• Applied Chemistry for Engineering
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• v.29 no.2
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• pp.209-214
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• 2018

In this paper, the techno-economic analysis of glycerol steam reforming for $H_2$ production capacity of $300m^3\;h^{-1}$ was carried out. The process of glycerol steam reforming was constructed by using Aspen $HYSYS^{(R)}$, a commercial process simulator, and parametric studies for the effect of the operating temperature on $H_2$ production was performed. Moreover, the economic analysis was conducted through an itemized cost estimation, sensitivity analysis (SA) and cash flow diagram (CFD), and the unit $H_2$ production cost was 5.10 $ ${kgH_2}^{-1}$ through the itemized cost estimation of glycerol steam reforming for $H_2$ production capacity of $300m^3\;h^{-1}$. SA was employed to identify key economic factors and various economic indicators such as net present value (NPV), discounted payback period (DPBP), and present value ratio (PVR) were found according to $H_2$ selling price using CFD.

• Journal of Energy Engineering
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• v.5 no.1
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• pp.34-41
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• 1996

The heat of evaporation (cold energy) of LNG is the energy consumed in the production of LNG. This energy amounts to 14% of the NG. In Pyungtak LNG terminal, it is about 96 MW in 1993. In order to utilize the cold energy, the cold power generation systems are investigated: The Rankine cycle using the low temperature energy, the partial expansion cycle using the pressure energy, and the Linde process which is a combined cycle of the Rankine and the partial direct expansion cycle. The commercial simulator, ASPEN Plus, is used. The conceptual design data are obtained from the current facilities of the Pyungtak LNG terminal. The performances of three systems are evaluated. The amount of electric power ranges iron 3 MW to 6MW. The optimum energy efficiency is about 37%. The optimum design conditions are obtained for the partial direct expansion (PDE) cycle. The performance of the PDE cycle is supposed to be comparable to that of the Rankine cycle if the areas of the total heat exchanger of the both cycle are equal.

• Journal of Energy Engineering
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• v.5 no.1
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• pp.8-18
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• 1996

As a part of comprehensive IGCC process simulation, the thermal performance analysis was performed for coal gas firing combined power plant. The combined cycle analyzed consisted of il Texaco gasifier and a low temperature gas cleanup system for the gasification block and a GE 7FA gas turbine, a HRSG and steam turbine for the power block. A steady state simulator called ASPEN(Advanced System for Process Engineering) code was used to simulate IGCC processes. Composed IGCC configuration included air integration between ASU and gas turbine and steam integration between gasifier, gas clean up and steam turbine. The results showed 20% increase in terms of gas turbine power output(MWe) comparing with natural gas case based on same heat input. The results were compared with other study results which Bechtel Canada Inc. performed for Nova Scotia power plant in 1991 and the consistency was identified within two studies. As a result, the analysing method used in this study is verified as a sound tool for commercial IGCC process evaluation.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.677-684
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• 2013

A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane ($C_1$), ethane ($C_2$), propane ($C_3$) and nitrogen ($N_2$) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.47 no.4
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• pp.305-310
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• 2002

The performance of 7 sugary (su) and 12 shrunken-2 (sh2) sweet com hybrids which are commercially grown in the United States was tested in Korea. The 100-seed weight of su hybrids (16.5-23.6 g) was much heavier compared to that of sh2 hybrids (10.9-17.5 g). The germination rate of su and sh2 hybrids at $25^{\circ}C$ ranged 93.3-100% and 86.7-98.9%, the emergence rate of su and sh2 hybrids in cold test ranged 78.9-97.8% and 62.2-97.8%, and field emergence rate of su and sh2 hybrids ranged 74.4-100.0% and 79.9-98.2%, respectively. In su hybrids, there was a significantly positive correlation between germination rate at $25^{\circ}C$ and emergence rate in cold test or early growth. In contrast, in sh2 hybrids seed weight was positively correlated with early plant growth, while not with the germination rate at $25^{\circ}C$ or emergence rate in cold test and field. Most sh2 hybrids produced larger and more marketable ears compared to su hybrids although there were significant differences among the hybrids in the same genotype. At harvest (24 days after pollination) soluble solids content of su hybrids (24.3-27.1 Brix %) was much higher than that of sh2 hybrids (13.8-18.0 Brix %), while total sugars of sh2 hybrids (21.4-28.6% on the dry weight basis) was much higher compared to su hybrids (2.4-15.9%). Considering germination and emergence rates, marketable ear production, and total sugar content, 'GCB 70' and 'Sweet Satin' in su hybrids and 'Ice Queen', 'Aspen', 'Sweet Magic', 'Bandit', 'Xtrasweet 82', 'Aspen', and 'Cambella 90' in sh2 hybrids performed better than other hybrids.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.128-134
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• 2012

