• Environmental Engineering Research
• /
• v.24 no.3
• /
• pp.443-448
• /
• 2019

The present study was conducted to compare the voltage generation in two-chamber microbial fuel cells (MFCs) with a biocathode where nitrate and oxygen are used as a terminal electron acceptors (TEA) and to investigate the nitrogen removal and the electrochemical characteristics depending on the separators of the MFCs for denitrification. The maximum power density in a biocathode MFC using an anion exchange membrane (AEM) was approximately 40% lower with the use of nitrate as a TEA than when using oxygen. The MFC for denitrification using an AEM allows acetate ($CH_3COO^-$) as a substrate and nitrate ($NO_3{^-}$) as a TEA to be transported to the opposite sides of the chamber through the AEM. Therefore, heterotrophic denitrification and electrochemical denitrification occurred simultaneously at the anode and the cathode, resulting in a higher COD and nitrate removal rate and a lower maximum power density. The MFC for the denitrification using a cation exchange membrane (CEM) does not allow the transport of acetate and nitrate. Therefore, as oxidation of organics and electrochemical denitrification occurred at the anode and at the cathode, respectively, the MFC using a CEM showed a higher coulomb efficiency, a lower COD and nitrate removal rate in comparison with the MFC using an AEM.

• Membrane Journal
• /
• v.31 no.4
• /
• pp.275-281
• /
• 2021

To evaluate the possibility as a separator in alkaline water electrolysis, the thermal stability, ion conductivity and durability of 5 commercially available anion exchange membranes were tested. The thermal stability of FAAM-PK-75 and FAAM-40 membrane analyzed by thermo-gravimetric analysis (TGA) showed good performance compared to the other three types of AEM, AHO, and AHA membrane. The ion conductivity of AEM membrane measured in 7 M KOH solution at 25℃ and 80℃ had a higher value of about 4~17 times compared to the other membranes. The durability of FAAM-PK-75 tested in 7 M KOH solution at 25℃ was high compared to the other membranes.

• Transactions of the Korean hydrogen and new energy society
• /
• v.35 no.2
• /
• pp.185-194
• /
• 2024

Fe-Ni nanocatalysts loaded on carbon black were prepared via spontaneous reduction reaction of iron (II) acetylacetonate and nickel (II) acetylacetonate in dry process. Their morphology and elemental analysis were characterized by scanning electron microscopy, transmission electron microscopy (TEM), and energy dispersive X-ray analyzer. The loading weight of the nanocatalysts was measured by thermogravimetric analyze and the surface area was measured by BET analysis. TEM observation showed that Fe and Ni nanoparticles was well dispersed on the carbon black and their average particle size was 4.82 nm. The loading weight of Fe-Ni nanocatalysts on the carbon black was 6.83-7.32 wt%, and the value increased with increasing iron (II) acetylacetonate content. As the Fe-Ni loading weight increased, the specific surface area decreased significantly by more than 50%, because Fe-Ni nanoparticles block the micropores of carbon black. I-V characteristics showed that water electrolysis performance increased with increasing Ni nanocatalyst content.

• Journal of the Korean Electrochemical Society
• /
• v.25 no.2
• /
• pp.69-80
• /
• 2022

The anion exchange membrane (AEM) water electrolysis for high purity hydrogen production is attracting attention as a next-generation green hydrogen production technology by using inexpensive non-noble metal-based catalysts instead of conventional precious metal catalysts used in proton exchange membrane (PEM) water electrolysis systems. However, since AEM water electrolysis technology is in the early stages of development, it is necessary to develop research on AEM, ionomers, electrode supports and catalysts, which are key elements of AEM water electrolysis. Among them, current research in the field of catalysts is being studied to apply a previously developed half-cell catalyst for alkali to the AEM system, and the applied catalyst has disadvantages of low activity and durability. Therefore, this review presented a catalyst synthesis technique that promoted oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) using a non-noble metal-based catalyst in an alkaline medium.

• Proceedings of the Korean Information Science Society Conference
• /
• 2000.04b
• /
• pp.181-183
• /
• 2000

현재의 컴퓨팅 환경은 멀티미디어와 인터넷, 즉 웹 환경으로 요약된다. 이러한 환경에서 운영되는 복잡한 정보 시스템-인터넷 TV 방송, 문서 관리시스템, 가상 대학, 그룹 웨어, 지식 경영 시스템 등은 대용량의 데이터베이스 데이터와 멀티미디어 데이터를 기반으로 해서 동작한다. 이러한 시스템들에서의 데이터은 데이터 베이스 내에 존재하는 메타 데이터와 운영체제의 파일 시스템 내에 존재하는 파일 데이터로 나뉜다. 이러한 데이터의 분리로 인해서 나타나는 가장 큰 문제점은 이 둘 데이터 사이의 불일치성(inconsistency)이다. 이는 멀티미디어 데이터와 데이터베이스 데이터를 접근해서 사용하는 기능(operation)의 차이로 인해서 발생하게 된다. 본 논문에서는 복잡한 정보시스템에서 사용되어 지는 데이터들 사이에 발생되는 불일치성을 해결하며, 쉬운 프로그램밍을 위한 응용 프로그래밍 인터페이스(ATI)를 제공해주는 AEM(Activity Execution Manager) 프레임워크를 설계 및 구현한다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.10
• /
• pp.7109-7117
• /
• 2015

Investors analyze corporate value using the methodology trying to simultaneously satisfy the profitability and stability. In this study, comparing/combining the methodology of corporate value analysis to present a method of analyzing the optimal corporate value. The results of this study can be classified into two. First, it is a model derivation for corporate value analysis. EVA, AEM, and DDM models, to analyze the results, it was look in terms of profitability and stability. EVA and AEM model was stable than the market, profitability appear high, it was suitable to assess the value of the company. However, DDM, which is more stable than the market, profitability is low, it was not suitable. Secondly, by metering the existing methodology presented a new analysis method. A result of a combination of methodology was analyzed by deformation model, "AEM + DEA" and "DDM + DEA", "AEM + EVA", it was found that it is better than the market and the traditional model. AEM and DDM modified model was also found to be better than the market and the existing methodologies. This was reflected in a situation where a change in market environment based on, for being able to present an appropriate analytical method, it can find the suggestions of the study.

