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Study on NbTi superconducting joint process for high field MRI magnet (고자장 MRI 마그네트를 위한 NbTi 초전도 접합 공정 연구)

  • 하동우;오상수;하홍수;이남진;고락길;권영길;류강식
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.165-167
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    • 2002
  • NbTi/Cu superconducting wires were jointed inserting the NbTi filaments into Cu/NbTi sleeve and pressing it. When the NbTi filaments were inserted into Cu/NbTi sleeve, additional NbTi filaments were inserted together to increase the numbers of filaments in the hole of sleeve. Critical current of the joint of 28 filaments wires with 1.7 mm thickness of dimple was 450 A at 4.2K, 0.5T. Ic of the joint of 54 filaments wires with 2.0 mm thickness of dimple was 600 A at 4.2K, 2T. It is possible to manufacture MRI magnet by using these results.

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Preparation and Characterization of Fine $TiO_2$ Powders by Vapor-Phase Hydrolysis of TiCl4 (사염화티타늄의 기상가수분해반응에 의한 $TiO_2$ 미분의 제조 및 입자특성)

  • 염선민;김광호;신동원;박찬경
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.525-532
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    • 1992
  • TiO2 fine powder was synthesized in the gas phase by chemical vapor deposition using hydrolysis of TiCl4. Content of rutile phase in the powder was investigated. Powder characteristics such as size, crystallinity and morphology were also studied by means of TEM, SEM and XRD. Rutile phase in TiO2 powder started to be formed from 100$0^{\circ}C$ and the content increased with the reaction temperature and TiCl4 concentration. As the temperature increased from 80$0^{\circ}C$ to 140$0^{\circ}C$, the primary particle size increased while secondary particle size decreased. Spherical secondary particle with fine primary crystals agglomerated was produced at low temperature of 80$0^{\circ}C$ whereas the grown primary particle being final particle size was produced at higher temperature of 140$0^{\circ}C$. Other effects of TiCl4 and H2O partial pressures on particle size were also reported in this study.

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Tissue Distribution of $TiO_2$ Nanoparticles in Mice after Oral Administration, and Skin Treatment (마우스 경구 및 경피투여에 의한 $TiO_2$ 나노입자의 체내분포)

  • Park, Eun-Jung;Park, Kwang-Sik
    • Environmental Analysis Health and Toxicology
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    • v.23 no.1
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    • pp.63-65
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    • 2008
  • The tissue distribution of $TiO_2$, nanopaprticles was investigated in mice after oral administration, and skin treatment. Male mice were treated with the dose of 5 g/kg of $TiO_2$ for three consecutive days and sacrificed at 24 hours after the last administration. As results, the orally administered $TiO_2$ nanoparticels were shown to be distributed in the testis, lung, and brain at 24 hours after the last treatment. Kidney does not seem to be the main target of $TiO_2$ nanoparticle distribution. It means that $TiO_2$ nanoparticles (17 nm) are easily absorbed through entero-gastric system and may cause toxicity in brain, lung, and reproductive organs. The distribution of skin treatment showed the same pattern like oral administration.

Effect of $BF_2$ Dopant on the Formation of Ti-Polycide ($BF_2$ Dopant가 Titanium Polycide 형성에 미치는 영향)

  • 최진성;백수현
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.28A no.11
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    • pp.887-893
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    • 1991
  • To take advantage of Ti-polycide, when it is contacted with both n+ and p+ active area of silicon, the effects of BF$_2$ on the formation of Ti-silicide were investigated with RTA temperature and dopant concentration. The intermediate phase C49 TiSi$_2$ appeared at $650^{\circ}C$ and the stable phase C54 TiSi2 was formed at $700^{\circ}C$. And the formation of Ti-silicide was hindered by BF$_2$ doping and this trend was decreased with increasing temperature. The out-diffusion phenomena of BF$_2$ into Ti silicide were not observed. And significantly, the native oxide was a chief factor preventing the formation of Ti-silicides.

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The study on the formation of titanic acid by dehydration of TiCl₄ (TiCl₄가수분해에 의한 titanic acid의 생성에 관한 연구)

  • Kim, Heon;Kim, Dae Ung;Lee, Gyeong Hui;Baek, Un Pil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.342-342
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    • 1998
  • The effect of pH on the dehydration reaction of TiCl₄solution. KOH and HCl were used as a accelerater and retarder in dehydration. Results are follow. Neutralization point is pH 7.4 in the system of $TiCl_4-KOH$ and the production which is produced at acidic side is Ti-gel of poly metatitanic acid. The production which is produced at alkalic side is aligomer and crystalline potasium titanate is not detected.