The pilot scale experiments can handle the flue gas up to 1,000 $Nm^3/hr$ for separation of carbon dioxide included in real flue gas at coal-fired power plant. The operational characteristics was analyzed with the main experimental variables such as flue gas flow rate, absorbent circulation rate using chemical absorbents mono-ethanolamine( MEA) and 2-amino-2-methyl-1-propanol(AMP). The more flue gas flow rate decreased in 100 $m^3/hr$ in the MEA 20 wt% experiments, the more carbon dioxide removal efficiency was increased 6.7% on average. Carbon dioxide removal efficiency was increased approximately 2.8% according to raise of the 1,000 kg/hr absorbent circulation rate. It also was more than 90% at $110^{\circ}C$ of re-boiler temperature. Carbon dioxide removal efficiency of the MEA was higher than that of the AMP. In the MEA(20 wt%) experiment, carbon dioxide removal efficiency(85.5%) was 10% higher than result(75.5%) of ASPEN plus simulation.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.69-83
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• 2020

Light olefins are important petrochemicals as well as primary building blocks for various chemical intermediates. As the number of ethane cracking center (ECC) process, in which ethylene accounts for most of the production, has increased in recent years, propylene supply is not catching up with steadily increasing propylene demand. This trend makes the conversion of methanol to olefins to get more industrial importance. The methanol to olefins (MTO) process produces methanol through syngas and obtain olefins such as propylene through methanol. Since the reaction from methanol to olefins provides different product compositions depending on the catalyst used for the reaction, it is important to choose an appropriate separation process for the reaction product with different composition. Four different separation processes are considered for four representative cases of product compositions. The separation processes for the reaction products are evaluated by techno-economic analysis based on the simulation results using Aspen plus. Guidelines are provided for selecting a suitable separation process for each of representative case of product compositions in the MTO process.

• Korean Chemical Engineering Research
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• v.52 no.1
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• pp.98-105
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• 2014

Lysozyme amounts to 0.3% in egg white and functions as an agent of cell lysis and activator of tissue reconstruction. Ion exchange chromatography is the most useful method of separation among affinity chromatography, ion exchange chromatography, and ultra-filtration. The aim of present study is to find the optimum pH and temperature for the separation of lysozyme in egg white within cation exchange gel filled glass column. And we compared results of experiments with those of simulations. Phosphate buffer was used, and pH and temperature were varied as 5~7 and $25{\sim}40^{\circ}C$ respectively. RP-HPLC was the tool for the retention time identification and quantitative analysis of lysozyme. OriginPro 8 measured the peak area of lysozyme chromatogram and quantified the eluted lysozyme. Largest amount of lysozyme was separated under the conditions of pH 5 and T $25^{\circ}C$.

• Clean Technology
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• v.17 no.4
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• pp.329-335
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• 2011

$SF_6$ gas is well known as a global warming gas. Global warming potential of $SF_6$ gas is 22,000 times higher than that of $CO_2$. Recycling of $SF_6$ gas is an essential technology for the sake of the environment and the economy. The recovery processes of $SF_6$ gas studied in this work were liquefaction, distillation, and crystallization processes because these processes were thought to be easily carried to the fields for recycling waste $SF_6$ gas. The processes were simulated and optimized using Aspen plus. The optimization problems were formulated to minimize energy consumption with satisfying product specification and desired recovery. The performance of the processes was compared based on the optimization results. Effects of major process variables on the recovery performance were investigated and optimal operation guide for changing product specification and product recovery was provided.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.903-914
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• 2008

This study was undertaken for the production capacity expansion and energy saving through entire process simulation and optimization for the commercial process of manufacturing monoethylene glycol as a staple from ethylene oxide. Aspen $Plus^{TM}$(ver. 2006) was employed in the simulation and optimization work. The multicomponent vapor-liquid equilibria involved in the process were calculated using the NRTL-RK equation. As for the binary interaction parameters required for a total of 91 binary systems, those for 8 systems were self-supplied by the simulator, those for 28 systems were estimated through regression of the VLE data in the literature, and the remainder were estimated with the estimation system built in the simulator. Subsequent to ascertaining the accuracy of the generated parameters through comparison between actual and simulated process data, sensitive variables highly affecting the process were searched and selected using sensitivity analysis tool in the simulator. The optimum operating conditions minimizing the total heat duty of the process were investigated using the optimization tool based on the successive quadratic programming in the simulator.