• Title/Summary/Keyword: AM materials

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Electrical Properties of a-IGZO Thin Films for Transparent TFTs

  • Bang, J.H.;Song, P.K.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.99-99
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    • 2010
  • Recently, amorphous transparent oxide semiconductors (TOS) have been widely studied for many optoelectronic devices such as AM-OLED (active-matrix organic light emitting diodes). The TOS TFTs using a-IGZO channel layers exhibit a high electron mobility, a smooth surface, a uniform deposition at a large area, a high optical transparency, a low-temperature fabrication. In spite of many advantages of the sputtering process such as better step coverage, good uniformity over large area, small shadow effect and good adhesion, there are not enough researches about characteristics of a-IGZO thin films. In this study, therefore, we focused on the electrical properties of a-IGZO thin films as a channel layer of TFTs. TFTs with the a-IGZO channel layers and Y2O3 gate insulators were fabricated. Source and drain layers were deposited using ITO target. TFTs were deposited on unheated non-alkali glass substrates ($5cm{\times}5cm$) with a sintered ceramic IGZO disc (3 inch $\varnothing$, 5mm t), Y2O3 disc (3 inch $\varnothing$, 5mm t) and ITO disc (3 inch $\varnothing$, 5mm t) as a target by magnetron sputtering method. The O2 gas was used as the reactive gas. Deposition was carried out under various sputtering conditions to investigate the effect of sputtering process on the characteristics of a-IGZO thin films. Correlation between sputtering factors and electronic properties of the film will be discussed in detail.

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High-Efficiency Dye-Sensitized Solar Cells by Extended Spectral Response Utilizing Dye Selective Positioning Method

  • Lee, Do-Gwon;Park, Se-Ung
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.12.1-12.1
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    • 2010
  • We have developed a facile method to position different dyes (N719 and N749) sequentially in a mesoporous TiO2 layer through selective desorption and adsorption processes. Only upper part of the first adsorbed N719 dye was selectively removed by the desorption solution formulated with polypropylene glycol and tetrabutylammonium hydroxide without any damages of the dye. The desorption depth was controlled by the number of desorption process. Multi-dyed dye-sensitized solar cells (MDSSC) were fabricated by utilizing the method and their photovoltaic properties were investigated. From the incident photon-to-current conversion efficiency (IPCE) measurement, it was found that the MDSSC exhibited the extended spectral response for the solar spectrum while without decrease of maximum IPCE value compare to the DSSCs using one kind of dye (N719 or N749). The highest photocurrent density of 19.3 mA/cm2 was obtained from the MDSSC utilizing $15\;{\mu}m$ N719 / $14\;{\mu}m$ N749 bi-layered mesoporous TiO2 film. The photocurrent density was 25% and 8% higher than that of the DSSC using only N719 and N749 dye as a sensitizer, respectively. The power conversion efficiency of 9.8% was achieved from the MDSSC under the AM 1.5G one sun illumination.

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Enhanced Essential Oil Formation by Two-phase Culture of Mentha piperita Cells in Shake Flask and Air-lift Bioreactors

  • Kim, Teresa;Kim, Tae-Yong;Bae, Geun-Won;Chae, Young-Am;Lee, Hyong-Joo;Chung, In-Sik
    • Journal of Microbiology and Biotechnology
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    • v.5 no.6
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    • pp.364-369
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    • 1995
  • Effect of two-phase culture on Mentha piperita cell growth and essential oil formation was investigated using shake flask and air-lift bioreactors. LiChroprep RP-B(RP-B) addition did not impair M. piperita cell growth, but resulted in stimulated formation of essential oils and increased ratios of extracellular oil to intracellular oil formation. However, the combined use of RP-B and chitosan elicitor was not synergistic. Volumetric productivity of essential oils in RP-B treated culture using cell-recycled air-lift bioreactor was $6.9\;\mu\textrm{g}/l{\cdot}day$ which was substantially higher than that obtainable from the control. Our results demonstrate the potential of a second phase to enhance overall productivity for M. piperita cell culture.

