• Title/Summary/Keyword: Absorption Spectroscopy

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Investigation of Absorption Cross-Section Effects on the Formaldehyde Column Density Retrieval from Direct Sun Measurement (태양 직달광 관측 자료로부터 포름알데히드 연직 농도 산출 시 흡수단면적이 미치는 영향 연구)

  • Gyeong Park;Jeonghyeon Park;Hanlim Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.5_1
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    • pp.551-561
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    • 2023
  • In this study, we investigated the effects of the spectral fitting window and absorption cross-section on the retrieval of the formaldehyde (HCHO) slant column density (SCD) from the direct-sun measurement of pandora spectrometer system using differential optical absorption spectroscopy (DOAS). Pandora Level 1 data observed at Yonsei University in Seoul from October 12 to 31, 2022 were used. The HCHO column density was retrieved under eight ranges including the spectral fitting window used in the Second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2) and seven types of absorption cross-section composition. The spectral fitting window was selected from 336.5 to 359.0 nm with minimum residual and HCHO SCD error. When the nitrogen dioxide (NO2) absorption cross-section at 220 K was added to the cross-section composition used in the CINDI-2 campaign among seven types, the residual and HCHO SCD error were the smallest and the HCHO column density wasstably retrieved. The average HCHO SCD with the highest retrieval accuracy and the values retrieved under other conditions differed from a minimum of 4% to a maximum of 40%.

A PRELIMINARY STUDY ON THE CHARACTERIZATION OF HONEY BY NEAR INFRARED SPECTROSCOPY

  • Davies, Anthony M.C.;Radovic, Branka;Fearn, Tom;Anklam, Elke
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1052-1052
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    • 2001
  • Hear infrared (NIR) spectra were measured, at five temperatures, for forty-eight samples of honey, from a variety of geographical and botanical sources, and the data has been used to explore the possibility of using NIR spectroscopy for testing label claims concerning the geographical and botanical source of honey being offered for sale to the public. These results demonstrate that the successful characterization of the botanical source of a honey may be obtained by NIR spectroscopy. Further work with large numbers of samples and groups will be required to realized this potential. Additional analysis of these data suggest that research into new ways of obtaining information on the change of absorption with temperature might be beneficial for a range of technologies.

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Synthesis and spectroscopic characterization of zinc ferrite nanoparticles

  • Arora, Shefali;Nandy, Subhajit;Latwal, Mamta;Pandey, Ganesh;Singh, Jitendra P.;Chae, Keun H.
    • Advances in nano research
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    • v.13 no.5
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    • pp.437-451
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    • 2022
  • Synthesis approaches usually affect the physical and chemical properties of ferrites. This helps ferrite materials to design them for desired applications. Some of these methods are mechanical milling, ultrasonic method, micro-emulsion, co-precipitation, thermal decomposition, hydrothermal, microwave-assisted, sol-gel, etc. These methods are extensively reviewed by taking example of ZnFe2O4. These methods also affect the microstructure and local structure of ferrite which ultimately affect the physical and chemical properties of ferrites. Various spectroscopic techniques such as Raman spectroscopy, Fourier Transform Infrared spectroscopy, Ultra Violet-Visible spectroscopy, Mossbauer spectroscopy, extended x-ray absorption fine structure, and electron paramagnetic resonance are found helpful to reveal this information. Hence, the basic principle and the usefulness of these techniques to find out appropriate information in ZnFe2O4 nanoparticles is elaborated in this review.

Measurement of Hydroxyl Radical Density at Bio-Solutions Generated from the Atmospheric Pressure Non-Thermal Plasma Jet

  • Kim, Yong Hee;Hong, Young June;Uhm, Han Sub;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.494-494
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    • 2013
  • Atmospheric pressure non-thermal plasma of the needle-typed interaction with aqueous solutions has received increasing attention for their biomedical applications [1]. In this context, surface discharges at bio-solutions were investigated experimentally. We have generated the non-thermal plasma jet bombarding the bio-solution surface by using an Ar gas flow and investigated the emission lines by OES (optical emission spectroscopy) [2]. Moreover, The non-thermal plasma interaction with bio-solutions has received increasing attention for their biomedical applications. So we researched, the OH radical density of various biological solutions in the surface by non-thermal plasma were investigated by Ar gases. The OH radical density of DI water; deionized water, DMEM Dulbecco's modified eagle medium, and PBS; 1x phosphate buffered saline by non-thermal plasma jet. It is noted that the OH radical density of DI water and DMEM are measured to be about $4.33{\times}1016cm-3$ and $2.18{\times}1016cm-3$, respectively, under Ar gas flow 250 sccm (standard cubic centimeter per minute) in this experiment. The OH radical density of buffer solution such as PBS has also been investigated and measured to be value of about $2.18{\times}1016cm-3$ by the ultraviolet optical absorption spectroscopy.

