• Title/Summary/Keyword: Absorption model

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Estimation of Carbon Absorption Distribution based on Satellite Image Considering Climate Change Scenarios (기후변화 시나리오를 고려한 위성영상 기반 미래 탄소흡수량 분포 추정)

  • Na, Sang-il;Ahn, Ho-yong;Ryu, Jae-Hyun;So, Kyu-ho;Lee, Kyung-do
    • Korean Journal of Remote Sensing
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    • v.37 no.5_1
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    • pp.833-845
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    • 2021
  • Quantification of carbon absorption and understanding the human induced land use changes forms one of the major study with respect to global climatic changes. An attempt study has been made to quantify the carbon absorption by land use changes through remote sensing technology. However, it focused on past carbon absorption changes. So prediction of future carbon absorption changes is insufficient. This study simulated land use change using the Conversion of Land Use and its Effects at Small regional extent (CLUE-S) model and predicted future changes in carbon absorption considering climate change scenarios 4.5 and 8.5 of the Representative Concentration Pathways (RCP). Results of this study, in the RCP 4.5 scenarios there predicted to be loss of 7.92% of carbon absorption, but in the RCP 8.5 scenarios was 13.02%. Therefore, the approach used in this study is expected to enable exploration of future carbon absorption change considering other climate change scenarios.

Microwave-assisted Solvent-free Synthesis of Some Dimethine Cyanine Dyes, Spectral Properties and TD-DFT/PCM Calculations

  • Zhang, Xiang-Han;Wang, Lan-Ying;Zhai, Gao-Hong;Wen, Zhen-Yi;Zhang, Zu-Xun
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2382-2388
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    • 2007
  • A series of dimethine cyanine dyes were synthesized in a fast, efficient and high yield by the condensation of quaternary salts with 1H-indole-3-carbaldehyde in the presence of piperidine under solvent-free microwave irradiation. The products were identified by 1H NMR, IR, UV-Vis spectra and elemental analysis. The absorption and fluorescence properties of these dyes were investigated both experimentally and theoretically. Calculations performed at a combination of time-dependent density functional theory (TD-DFT) and the polarizable continuum model (PCM) reproduced the π-π* type absorption bands of the dyes. Regression analysis was used for studying theoretical results of the absorption maxima in different solvents. Compared with experimental counterparts, estimated overall uncertainties in the absorption maxima were about ±2%.

Effect of elasticity of aqueous colloidal silica solution on chemical absorption of carbon dioxide with 2-amino-2-methyl-1-propanol

  • Park, Sang-Wook;Choi, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.18 no.3
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    • pp.133-141
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    • 2006
  • Carbon dioxide was absorbed into the aqueous nanometer sized colloidal silica solution of 0-31 wt% and 2-amino-2-methyl-1-propanol of $0-2kmol/m^3$ in a flat-stirred vessel with the impeller of various sizes and speeds at $25^{\circ}C$ and 0.101 MPa to measure the absorption rate of $CO_2$. The volumetric liquid-side mass transfer coefficient$(k_La)\;of\;CO_2$ was used to obtain the empirical correlation formula containing the rheological behavior of the aqueous colloidal silica solution. Reduction of the measured $k_La$ was explained by the viscoelastic properties of the aqueous colloidal silica solution. The theoretical value of the absorption rate of $CO_2$ was estimated from the model based on the film theory accompanied by chemical reaction and compared with the measured value.

Nonlinear Impedance Characteristics of Helmholtz Resonator with Tapered Neck (경사진 목을 가지는 헬름홀쯔 공명기의 비선형 임피던스 특성)

  • Seo, Sang-Hyeon;Chung, Hoe-min;Kim, Yang-hann
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2012.10a
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    • pp.75-80
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    • 2012
  • Helmholtz resonator is widely used acoustic instrument which has high absorption characteristics at its resonance frequency. Particularly it maintains good performance even in the low frequency region that is difficult to control by general porous absorptive materials. However, under severely high sound pressure level, the absorption characteristics are changed by increase of resistance due to nonlinear behavior of neck impedance. Because of this nonlinear behavior, it is difficult to obtain the expected absorption performance under high sound pressure environment. Thus, in order to prevent excessive rise of resistance, the resonator with neck having cross section dimension decrease away from the entry of the resonator cavity could be suggested. This paper introduces the experiment method and results about nonlinear characteristics of Helmholtz resonator with tapered neck and proposes the approximate nonlinear impedance model.

