• Title/Summary/Keyword: Absorbent

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Enhancing the Thermotolerance of Entomopathogenic Isaria fumosorosea SFP-198 Conidial Powder by Controlling the Moisture Content Using Drying and Adjuvants

  • Kim, Jae Su;Lee, Se Jin;Lee, Hyang Burm
    • Mycobiology
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    • v.42 no.1
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    • pp.59-65
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    • 2014
  • Entomopathogenic fungi are promising pest-control agents but their industrial applicability is limited by their thermosusceptibility. With an aim to increase the thermotolerance of Isaria fumosorosea SFP-198, moisture absorbents were added to dried conidial powder, and the relationship between its water potential and thermotolerance was investigated. Mycotized rice grains were dried at $10^{\circ}C$, $20^{\circ}C$, $30^{\circ}C$, and $40^{\circ}C$ and the drying effect of each temperature for 24, 48, 96, and 140 hr was determined. Drying for 48 hr at $10^{\circ}C$ and $20^{\circ}C$ reduced the moisture content to < 5% without any significant loss of conidial thermotolerance, but drying at $30^{\circ}C$ and $40^{\circ}C$ reduced both moisture content and conidial thermotolerance. To maintain thermotolerance during storage, moisture absorbents, such as calcium chloride, silica gel, magnesium sulfate, white carbon, and sodium sulfate were individually added to previously dried-conidial powder at 10% (w/w). These mixtures was then stored at room temperature for 30 days and subjected to $50^{\circ}C$ for 2 hr. The white carbon mixture had the highest conidial thermotolerance, followed by silica gel, magnesium sulfate, and then the other absorbents. A significant correlation between the water potential and conidial thermotolerance was observed in all conidia-absorbent mixtures tested in this study (r = -0.945). Conidial thermotolerance in wet conditions was evaluated by adding moisturized white carbon (0~20% $H_2O$) to conidia to mimic wet conditions. Notably, the conidia still maintained their thermotolerance under these conditions. Thus, it is evident that conidial thermotolerance can be maintained by drying mycotized rice grains at low temperatures and adding a moisture absorbent, such as white carbon.

Absorption Characteristics of Aqueous Sodium Glycinate Solution with Carbon Dioxide and Its Mechanistic Analysis (Sodium Glycinate 수용액의 CO$_2$ 흡수특성 및 반응 메커니즘 해석)

  • Shim, Jae-Goo;Kim, Jun-Han;Jang, Kyung-Ryong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.430-438
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    • 2008
  • The experiments for separation and recovery of CO$_2$ were conducted by aqueous sodium glycinate solution, which is one of the amino acid salts, as an absorbent of CO$_2$ in this study. Absorption capacities of aqueous MEA and sodium glycinate solution according to partial pressure of CO$_2$ were evaluated by vapor-liquid equilibrium tests of 20 wt% and 30 wt% above-mentioned absorbents, respectively. In addition, the pilot scale(2 t-CO$_2$/day) experiments based on prior results were carried out. As a result, CO$_2$ removal efficiency of aqueous sodium glycinate solution was lower than that of aqueous MEA solution. This phenomenon means that CO$_2$ removal efficiency of aqueous sodium glycinate solution mainly depends on its molecular structure. Consequently, the first application of certain amino acid salt, as an absorbent of CO$_2$, to pilot plant of 2 t-CO$_2$/day scale was carried out in our country.

A Study on the Separation of $CO_2$from Flue Gas by Chemical Absorption (화학흡수법에 의한 연소폐가스 중 지구온난화 가스 $CO_2$분리에 관한 연구)

  • 안성우;김영국;송호철;박진원
    • Journal of Energy Engineering
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    • v.6 no.2
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    • pp.203-211
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    • 1997
  • This study is on the separation of Global warming effect gas, CO$_2$by chemical absorption from mixture of CO$_2$-N$_2$which was modeled after flue gas of fire power plant. Investigation of optimum condition for absorbent was carried out by using sparged vessel apparatus. Through packed tower experiments, applicabilities of two absorption models were tested by comparing experimental results with theoretical values. Absorbent used in the experiments was Monoethanolamine (MEA) and gas mixture was made in the mole composition of 15% CO$_2$and 85% N$_2$. Through estimations of CO$_2$loading and CO$_2$removal efficiency, optimum concentration of absorbent was found in the range of 4-5 M. To find a rate of absorption, an enhancement factor was introduced. Values of rate of absorption were calculated by Film model and Higbie model, respectively. Higbie model showed good agreement with experimental results. Therefore, this models is considered to be applicable to the CO$_2$separation process for flue gas from fire power plant.

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Removal Efficiency of Some Odorants against Water as Sorptive Media: A Case Study on Trimethylamine and Reduced Sulfur Compounds (물을 흡수매체로 이용한 트리메틸아민과 환원황화합물의 제거효율 비교 연구)

  • Ahn, Ji-Won;Kim, Ki-Hyun;Ok, Joon-Seok;Kim, Yong-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.6
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    • pp.512-522
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    • 2009
  • In this study, the removal efficiency of trimethylamine (TMA) and four reduced sulfur compounds (RSC) of $H_2S$, $CH_3SH$, DMS, and DMDS was investigated using deionized water as absorbent. To this end, two types of experiments were conducted which include: (1) by passing both RSC and TMA standard gases through water contained in an impinger system and (2) by passing TMA gases through a water spray system. In the former method, TMA standard gases were effectively removed (below detection limit) in all experiments. Likewise, minor fractions of some RSC ($CH_3SH$, DMS, and DMDS) were removed by water in line with theoretical expectations. In addition, the first type of our experiment was extended further to test some commercially available odor treatment products. The results of this test showed that removal efficiencies of RSC $(8.2\pm13.7\sim43.7\pm2.48%)$ were different significantly among 4 kinds of absorbent, while the removal of TMA was consistently good as water. In the second phase of experiment, removal efficiency of TMA was tested by passing its standard gas through a water spray system. The overall results of our study showed that the actual removal efficiency of odorants by water (as sorptive media) approached the values that can be predicted theoretically (by Henry's law).

