• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.765-768
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• 2008

The prevent methods of Alkali-Silica Reaction (ASR) are studying after the failure cases by ASR were reported in Korea. When ASR failure is causing to the step of maintenance, the available repair methods were rarely studied in the World. In this study, premixed fly ash cement was applied to prevent ASR in the concrete pavement. The ratio of fly ash and cement is 20 percent and 80 percent by weight of total cementious material. The construction performance of premixed fly ash cementious concrete pavement was studied that the application is verify to performance collected data during the constructing in the field. The freeze-thaw test was studied to verify durability of the premixed fly ash cementious material made specimen in the laboratory. The results show that construction performance and durability are well condition in this test section and freeze-thaw test.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.701-704
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• 2008

The case of failure of Alkali-silica reaction (ASR) on the cement concrete pavement was reported in Korea. In the United States America, the fly ash has less than 10 percent Cao reported that prevent expansion by ASR. Most of all fly ash in Korea have less than 10 percent CaO, therefore it is similar ASTM F fly ash in the USA. Crushed aggregates of the test section had expansion behavior by potential ASR that the ASTM C 1260 test method tested expansion 0.17 percent during 14 days. The test section of concrete pavement used crushed aggregate was constructed that fly ash have 20 percent weight of cementitious materials to prevent expansion by ASR. This study was performed flexural strength test for elapsed days and durability by freeze-thaw test. It was shown that flexural strength was increased elapsed days and good performed freeze-thaw test. This study shown that fly ash concrete pavement was good performance in the test section.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.903-908
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• 2002

The production of waste glasses has been increased with the development of industry. The utilization of waste glass for concrete can cause the concrete to be cracked and to be weakened due to an expansion by alkali-silica reaction(ASR). When used the fibers with waste glass, there is an effect on reduction of expansion and strength loss due to ASR between the alkali in the cement paste and the silica in the waste glass. In this study, we conducted basic experimental research to analyze the possibilities of recycling of amber waste glass as fine aggregates for steel fiber reinforced concrete. Test results of fresh concrete. slump is decreased because grain shape is angular and air content is increased due to involving small size particles so much in waste glasses. Also. tensile and flexural strengths increased as the content of steel fibers increased. In conclusion, the content of waste glass below 40% is reasonable and usage of pertinent admixture is necessary to obtain workability or air content.

• Economic and Environmental Geology
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• v.28 no.5
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• pp.519-525
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• 1995

Recently, there have been several cases of serious accidents on concrete structure resulting from rapid deterioration of concrete strength. On the view point of long term stability of concrete, deterioration of concrete strength is mostly due to chemical reaction between alkali and reactive aggregates (alkali-aggreagte reaction; AAR) in concrete rather than a problem of execution. For long-term stability of concrete, concrete aggregates must be carefully selected. Some of rocks used for concrete aggregates contain deleterious minerals reactive to alkali components in concrete. Most of AAR result from chemical reaction between alkali components and reactive silica minerals in aggregates (so called alkali-silica reaction; ASR). The silica minerals are as follows; quartz with seriously distorted lattice structure, volcanic glass, chalcedony, opal, cristobalite, tridymite, etc. ASR may cause expansion and cracks, further collapse in concrete structure, in a few years. In case of crushed aggregates, only a part of rock mass without reactive minerals must be produced in aggregates mine after thorough examination of the distribution of rocks with reactive minerals. In case of natural aggregates, the total content of reactive minerals must be calculated, if, the content is more than 20%, the rate should be lower by mixing other non-reactive crushed- or natural aggregates. If it is obliged to use concrete aggregates all containing deleterious minerals in a discrete area, they must be used with low alkali cement Even if it is low quality in the chemical properties, aggregates with suitable range in the physical properties can be utilized as the aggregate of other purposes.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.04a
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• pp.169-173
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• 1994

Recently, the use of crushed stones is increased due to the shortage of natural aggregates. In the previous papers of part 1 and 2, we got the conclusions that some of crushed stones have the characteristic of alkali-silica reaction(ASR). And these reactions are influenced by the amount and type of alkali in cement. The purpose of this paper is how to prepare for the prevention against alkali-silica reaction. As a solution of problems, we have conducted the experiments of two methods. One was the replacement of innocuous aggregates instead of reactive aggregates, the other was the addition of various pozzolanic materials. As a result, we found that the expansion by alkali-silica reaction in mortar bar could be effectively decredsed by upper methods.

