• Title/Summary/Keyword: Absorption Spectroscopy

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EVALUATION OF RAPID DETERMINATION OF PHOSPHORUS IN SOILS BY NIR SPECTROSCOPY

  • Ryu, Kwan-Shig;Kim, Book-Jin;Park, Jin-Sook
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1072-1072
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    • 2001
  • The purpose of this research is to evaluate rapid determination of phosphorus in soils using NIR spectroscopy. The soil samples from the fields subject to different crops and land-use in Kyeongbook province, Korea were used to make the calibration and validation of the calibration set estimating phosphorus in soil. The NIR reflectance was scanned at 2nm intervals from 1100 to 2500nm with an InfraAlyzer 500 (Bran+Luebbe Co.). Various regression analyses were used to evaluate a NIRS method for determination of phosphorus in the soil. NIR absorption approach requires many soil samples to obtain optimal prediction. Applicability of NIR spectra technique may allow for the analysis of available soil phosphorus rapidly as well as total component within a few seconds.

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ESR Spectroscopy for Detecting Gamma-Irradiated Shellfishes (방사선 조사된 조개류의 확인을 위한 ESR Spectroscopy의 이용)

  • 남혜선;양재승
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.1
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    • pp.43-47
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    • 2001
  • Electron spin resonance (ESR) spectroscopy was used to investigate the effect of irradiation dose on the ESR signal intensity and to identify the stability of radicals after 9 weeks of storage in order to detect irradiated shellfishes. The irradiated shellfishes (short-necked clam, purplish washington clam, freshwater clam, jackknifed clam, scallop and hard-shell mussel) presented an asymmetric absorption in shape at $g_{1}$=2.002~2.003 and $g_{2}$=1.998. The strength of the ESR signal increased linearly with the applied doses (1~7 kGy). A highly positive correlation coefficients ($R^{2}$=0.9136~0.9896) were obtained between the irradiation dose and corresponding ESR signal intensity. The intensity of the signals after irradiation was stable even after 9 weeks of storage at 5$\pm$1$^{\circ}C$.

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Catalytic Breakdown of Graphene by Gold

  • Lee, Gyeong-Jae;Yang, Mi-Hyeon;Im, Gyu-Uk;Gang, Tae-Hui;Jeong, Seok-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.214-214
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    • 2012
  • It was reported that oxidative etching of graphene occurs at about $450-550^{\circ}C$ under oxygen atmosphere. We found catalytic breakdown of graphene by Au on the SiOx surface. This catalytic process was investigated using x-ray photoelectron spectroscopy and absorption spectroscopy at 4D PES beamline in PAL. Spectrosopic results suggest that the destruction of graphene is initiated by catalytic interaction between the oxidized gold and carbons in vacancy defects of graphene.

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Characterization of uranium species in molten salt : An application of synchrotron-based XAFS spectroscopy

  • Cho, Young-Hwan;Choi, In-Kyu;Kim, Won-Ho
    • Proceedings of the Korean Nuclear Society Conference
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    • 2002.10a
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    • pp.319.2-319
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    • 2002
  • Synchrotron-based X-ray absorption spectroscopy has been applied to determine the changes in bulk oxidation state of uranium oxides in molten salt. From an analysis of XANES data, one can determine the cahnges in bulk oxidation-state of U compounds in salts(LiCl/KCl). XAFS spectroscpy is a powerful tool for probing the changes in valence state and structure of uranium compounds in colten salt as well as in noncrystalline form and doped in other matrices.