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Improved Optimization of Indirubin Production from Bioreactor Culture of Polygonum tinctorium

  • Chung, Choong Sik;Kim, Kyung Il;Bae, Geun Won;Lee, Youn Hyung;Lee, Hyong Joo;Chae, Young Am;Chung, In Sik
    • Journal of Applied Biological Chemistry
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    • v.43 no.2
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    • pp.109-111
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    • 2000
  • Effect of the two-stage operation and cell concentration on indirubin production was investigated using bioreactor culture of Polygonum tinctorium. Two-stage culture was operated successfully for 110 days without any adverse effects on continuous indirubin production. Maximum indirubin concentration was found to be at 80 mg/bioreactor. Initial cell concentration significantly affected indirubin production. The indirubin production at 29.2% PCV was improved by 845%, compared to that at 5% PCV. For high-density bioreactor culture of P. tinctorium, a maximum production rate of 10.2 mg indirubin/L day was obtained. Indirubin recovery for bioreactor operation was also examined using XAD-2, XAD-4, XAD-7, and solid silicon. XAD-4 was 1.6-fold more effective than that for solid silicon in indirubin recovery.

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Relationship between Compressive Strength of Geo-polymers and Pre-curing Conditions

  • Kim, Hyunjung;Kim, Yooteak
    • Applied Microscopy
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    • v.43 no.4
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    • pp.155-163
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    • 2013
  • Meta-kaolin (MK) and blast furnace slag (BS) were used as raw materials with NaOH and sodium silicate as alkali activators for making geo-polymers. The compressive strength with respect to the various pre-curing conditions was investigated. In order to improve the recycling rate of BS while still obtaining high compressive strength of the geo-polymers, it was necessary to provide additional CaO to the MK by adding BS. The specimens containing greater amounts of BS can be applied to fields that require high initial compressive strength. Alkali activator(s) are inevitably required to make geo-polymers useful. High temperature pre-curing plays an important role in improving compressive strength in geo-polymers at the early stage of curing. On the other hand, long-term curing produced little to no positive effects and may have even worsened the compressive strength of the geo-polymers because of micro-structural defects through volume expansion by high temperature pre-curing. Therefore, a pre-curing process at a medium range temperature of $50^{\circ}C$ is recommended because a continuous increase in compressive strength during the entire curing period as well as good compressive strength at the early stages can be obtained.

The Synthesis and Evaluation of Pendant Oligosaccharide-Lipid Side Chain Copolymer

  • Nam, Hye-Sung;Kim, Hyun-Joo;Nam, Kwang-Woo;Chung, Dong-June
    • Macromolecular Research
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    • v.11 no.2
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    • pp.115-121
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    • 2003
  • In this research, the in vitro anti-thrombogenecity of artificial materials was evaluated using hydrophilic/hydrophobic copolymers containing oiligosaccharide as hydrophilic moiety and phospholipid as hydrophobic moiety respectively. N-(p-vinylbenzyl)-[O-$\alpha$-D-glucopyranosyl-(1longrightarrow4)]$_{n-1}$-D-glucoamide(VM7A) was (VM7 A) was adopted as hydrophilic oligosaccharide and 2-acryloxybutyl-2-(triethylammonium)ethyl phosphoric acid (HBA-choline) was adopted as hydrophobic phospholipid. Copolymers having various monomer feeding molar ratios were synthesized through radical polymerization. The synthesized copolymers were identified using FT-IR, $^1$H-NMR, XPS, and DSC. The surface energy of the copolymers were evaluated by dynamic contact angle (DCA) method and checked different roles of VM7A as hydrophilic moiety and HBA-choline as hydrophobic moiety on surface. The surface morphological differences between hydrated and unhydrated surfaces of copolymers were observed and evaluated using Am. The platelets were separated from canine whole blood by centrifugation and adopted to the anti-thromobogenecity test of the copolymers. From the results, we find out that as VM7A ratio increases, so did anti-thrombogenecity. Such results show the possibility of using these copolymers as blood compatible materials in living body.y.