• Computers and Concrete
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• v.13 no.6
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• pp.739-748
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• 2014

In this article, by using experimental studies and artificial neural network has been tried to investigate the use of nano-silica as concrete admixture to reduce alkali-silica reaction. If there are reactive aggregates and alkali of cement with enough moisture in concrete, a gel will be formed. Then with high reactivity between alkali of cement and existence of silica in aggregates, this gel will expand by absorption of water, and causes expansive pressure and cracks be formed. At the time passes, this gel will reduce both durability and strength of the concrete. By reducing the size of silicate to nano, specific surface area of particles and number of atoms on the surface will be increased, which causes more pozzolanic activity of them. Nano-silica can react with calcium hydroxide ($Ca(OH)_2$) and produces C-S-H gel. In this study, accelerated mortar bar specimens according to ASTM C 1260 and ASTM C 1567, with different mix proportions were prepared using aggregates of Kerman, such as: none admixture and plasticizer, different proportions of nano-silica separately. By opening the moulds after 24 hour and curing in water at $80^{\circ}C$ for 24 hour, then curing in (1N NaOH) at $80^{\circ}C$ for 14 days, length expansion of mortar bars were measured and compared. It was noted that, the lowest length expansion of a specimens shows the best proportion of admixture based on alkali-silica reactivity. Then, prediction of alkali-silica reaction of concrete has been investigated by using artificial neural network. In this study the backpropagation network has been used and compared with different algorithms to train network. Finally, the best amount of nano silica for adding to mix proportion, also the best algorithm and number of neurons in hidden layer of artificial neural network have been offered.

• New & Renewable Energy
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• v.5 no.2
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• pp.9-14
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• 2009

Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

• Journal of the Korea Concrete Institute
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• v.21 no.4
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• pp.531-537
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• 2009

In this study alkali reactivity of crushed stone was conducted according to the ASTM C 227 that is traditional mortar bar test, and C 1260 that is accelerated mortar bar test method. The morphology and chemical composition of products formed in mortar bar, 3 years after the mortar bar tests had been performed, were examined using scanning electron microscopy (SEM) with secondary electron imaging (SEI) and electron probe microanalysis (EPMA) with backscattered electron imaging (BSEI). The crushed stone used in this study was not identified as being reactive by ASTM C 227. However, mortar bars exceeded the limit for deleterious expansion in accelerated mortar bar test used KOH solution. The result of SEM (SEI) analysis, after the ASTM C 227 mortar bar test, confirmed that there were no reactive products and evidence of reaction between aggregate particles and cement paste. However, mortar bars exposed to alkali solution (KOH) indicated that crystallized products having rosette morphology were observed in the interior wall of pores. EPMA results of mortar bar by ASTM C 227 indicated that white dots were observed on the surface of particles and these products were identified as Al-ASR gels. It can be considered that the mortar bar by ASTM C 227 started to appear sign of alkali-silica reaction in normal condition. EPMA results of the mortar bar by ASTM C 1260 showed the gel accumulated in the pores and diffused in to the cement matrix through cracks, and gel in the pores were found to be richer in calcium compared to gel in cracks within aggregate particles. In this experimental study, damages to mortar bars due to alkali-silica reaction (ASR) were observed. Due to the increasing needs of crushed stones, it is considered that specifications and guidelines to prevent ASR in new concrete should be developed.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.9-14
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• 2022

Most of the existing research on ferronickel slag has focused on its potential as aggregate and fine aggregate, this study was conducted focusing on the potential of ferronickel slag powder as a concrete admixture. For concrete, which fly ash, blast furnace slag, and FSP were mixed with each 10 % type the reactivity was evaluated by applying ASTM C 1260 of the United States. As a result, compared with the control group, the expansion rate of fly ash decreased by 8.43 % and that of fine blast furnace slag powder decreased by 14.46 %, while the expansion rate of ferronickel slag decreased by 49.40 %. it was confirmed that ferronickel slag can sufficiently be replaced existing supplementary cementitious admixtures such as fly ash and blast furnace slag in terms of suppressing the reactivity of aggregates. However as a result of SEM analysis, ettringites were generated, and additional research about how it affects concrete is needed.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.261-262
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• 2009

The prevent methods of Alkali-Silica Reaction (ASR) are studying after the failure cases by ASR were reported in Korea. In this study, the freeze-thaw test and scaling test for premixed fly ash cement were performed. The ratio of fly ash and cement is 20 percent and 80 percent by weight of total cementious material. The results show that the dynamic modulus after 300 cycles the freeze-thaw test for most of specimen except the specimen have less 3% air was more than 90 % and the loss of weigh the specimen after 50 cycles scaling test was less than 1kg/$m^3$.