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Dynamic Analysis of Single-Effect/Double-Lift Libr-Water Absorption System using Low-Temperature Hot Water (저온수를 이용하는 일중효용/이단승온 리튬브로마이드-물 흡수식 시스템의 동적 해석)

  • Kim, Byong-Joo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.12
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    • pp.695-702
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    • 2009
  • Dynamic behavior of Libr-water absorption system using low-temperature hot water was investigated numerically. Thermal-hydraulic model of single-effect/double-lift 100 RT chiller was developed by applying transient conservation equations of total mass, Libr mass, energy and momentum to each component. Transient variations of system properties and transport variables were analysed during start-up operation. Numerical analysis were performed to quantify the effects of bulk concentration and part-load operation on the system performance in terms of cooling capacity, coefficient of performance, and time constant of system. For an absorption chiller considered in the present study, optimum bulk concentration was found to exist, which resulted in the minimum time constant with stable cooling capacity. COP and time constant increased as the load decreased down to 40%, below which the time constant increased abruptly and COP decreased as the load decreased further.

Dynamic Analysis of an Ammonia-Water Absorption Chiller (암모니아-물 흡수식 냉각기의 동적 해석)

  • Kim Byong Joo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.10
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    • pp.990-998
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    • 2004
  • Dynamic behavior of an ammonia-water absorption system was investigated numerically. Thermal-hydraulic model for a single-effect 3 RT chiller was developed by applying transient conservation equations of total mass, $NH_3$ mass, energy and momentum to each component. Transient variations of system properties and transport variables were analysed during start-up operation. Numerical analyses were performed to quantify the effects of bulk concentration and charging ratio on the system performance in terms of cooling capacity, coefficient of performance, and time constant of system. For an absorption chiller considered in the present study, optimum charging ratio and bulk concentration were to found to exist, which resulted in the maximum cooling capacity and COP. The time constant increased as the charging ratio increased, but decreased with the increase of bulk concentration.

A Theoretical Study on the Low Transition Temperature of VO2 Metamaterials in the THz Regime

  • Kyoung, Jisoo
    • Current Optics and Photonics
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    • v.6 no.6
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    • pp.583-589
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    • 2022
  • Vanadium dioxide (VO2) is a well-known material that undergoes insulator-to-metal phase transition near room temperature. Since the conductivity of VO2 changes several orders of magnitude in the terahertz (THz) spectral range during the phase transition, VO2-based active metamaterials have been extensively studied. Experimentally, it is reported that the metal nanostructures on the VO2 thin film lowers the critical temperature significantly compared to the bare film. Here, we theoretically studied such early transition phenomena by developing an analytical model. Unlike experimental work that only measures transmission, we calculate the reflection and absorption and demonstrate that the role of absorption is quite different for bare and patterned samples; the absorption gradually increases for bare film during the phase transition, while an absorption peak is observed at the critical temperature for the metamaterials. In addition, we also discuss the gap width and VO2 thickness effects on the transition temperatures.

Theoretical Modeling of the Internal Power Flow and Absorption Loss of the Air Mode Based on the Proposed Poynting Vector Analysis in Top-emitting Organic Light-emitting Diodes

  • Kim, Jiyong;Kim, Jungho;Kim, Kyoung-Youm
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1663-1674
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    • 2018
  • We propose the Poynting vector analysis of the air mode in a top-emitting organic light-emitting diode (OLED) by combining the transfer matrix method and dipole source term. The spatial profiles of the time-averaged optical power flow of the air mode are calculated inside and outside the multilayer structure of the OLED with respect to the thickness of the semi-transparent top cathode and capping layer (CPL). We elucidate how the micro-cavity effect controlled by the thickness variation of the semi-transparent top cathode or CPL affects the internal optical power and absorption loss inside the OLED multilayer and the external optical power coupled into the air. When the calculated absorption loss and external power obtained by the proposed Poynting vector and currently-used point dipole models are compared, two calculation results are identical, which demonstrates the validity of the two models.

