed under the exposure of a circularly polarized visible light with UV-Vis absorption spectroscopy. Reorientation of polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532nm. Polarized absorption spectroscopy was employed to investigate the anisotropy of the polymer film during irradiationg of the excitation light. Layers of two photosensitive polymers were used for aligning liquid crystal(LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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