Polymer semiconductor based transistors for flexible display

  • Lee, Ji-Yeol;Lee, Bang-Rin;Kim, Ju-Yeong;Jeong, Ji-Yeong;Park, Jeong-Il;Jeong, Jong-Won;Gu, Bon-Won;Jin, Yong-Wan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.59.1-59.1
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    • 2012
  • Organic thin-film transistors (OTFTs) with printable semiconductors are promising candidate devices for flexible active-matrix (AM) display applications. Yet, stable operation of actual display panels driven by OTFTs has seldom been reported up to date. Here, we demonstrate a flexible reflective type polymer dispersed liquid crystal (PDLC) display, in which inkjet-printed OTFT arrays are used as driving elements with excellent areal uniformity in terms of device performance. As the active semiconductor, a novel, ambient processable conjugated copolymer was synthesized. The stability of the devices with respect to electrical bias stress was improved by applying a channel-passivation layer, which suppresses the environmental effects and hence reduces the density of trap states at the channel/dielectric interface. The combination of high performance and high stability OTFT devices enabled the successful realization of stable operating flexible color-displays by inkjet-printing.

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Characterization of Western Asia Glassware excavated from Hwangnamdaechong Great Tomb (황남대총(남분)의 서역계 유리제품 특성화 연구)

  • Kang, Hyung-tae;Chung, Young-dong;Huh, Woo-young;Shin, Yong-bi
    • 한국문화재보존과학회:학술대회논문집
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    • 2004.10a
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    • pp.131-134
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    • 2004
  • A lot of foreign objects(ceramics, pottery, bronze, glassware and coins, etc.) have been found in the archaeological sites in Korea. These foreign objects are the evidences of the cultural exchanges of that time, whose scale and routes are an important part of the studies in ancient history. So it is crucial to accumulate basic reference information such as the raw materials and the production method of these objects through scientific researches, along with archeological researches. These scientific research materials provide a basis for finding the importing route and the origin of these objects. Besides, we can find out extraordinary and distinctive production technique by comparison with tile domestic objects. This article reports the result of an analysis, performing on 36 samples of the glassware fragments excavated from the South Tomb of the Hwangnamdaechong, to verify their components and note peculiar features. We have analyzed the major and minor components of 10 elements, and then by using these data examined the differences in the composition of components, varying with the origin and color of glassware. We used the PCA(principal component analysis) as the statistical method to classify the sample in order to find out how the samples formed groups.

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Transmission Electron Microscopy on Memristive Devices: An Overview

  • Strobel, Julian;Neelisetty, Krishna Kanth;Chakravadhanula, Venkata Sai Kiran;Kienle, Lorenz
    • Applied Microscopy
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    • v.46 no.4
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    • pp.206-216
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    • 2016
  • This communication is to elucidate the state-of-the-art of techniques necessary to gather information on a new class of nanoelectronic devices known as memristors and related resistive switching devices, respectively. Unlike classical microelectronic devices such as transistors, the chemical and structural variations occurring upon switching of memristive devices require cutting-edge electron microscopy techniques. Depending on the switching mechanism, some memristors call for the acquisition of atomically resolved structural data, while others rely on atomistic chemical phenomena requiring the application of advanced X-ray and electron spectroscopy to correlate the real structure with properties. Additionally, understanding resistive switching phenomena also necessitates the application not only of pre- and post-operation analysis, but also during the process of switching. This highly challenging in situ characterization also requires the aforementioned techniques while simultaneously applying an electrical bias. Through this review we aim to give an overview of the possibilities and challenges as well as an outlook onto future developments in the field of nanoscopic characterization of memristive devices.

Experimental and theoretical study of BF3 detector response for thermal neutrons in reflecting materials

  • Nasir, Rubina;Aziz, Faiza;Mirza, Sikander M.;Mirza, Nasir M.
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.439-445
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    • 2018
  • Experimental measurements of the response of $BF_3$ detector to a 3 Ci Am-Be neutron source for three different reflecting materials, i.e., aluminum, wood, and Perspex of varying thicknesses have been carried out. The varying contribution of wall effect to the response due to change in active volume of the detector has also been determined experimentally. Then, a Monte Carlo code has been developed for the calculation of the neutron response function of the $BF_3$ detector using source biasing and importance sampling. This code simulates the $BF_3$ detector response exposed to the neutron field in a three-dimensional source, detector, and reflecting medium configurations. The results of simulation have been compared with the corresponding experimental measurements and are found to be in good agreement. The experimental neutron albedo measurements for various values of Perspex thickness show saturating behavior, and results agree very well with the data obtained by Monte Carlo simulation.