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Development of AI oxygen temperature measurement technology using hyperspectral optical visualization technology (초분광 광학가시화 기술을 활용한 인공지능 산소온도 측정기술 개발)

  • Jeong Hun Lee;Bo Ra Kim;Seung Hun Lee;Joon Sik Kim;Min Yoon;Gyeong Rae Cho
    • Journal of the Korean Society of Visualization
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    • v.21 no.1
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    • pp.103-109
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    • 2023
  • This research developed a measurement technique that can measure the oxygen temperature inside a high temperature furnace. Instead of measuring only changes in frequency components within a small range used in the existing variable laser absorption spectroscopy, laser spectroscopy technology was used to spread out wavelength of the light source passing through the gas Based on a total of 20,000 image data, research was conducted to predict the temperature of a high-temperature furnace using CNN with black and white images in the form of spectral bands by temperature of 25 to 800 degrees. The optimal model was found through Hyper parameter optimization, R2 score is 0.89, and the accuracy of the test data is 88.73%. Based on this research, it is expected that concentration measurement and air-fuel ratio control technology can be applied.

NEAR-INFRARED HIGH-RESOLUTION SPECTROSCOPY OF THE OBSCURED AGN IRAS 01250+2832

  • Shirahata, M.;Usuda, T.;Oyabu, S.;Nakagawa, T.;Yamamura, I.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.295-296
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    • 2012
  • We provide a new physical insight on the hot molecular clouds near the nucleus of the heavily obscured AGN IRAS 01250+2832, based on the results of near-infrared high-resolution spectroscopy of gaseous CO ro-vibrational absorption lines with Subaru/IRCS. The detected CO absorption lines up to highly excited rotational levels reveal that hot dense molecular clouds exist around the AGN under the peculiar physical conditions.

Simple fabrication route for vertically-aligned CZTS nanorod arrays for photoelectrochemical application based on AAO template

  • Kim, Ji-Min;Yang, U-Seok;O, Yun-Jeong;Mun, Ju-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.402.2-402.2
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    • 2016
  • In photoelectrochemical (PEC) water splitting, Cu2ZnSnS4 (CZTS) compound has attracted intense attention as a photocathode due to not only large optical absorption coefficient, but also earth-abundance of constituent elements and suitable band alignment. With rapid development of nanotechnology, one-dimensional nanostructures of CZTS have been investigated as a potential form to achieve high efficiency because the nanostructures are expected to be capable of capturing more light and enhancing charge separation and transport. Here, we report a well-controlled fabrication route for vertically-aligned CZTS nanorod arrays on anodic aluminium oxide (AAO) template via simple sol-gel process followed by deposition of ZnS or CdS buffer layers on the CZTS nanorod to enhance charge separation. The structure, morphology, composition, optical absorption, and PEC properties of the resulting CZTS nanorod samples were characterized using X-ray diffraction, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray spectrometry, scanning electron microscopy, and UV-vis spectroscopy.

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Trace elements analysis in some medicinal plants using graphite furnace-atomic absorption spectroscopy

  • Anal, Jasha Momo H.;Chase, Petevino
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.247-255
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    • 2016
  • Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

Spatiotemporal Behavior of the Excited Xe Atom Density in the $1s_5$ Metastable State According to the Hoof-type Electrode Structure in an Alternating-current Plasma Display Pane

  • Kim, Yong-Hee;Hong, Young-June;Choi, Joon-Ho;Cho, Byeong-Seong;Uhm, Han-Sub;Choi, Eun-Ha
    • Journal of Information Display
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    • v.11 no.4
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    • pp.149-153
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    • 2010
  • To improve the luminescence characteristics of high-efficiency alternating-current plasma display panels (AC-PDPs), we developed a new hoof-type electrode structure, and we studied the spatiotemporal behavior of the density of the excited Xenon atom in the $1s_5$ metastable state via laser absorption spectroscopy. Using this structure, the maximum density of the excited Xenon atom per cell was improved by 2.4 times that when the conventional electrode structure was used.

Photoisomerization and Photo-induced Optical Anisotropy of Polymethacrylate Containing Aminonitroazobenzene

  • Park, Dong-Hoon;Cho, Kang-Jin
    • Fibers and Polymers
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    • v.2 no.1
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    • pp.123-130
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    • 2001
  • Photoresponsive side chain copolymer and homopolymer containing an aminonitroazobenzene were synthesized for studying photoisomerization behavior and photo-induced anisotropy. Trans-to-cis photoisomerization was observed under the exposure of a circularly polarized visible light with UV-Vis absorption spectroscopy. Reorientation of polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532nm. Polarized absorption spectroscopy was employed to investigate the anisotropy of the polymer film during irradiationg of the excitation light. Layers of two photosensitive polymers were used for aligning liquid crystal(LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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