A Study of Future Residential Land Use Change considering Climate Change using Land Use Equilibrium Model in Jeju (토지이용균형 모델을 이용한 기후변화에 따른 주거용 토지이용변화 - 제주 지역을 대상으로 -)

  • Yoo, Somin;Lee, Woo-Kyun;Yamagata, Yoshiki;Kim, Jiyoung;Kim, Moon-Il;Lim, Chul-Hee
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.1-10
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    • 2015
  • Climate change lead to environmental pollution caused by the radical economic growth and development of industry. The amount of damage from abnormal climate is increasing rapidly for this reason in Korea. In particular, the cities is a lot of carbon emission quantity from the radical growth. Thus the government present "low carbon green growth" for eco-friendly city planning. As one of the important factors effecting climate change, active researches on land use change is performed. In this study, we knew land use change of each scenarios using land use equilibrium model which is kind of predictive model of land use in Japan. First, we selected study area to Jeju lsland. For this study, indicators for input data were selected and spatial data for input data were established using GIS program. Second, we established future scenarios based in 2040s. There are 2 future scenarios: dispersion scenario, compact scenario. Third, we compared with residential area of current and residential area for future scenarios. Results showed that residential area of the difference between current and dispersion scenario were 1,230 ha and residential area of the difference between current and compact scenario were 1,515 ha. Finally, for comparing carbon dioxide absorption volume between dispersion scenarios and compact scenarios, we calculated carbon dioxide absorption volume according to residential area decreased of each future scenarios. Results showed that carbon dioxide absorption volume in dispersion scenario was 477,878 ton and carbon dioxide absorption volume in compact scenario was 588,606 ton. Therefore, the study showed that land use equilibrium model is expected to put to use for future enhancement in creating data for climate change stabilization. And it is also expected to be utilized for city planning research in Korea.

Evaluation of Dermal Absorption Rate of Pesticide Chlorpyrifos Using In Vitro Rat Dermal Tissue Model and Its Health Risk Assessment

  • Kim, Su-Heyun;Jang, Jae-Bum;Park, Kyung-Hun;Paik, Min-Kyoung;Jeong, Sang-Hee
    • Biomedical Science Letters
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    • v.22 no.4
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    • pp.140-149
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    • 2016
  • All pesticides must be assessed strictly whether safe or not when agricultural operators are exposed to the pesticides in farmland. A pesticide is commonly regarded as safe when estimated dermal absorption amount is lower than the acceptable operator's exposure level (AOEL). In this study, dermal absorption rate of chlorpyrifos, a widely used organophosphate insecticide, was investigated using rat dermal tissue model. Chlorpyrifos wettable powder solved in water (250, 500 and 2,500 ppm) was applied to freshly excised rat dermal slices ($341{\sim}413{\mu}m$ thickness) on static Franz diffusion cells at $32^{\circ}C$ for 6 hours. After exposure period of 6 hours, and then washing-at residual amount of chlorpyrifos was analyzed in dermal tissues, tape strips, washing solution, washing swabs of receptor bottles and receptor fluids at 1, 2, 4, 8 and 24 hours. Chlorpyrifos was only detected in dermal tissue but not found in receptor fluid at each concentration and time point, and the absorption rate of 250, 500 and 2,500 ppm was 2.36%, 1.96% and 1.69%, respectively. The estimated exposure level of chlorpyrifos was calculated as 0.012 mg/kg bw/day. The health risk for farmers in this condition is a level of concern because the estimated exposure level is 12 times higher than AOEL 0.001 mg/kg bw/day. However, actual health risk will be alleviated than estimated because absorbed chlorpyrifos is not permeated into internal body system and only retained in skin layer.