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Measurement of Glucose concentration using Polarization Sensitive Low Coherence Interferometer (Polarization Sensitive Low Coherence Interferometer를 이용한 Glucose 농도 측정)

  • 이상원;김법민
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.128-129
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    • 2003
  • 최근 수년간 polarimetry, Raman spectroscopy, near infrared (NIR) absorption spectroscopy, NIR scattering, optoacoustics 등의 방법을 통하여 비침습적으로 Glucose의 농도를 측정하려는 연구가 많이 시도되었다. 일반적으로 이들 방법은 sensitivity 와 signal-to-noise ratio가 매우 낮고 복잡한 알고리즘이 요구되어져 glucose 농도 측정에 한계가 있음이 드러났다. 본 연구에서는 polarization sensitive optical coherence tomography (PS-OCT)에 사용되는 polarization sensitive low coherence inter-ferometer (PS-LCI) 기법을 이용하여 비침습적으로 glucose의 농도 측정을 가능하게 하는 시스템 개발에 중점을 두었다. (중략)

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Study of Synthesis and Optical Characterization of Amino-functionalized Tetraphenylsilole (아미노기로 기능화 된 실올의 합성 및 광학적 특성에 관한 연구)

  • Cho, Sungdong
    • Journal of Integrative Natural Science
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    • v.2 no.3
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    • pp.194-197
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    • 2009
  • Organometallic containing silole unit has been interested, since silole has a unique optical and electronic properties. The main goal of this work is to develop new selective sensors for organosilicon of 1-methyl-2,3,4,5-tetraphenyl-1H-silole and 1-methyl-1-(3-aminopropyl)-2,3,4,5-tetraphenylsilole based on new silole have been characterized by UV-vis absorption spectroscopy. their optical characteristics have been also investigate using photoluminescence spectroscopy.

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Measurement of Stokes parameter changes due to blood glucose using PS-LCI (PS-LCI를 이용한 혈당 농도에 따른 Stokes 파라미터 측정)

  • 이상원;김법민
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.07a
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    • pp.258-259
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    • 2003
  • 최근 수년간 polarimetry, Raman spectroscopy, near infrared (NIR) absorption spectroscopy, NIR scattering, optoacoustics 등의 방법을 통하여 비침습적으로 Glucose의 농도를 측정하려는 연구가 많이 시도되었다. 일반적으로 이들 방법은 sensitivity 와 signal-to-noise ratio가 매우 낮고 복잡한 알고리즘이 요구되어져 glucose 농도 측정에 한계가 있음이 드러났다. 본 연구에서는 polarization sensitive low coherence interferometer (PS-LCI) 기법을 이용하여 농도에 따른 stokes parameters를 측정함으로써 비침습적으로 glucose를 측정하는 것이 가능한지 알아보는데 그 목적이 있다. (중략)

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Study on Gas Concentration Measurement of O2 and NO Using Calibration-free Wavelength Modulation Spectroscopy in Visible and Mid-Infrared Region (가시광선과 중적외선 영역의 무보정 파장 변조 분광법을 이용한 O2와 NO 가스 농도 측정에 관한 연구)

  • Aran Song;Geunhui Ju;Kanghyun Kim;Jungho Hwang;Daehae Kim;Changyeop Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.70-77
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    • 2023
  • Air environment regulations have been strengthened due to increasing air pollutant emissions, the target of reducing emissions has increased and interest in gas measurement methods is also increasing. The sampling method is mainly used, but due to the spatial and temporal measurement limitations, the laser absorption spectroscopy which is a real-time and in-situ method is in the spotlight. In this study, we studied the wavelength modulation spectroscopy and described the calibration-free algorithm. The developed algorithm was modified to reflect 46 multi-absorption lines and was applied to light absorption signal analysis in visible and mid-infrared regions. In addition, the difference between the modulation parameters of laser was analyzed. As a result of reviewing the performance through O2 and NO gas measurement experiments of various concentration conditions, the linearity was R2O2=0.99999 and R2NO=0.99967.

A Study on Single-Beam Photoacoustic Spectroscopy (Single-Beam을 이용한 광음향 분광법에 관한 연구)

  • 김중환
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1984.12a
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    • pp.33-35
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    • 1984
  • A new type single beam photoacoustic spectrometer suitable for measuring optical absorption of condensed powder matter with the automatic calibration capability of a source power spectrum is introduced. The signal processing until of this spectrometer consists of a photoacoustic cell a lock-in amp., a switching circuit and a personal computer. The measured optical absorption spectra of a few material by this method are good agreement with the results obtained by the double-beam photoacoustic spectrometer.

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