Determination and Calculation of Physical Properties for Sodium Glycinate as a CO2 Absorbent (CO2 제거용 흡착제 Sodium Glycinate의 물성측정과 추산)

  • Park, So-Jin;Jang, Gyeong-Ryong;Park, In Hwan
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.277-283
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    • 2006
  • Aqueous solution of sodium glycinate was checked as a suitable $CO_2$ absorbent from the flu gas in the thermal power plant. For this purpose, solubility, vapor pressure, latent heat of vaporization and thermal conductivity were determined for pure and aqueous solution of sodium glycinate. The solubility of sodium glycinate in the solvent, 25 g of $H_2O$, was increased with increasing the temperature and their relation was represented as a first order equation of y = 0.3471x + 20.993. The vapor pressure for 10 wt% to 60 wt% of aqueous sodium glycinate solution were determined and the latent heat of vaporization of each aqueous solution was calculated from measured vapor pressure using Clausius-Clapeyron equation. Besides, thermal conductivity of sodium glycinate powder was also determined and it was $1.0933kcal/m{\cdot}hr{\cdot}^{\circ}C$.

Absorption Rate of Carbon Dioxide into Blended Ammonia Solution with Amine Additives in a Stirred Cell Reactor (교반셀에서 측정한 아민첨가 암모니아수 흡수제의 이산화탄소 흡수 반응 속도 측정)

  • Park, HoSeok;You, Jong Kyun;Hong, Won Hi;Kim, Jong Nam
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.185-189
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    • 2009
  • Absorption rate of carbon dioxide into aqueous ammonia absorbent(10 wt%) was measured in the temperature range from 293 K to 337 K using a stirred-cell reactor. The reaction rate constant was correlated with the Arrehnius equation and the activation energy was 50.42 kJ/mol. $CO_2$ absorption rate into modified ammonia absorbent was also investigated. For the modified ammonia absorbent, 1 wt% sterically hindered amines of 2-amino-2-methyl-1-propanol(AMP), 2-amino-2-methyl-1,3-propandiol(AMPD) and 2-amino-2-ethyl-1,3-propandiol(AEPD) were used as additives. The $CO_2$ absorption rate increased by adding 1 wt% of the amine additive, in the case of AMP additive, the absorption rate enhanced by about 53%.

Mineralization Environments and Evaluation of Resources Potentials for the Absorbent-functional Mineral Resources Occurred in the Coal-bearing Formation of the Janggi Group (장기층군의 함탄층에서 산출되는 흡착기능성 광물 자원의 부존 환경 및 자원잠재성 평가)

  • Noh, Jin-Hwan
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.3 s.49
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    • pp.197-207
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    • 2006
  • In the coal-bearing formations of the Janggi Group, which are reported as typical clastic sediments, several beds of volcaniclastic rocks are actually found in the Yeongil area. The coal-bearing formations generally exhibit alternating lithologic characteristics of pyroclastic and epiclastic sedimentary facies. Tuff and tuffaceous sandstone rich in pumice fragments are characteristic in the coal-bearing fermations. Diagenetic minerals found in the pyroclastic rocks of the upper and lower coal-bearing formations are montmorillonite, clinoptilolite, opal-CT, and quartz. Several tuffaceous beds correspond to the low-grade ores of zeolites and bentonite, and moreover, these ores mostly occur as thin beds less than 1 m in thickness. Thus, the potential of altered tuffaceous rocks as the resources typical of zeolite and bentonite seems to be low. However, based on mineral composition and CEC determinations, it can be evaluated that these tuffaceous rocks mostly have the promising potential for utilization as the absorbent-functional mineral resources such as acid clays, if these low-grade ores plus adjacent tuffaceous rocks are collectively exploited.

$CO_2$ Capture Process using Aqueous Monoethanolamine (MEA): Reduction of Solvent Regeneration Energy by Flue gas Splitting (모노에탄올아민(MEA)을 이용한 이산화탄소 포집공정: 배가스 분할 유입을 통한 흡수제 재생 에너지 절감 연구)

  • Jung, Jaeheum;Lim, Youngsub;Jeong, Yeong Su;Lee, Ung;Yang, Seeyub;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.764-768
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    • 2011
  • The process of $CO_2$ capture using aqueous Monoethanolamine(MEA) has been considered as one of the leading technologies for intermediate-term strategy to reduce the $CO_2$ emission. This MEA process, however, consumes relatively a large amount of energy in the stripper for absorbent regeneration. For this reason, various process alternatives are recently established to reduce the regeneration energy. This paper suggests a flue gas split configuration as one of MEA process alternatives and then simulates this process using commercial simulator. This flue gas splitting has an effect on reducing the temperature of the lower section of absorber as well as decreasing the absorbent flow rate. Compared to the base model, this optimized flue gas split process provides 6.4% reduction of solvent flow rate and 5.8% reduction of absorbent regeneration energy.