• Title/Summary/Keyword: ACETYLENE

Search Result 326, Processing Time 0.029 seconds

A Study on the TiC Coating Using Hollow Cathode Discharge Ion Plating (HCD 이온 플레이팅 방법을 이용한 TiC 코팅에 관한 연구)

  • Kim, In-Cheol;Seo, Yong-Woon;Whang, Ki-Whoong
    • Proceedings of the KIEE Conference
    • /
    • 1991.11a
    • /
    • pp.261-264
    • /
    • 1991
  • Titanium carbide(TiC) films were deposited on stainless-steel sheets using HCD(Hollow Cathode Discharge) reactive ion plating. Acetylene gas was used as the reactant gas. The characteristics of TiC films were examined by X-Ray diffraction, $\alpha$-step, ESCA(Electron Spectroscopy for Chemical Analysis), and, AES(Auger Electron Spectroscopy). The results were discussed with regard to various deposition conditions(bias voltage, acetylene flow rate, temperature).

  • PDF

Numerical Analysis for the Detailed Structure and the Soot Formation Mechanism in Counterflow Ethylene-Air Nonpremixed Flame (대향류 에틸렌/공기 비예혼합 화염의 구조 및 Soot 생성 메커니즘 해석)

  • 임효준;김후중;김용모
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.7 no.5
    • /
    • pp.40-54
    • /
    • 1999
  • The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

  • PDF

Contribution of van der Waals Interactions to the Adsorption Energy of $C_2H_2$, $C_2H_4$, and $C_6H_6$ on Si(100)

  • Kim, Seon-U;Lee, Jun-Ho;Jo, Jun-Hyeong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.269-269
    • /
    • 2013
  • Usingvan der Waals (vdW) energy-corrected density-functional theory without or with self-consistent screening (SCS) effects, we calculate the adsorption energy of acetylene, ethylene and benzene on Si(100). We find that vdW interactions without SCS effects increase the adsorption energy by 0.23, 0.30, and 0.64 eV for adsorbed $C_2H_2$, $C_2H_4$, and $C_6H_6$ on Si(100), respectively. However, if SCS effects are included, this increase of the adsorption energy is reduced as 0.19, 0.24, and 0.54 eV for the three adsorption systems, respectively. The resulting adsorption energy for each system is between the values computed using the local-density approximation and the generalized-gradient approximation.

  • PDF

Effect of Plasma Polymerization Coating of CNTs on the Tensile Strength of Pei/Cnt Composites

  • Song, K.C.;Yoon, T.H.
    • Journal of Adhesion and Interface
    • /
    • v.6 no.4
    • /
    • pp.7-11
    • /
    • 2005
  • Multi-walled carbon nanotubes (CNTs), which were purified by etching in 25% $H_2SO_4/HNO_3$ solution at $60^{\circ}C$ for 2 h, were modified via plasma polymerization coating of acrylic acid, allylamine or acetylene, and then utilized to prepare PEI/CNT composites. First, plasma polymerization conditions were optimized by measuring the solvent resistance of coatings in THF, chloroform and NMP, and the tensile strength of PEI/CNT (0.5%) composites as a function of plasma power (20~50 W) and monomer pressure (20~50 mTorr). The tensile strength of PEI/CNT composites was further evaluated as a function of CNT loading (0.2, 0.5 and 1%). Finally, FT-IR was utilized to provide a better understanding of the improved tensile properties of PEI/CNT composites via plasma polymerization coating of CNTs. Plasma polymerization of acrylic acid greatly enhanced the tensile strength of PEI/CNT composites, as did allylamine but to a lesser degree, while acetylene plasma polymerization coating decreased tensile strength.

  • PDF

Effect of Fe Catalyst on Growth of Carbon Nanotubes by thermal CVD

  • Yoon, Seung-Il;Heo, Sung-Taek;Kim, Sam-Soo;Lee, Yang-Kyu;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2007.08a
    • /
    • pp.760-763
    • /
    • 2007
  • The properties of carbon nanotube obtained by thermal chemical vapor deposition (CVD) process were investigated as a function of ammonia $(NH_3)$ gas in hydrocarbon gas, Fe catalyst thickness, and growth temperature. Fe catalyst was prepared by DC magnetron sputter and pre-treated with ammonia gas. CNTs were then grown with ammonia-acetylene gas mixture by thermal CVD. The diameter of these CNTs shows a strong correlation with the gas rate, the catalyst film thickness and temperature. From our results, it was found that the factors of grown CNTs positively acted to improve CNT quality.

  • PDF

Surface Treatment of Metal to Improve Bonding Strength of Metal/Composites (금속재/복합재의 본딩력 향상을 위한 금속재의 표면처리)

  • 양준호;지창헌;이경엽
    • Proceedings of the Korean Society For Composite Materials Conference
    • /
    • 2000.11a
    • /
    • pp.71-74
    • /
    • 2000
  • In this study, the optimal condition of surface treatment for aluminum panel was determined by measuring the contact angle and T-peel strength. The contact angle was measured for various mixture ratios of acetylene gas and nitrogen gas. The mixture (acetylene gas to nitrogen gas) ratios used were 1:9, 3:7, 5:5, 7:3, and 9:1. The contact angle was also measured as a function of time of surface treatment. The results showed that the contact angle was a minimum for mixture ratio of 5:5. T-peel strength was a maximum for the treatment time of 30 second.

  • PDF

A Study on the Detonation Characteristics of $C_2H_2$in Shock Tube (충격관을 이용한 $C_2H_2$의 폭굉특성연구)

  • 오규형
    • Journal of the Korean Society of Safety
    • /
    • v.11 no.4
    • /
    • pp.64-71
    • /
    • 1996
  • Detonation phenomena of $C_2H_2$were invesgated using the various shock tube. To study the detonation characteristics according to the composition of $C_2H_2-0_2$$_2$ and $C_2H_2$-air mixtures, the composition were varied from 5 to 90% and 5 to 50% of acetylene each other. A spiral ring was installed in the shock tube to study the effect of obstacles in DDT phenomena. Detonation velocities were measured using the photodiode, and the DDT phenomena was visualized using the high speed schlieren photograph. From the experimental result, it was found that the detonation velocity was most high near the 1. 8times the stoichiometric ratio of acetylene. And from the visualization of DDT phenomena, it was found that the detonation wave was strengthened throuth the pile up of small compression wave of burned gas. And the obstacles in shock tube accelerate the detonation reaction by turblent effect of flammable gas mixture.

  • PDF