• Physical Therapy Korea
• /
• v.24 no.4
• /
• pp.60-67
• /
• 2017

Background: Scapular downward rotation syndrome (SDRS) is a common scapular alignment impairment that causes insufficient upward rotation and muscle imbalance, shortened levator scapulae (LS) and rhomboid, and lengthened serratus anterior (SA) and trapezius. A modified shrug exercise (MSE), performing a shrug exercise with the shoulders at $150^{\circ}$ abduction, is known as an effective exercise to increase scapular stabilizer muscle activation. Previous studies revealed that scapular exercise are more effective when combined with trunk stabilization exercises in decreasing scapular winging and increasing scapular stabilizer muscle activation. Objects: The purpose of our study was to clarify the effect of MSE with or without trunk stabilization exercises in subjects with SDRS. Methods: Eighteen volunteer subjects (male=10, female=8) with SDRS were recruited for this experiment. All subjects performed MSE under 3 different conditions: (1) MSE, (2) MSE with an abdominal draw-in maneuver (ADIM), and (3) MSE with an abdominal expansion maneuver (AEM). The muscle thickness of the lower trapezius (LT) and the SA were measured using an ultrasonography in each condition. Electromyography (EMG) data were collected from the LT, LS, SA, and upper trapezius (UT) muscle activities. Data were statistically analysed using one-way repeated analysis of variance at a significance level of .05. Results: The muscle thickness of the LT and the SA were the significant different in the MSE, MSE with ADIM (MSE+ADIM) and MSE with AEM (MSE+AEM) conditions (p<.05) In both LT and SA, the order of thick muscle thickness was MSE+AEM, MSE+ADIM, and MSE alone. No significant differences were found in the EMG activities of the SA, UT, LS, and LT in all condition. Conclusion: In conclusion, MSE is more beneficial to people with SDRS when combined with trunk stabilization exercises by increased thickness of scapular stabilizer muscles.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.151-151
• /
• 2016

수소는 친환경 에너지원으로 주목 받고 있으며 미래 화석연료의 고갈에 대비할 수 있는 물질이다. 수전해는 natural gas steam reforming 또는 coal gasification 같은 방법에 비해 공해 물질의 방출이 없어 미래지향적인 기술로 간주된다. 저온형 수전해는 크게 알칼리 수전해와 고분자 전해질막 수전해로 구분되며 각각의 기술은 장단점을 가지고 있다. 알칼리 수전해는 비백금계 물질을 촉매로 사용할 수 있는 이점이 있으나 알칼리 용액으로 인한 부식, 높은 과전압에 의한 효율저하 그리고 간헐적인 사용에 적합하지 않다. 고분자 전해질막 수전해는 간헐적인 사용이 용이하고 높은 에너지 밀도를 가지지만 산성분위기로 인한 백금계 촉매를 사용해야 하므로 수소 생산 비용이 증가하게 된다. 본 연구에서는 알칼리 수전해와 고분자 전해질막 수전해 방식의 이점을 최대한 이용하고 단점을 극복하기 위한 방법으로 음이온 교환막(anion exchange membrane, AEM)을 적용한 셀 구조를 소개한다. 본문에서는 AEM 수전해 단위 셀의 구성요소들인 AEM 종류, 가스 확산층의 밀도와 운전조건인 알칼리 수용액 농도, 온도의 조건을 다르게 하여 최상의 구성 요소 조건 및 운전조건을 알아보았다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.579-579
• /
• 2012

Graphene has recently been a subject of much interest as a potential platform for future nanodevices such as flexible thin-film transistors, touch panels, and solar cells. And chemical vapor deposition (CVD) and related surface segregation techniques are a potentially scalable approach to synthesizing graphite films on a variety of metal substrates. The structural properties of such films have been studied by a number of methods, including Raman scattering, x-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and transmission electron microscopy (TEM). An understanding of the structural quality and thickness of the graphite films is of paramount importance both in improving growth procedures and understanding the resulting films' electronic properties. In this study, we synthesized the few-layered grapheneunder optimized condition to figure out the growth mechanism seen in CVD-grown graphenee by using various electron microscope. Especially, we observed directly film thickness, quality, nucleation site, and uniformity of grpahene by using AEM. The details will be discussed in my presentation.

• Transactions of the Korean hydrogen and new energy society
• /
• v.32 no.5
• /
• pp.285-292
• /
• 2021

To study the effect of the mixture ratio of Ni-Pt nanocatalysts on water electrolysis characteristics in anion exchange membrane system, Ni-Pt nanocatalysts were loaded on carbon black by using a spontaneous reduction reaction of acetylacetonate compounds. The loading weight of Ni-Pt nanocatalysts on the carbon black was measured by thermogravimetric analyzer and the elemental ratio of Ni and Pt was estimated by energy dispersive x-ray analyzer. It was found that the loading weight of Ni-Pt nanoparticles was 5.36-5.95 wt%, and the loading weight increased with increasing Pt wt%. As the Ni-Pt loading weight increased, the specific surface area decreased, because Ni-Pt nanoparticles block the pores of carbon black. It was confirmed by BET analysis and dynamic vapor sorption analysis. I-V characteristics were estimated.