Low Temperature Deposition of TiN on the Steel Substrate by Plasma-Assisted CVD (플라즈마 화학증착에 의한 강재위에 TiN의 저온증착)

  • 이정래;김광호;조성재
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.148-156
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    • 1993
  • TiN films were deposited onto high speed steel (SKH9) by plasma assisted chemical vapor deposition (PACVD) using a TiCl4/N2/H2/Ar gas mixture at around 50$0^{\circ}C$. The effects of the deposition temperature, R.F. power and TiCl4 concentration on the deposition of TiN and the microhardness of TiN film were investigated. The crystallinity and the microhardness of TiN films were improved with increase of the deposition temperature. Optimum deposition temperature in this study was 50$0^{\circ}C$, because a softening or phase transformation of the substrate occurred over 50$0^{\circ}C$. A large increase of the film growth rate with a strong(200) preferred orientation was obtained by increasing R.F. power. Much chlorine content of about 10at.% was found in the deposited films and resulted in relatively low average microhardness of about 1, 500Kgf/$\textrm{mm}^2$ compared with the theoretical value(~2, 000Kgf/$\textrm{mm}^2$).

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Influence of $TiO_2$ on Sintering and Microstructure of Magnesia (마그네시아의 소결과 미세구조에 미치는 $TiO_2$의 영향)

  • 이윤복;박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.471-476
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    • 1994
  • The influence of TiO2 addition on the sintering and microstructure of magnesia ceramics was studied. An excess amount of TiO2 over the solid solubility limit reacted with magnesia to form Mg2TiO4 compound above 130$0^{\circ}C$. The deviation of lattice parameter of MgO was estimated to be under 0.2% when existence of TiO2 in MgO. The addition of TiO2 markedly promoted the densification of MgO at comparatively low temperature and the sintered density of about 98% of the theorectical was obtained at 150$0^{\circ}C$, 2h. The densification was mainly governed by grain growth of MgO and the effect of Mg2TiO4 existing as a second phase on depression of grain growth of MgO was not exhibited.

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A Study on Pitting Resistance of TiN Film Coated on Inconel 600 by CPP Test in High Temperature NaCl Solution (nconel 600위에 증착된 TiN 박막의 고온 NaCl 수용액에서의 CPP 실험에 의한 핏팅저항성의 연구)

  • 김용일;정한섭;김홍회;이원종
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1301-1307
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    • 1995
  • Pitting corrosion of TiN film deposited on Inconel 600 by plasma assisted chemical vapor deposition (PACVD) was investigated. Cyclic potentiodynamic polarization (CPP) tests were conducted in order to determine the pit nucleation potentials, Enp, of the TiN-deposited sample and the bare Inconel 600 in deaerated NaCl solution at 25, 135 and 20$0^{\circ}C$. The effects of the TiN film thickness, the solution temperature and the Cl- concentration on Enp were studied. Enp of the TiN-deposited sample which had the film thickness above 1${\mu}{\textrm}{m}$ were higher than those of the bare Inconel 600 by 300~600mV at all the solution temperatures, implying the pitting resistance improvement of the TiN film. The morphologies of the pits generated after immersion test were examined with a scaning electron microscopy. The higher was the solution temperature, the more corrosion products, mainly composed of Cr and Ni oxides, were formed.

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Crystallization Kinetics of $PbO-TiO_2-SiO_2-B_2O_3$ Glasses by DSC (DSC에 의한 $PbO-TiO_2-SiO_2-B_2O_3$계 유리의 결정화 속도)

  • 손명모;이승호;이헌수;박희찬
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1331-1336
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    • 1995
  • The glass-ceramics for ferro-electric were made from compositions of 70PbO.16TiO2.8SiO2.4B2O3.2AlPO4 (wt%) and 67.5PbO.20TiO2.8.5SiO2.2B2O3.2AlPO4 (wt%). The crystallization kinetics for PbTiO3 crystalline phase formation from glass was studied using non-isothermal DSC techniques. The values of activation energy, ΔE using variables of heating rate and temperature were calculated at various reaction fractions obtained from peak area over DSC. The results indicated that activation energy was lowest at 60% reaction fractions and the activation energy of glass containing 20.0 wt% TiO2 is higher than that of glass containing 16.0 wt% TiO2. The crystallization mechanism was three dimensional growth (n=4).

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Magnetic and Microwave Absorbing Properties of Ti-and Co-Substituted Barium Ferrite (BaFe12-2X TiXCoXO19)

  • Han-Shin Cho;Yong-Jin Kim;Sung-Soo Kim
    • Journal of Magnetics
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    • v.4 no.2
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    • pp.65-68
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    • 1999
  • The M-type barium ferrite ($BaFe_{12}O_{19}$) is well known magnetic material to be used as a permanent magnet due to its strong uniaxial anisotropy. The substitution of nonmagnetic $Ti^{+4}$ and magnetically weak $Co+^2ion for Fe^{+3}$ to its strong uniaxial anisotropy. The substitution of nonmagnetic $Ti^{+4}$ and magnetically weak $Co+^2ion for Fe^{+3}$ sublattices reduces the uniaxial anisotropy and those compounds open a new application field of noise suppressor at high frequencies. In this study, the magnetic and microwave absorbing properties are investigated in Ti-and Co-substituted barium ferrites ($BaFe_{12-2X} Ti_XCo_XO_{19}$). The saturated magnetization decreases linearly with the substitution of Ti and Co. The rapid drop in coercive force is observed with Ti and Co substitution upto x=1.2. The magnetic permeability spectrum shows the natural magnetic resonance in the specimens with small coercive force and large attenuation of microwave is predicted in those specimens at high frequencies (above 4 GHz).

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