• Title/Summary/Keyword: AC7A

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Synthesis, Structure and Magnetic Properties of Mn12 Single Molecule Magnet Containing 4-(Methylthio)benzoate as Peripheral Ligands

  • Lim, Jin-Mook;Do, Young-Kyu;Kim, Jin-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.26 no.7
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    • pp.1065-1070
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    • 2005
  • $[Mn_{12}O_{12}(O_2CPh-4-SMe)_{16}(H_2O)_4]{\cdot}7CH_2Cl_2$ (1), a new single-molecule magnet complex has been successfully synthesized by substitution of acetate ligand of Mn12ac with 4-(methylthio)benzoic acid. Complex 1 crystallizes into triclinic P$\overline{1}$ with a = 18.321(3) $\AA$, b = 19.011(3) $\AA$, c = 27.230(4) $\AA$, $\alpha$ = 86.973(3)$^{\circ}$, $\beta$ = 76.919(3)$^{\circ}$, $\gamma$ = 87.613(3)$^{\circ}$, and Z = 2. In complex 1, one Mn(III) ion has an abnormal Jahn-Teller elongation axis oriented at an oxide ion. Complex 1 has two out-of-phase ac susceptibility peaks in the 2-4 K and 4-7 K regions. Effective anisotropy energy barrier and pre-exponential factor are $U_{eff}$ = 45.95 K, 1/$\tau$0 = 8.6 ${\times}\;10^9s^{-1}\;for\;{\chi}_M$'' peaks in the lower temperature region and $U_{eff}$ = 59.45 K, 1/$\tau_0$ = 2.2 ${\times}\;10^8\;s^{-1}$ for $\chi_M$'' peaks in the higher temperature region. The parameters of S = 10, g = 1.87, D = -0.40 $cm^{-1}$, and E = 0.00034 $cm^{-1}$ were obtained from the M/N${\mu}_B$ vs. H/T plot of complex 1.

Fast Extraction of Edge Histogram in DCT Domain based on MPEG-7 (MPEG-7 기반 DCT영역에서의 에지히스토그램 고속 추출 기법)

  • Eom Min-Young;Choe Yoon-Sik;Won Chee-Sun;Nam Jae-Yeal
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.43 no.4 s.310
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    • pp.19-26
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    • 2006
  • In these days, multimedia data is transmitted and processed in compressed format. Due to the decoding procedure and filtering for edge detection, the feature extraction process of MPEG-7 Edge Histogram Descriptor (EHD) is time consuming as well as computationally expensive. To improve efficiency of compressed image retrieval, we propose a new edge histogram generation algorithm in DCT domain in this paper. Using the edge information provided by the only two AC coefficients of DCT coefficients, we can get edge directions and strengths directly in DCT domain. The experimental results demonstrate that our system has good performance in terms of retrieval efficiency and effectiveness.

Effect of Scrap Addition Ratio on Tensile and Solidification Cracking Properties of AC4A Aluminum Casting Alloy (AC4A 알루미늄 합금의 인장 및 응고균열 특성에 미치는 스크랩 첨가 비율의 영향)

  • Oh, Seung-Hwan;Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.40 no.3
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    • pp.85-96
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    • 2020
  • The effect of an aluminum scrap addition ratio on the tensile and solidification cracking properties of the AC4A aluminum alloy in the as-cast state and heat-treated state were investigated in this study. Generally, the expected problem of using scrap in aluminum casting is an increase of hydrogen and Fe element inside the aluminum melt. Another issue is an oxide film which has a weak interface with the molten aluminum and acts as potent nucleation sites for internal porosity and crack initiation. Solidification cracking is one of the critical defects that must be resolved to produce high quality castings. A conventional evaluation method for solidification cracking is a relative and qualitative analysis method which does not provide quantitative data on the thermal stress in the solidification process. Therefore, a newly designed solidification cracking test apparatus was used in this study, and the device can provide quantitative data. As a result, after conducting experiments with different scrap addition ratios (0%, 20%, 35%, 50%), the tensile strengths and elongations in the as-cast state were 214, 187.7, 182.1 and 170.4MPa and 4.6%, 3.4%, 3.1% and 2.3%, respectively. In the case of the T6 heat-treated state, the tensile strengths and elongations were 314.9, 294.6, 293.1 and 271.1MPa and 5.4%, 4.6%, 3.8% and 3.1%, respectively. The strength of the solidification cracking was 3.1, 2.4, 2.2and 1.6MPa as the scrap addition ratio increases.

Association of MDR1 Gene Polymorphisms with Susceptibility to Hepatocellular Carcinoma in the Chinese Population

  • Ren, Yong-Qiang;Han, Ju-Qiang;Cao, Jian-Biao;Li, Shao-Xiang;Fan, Gong-Ren
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.11
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    • pp.5451-5454
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    • 2012
  • Objective: The objective of this study was to evaluate the association of MDR1 gene polymorphisms with susceptibility to hepatocellular carcinoma (HCC). Methods: A total of 689 HCC patients and 680 cancer-free subjects were enrolled. Human MDR1 gene polymorphisms were investigated by created restriction site-polymerase chain reaction (CRS-PCR) and DNA sequencing methods. Multiple logistic regression models were applied to estimate the association between MDR1 gene polymorphisms and susceptibility to HCC. Results: We detected a novel c.4125A>C polymorphism and our findings suggested that this variant was significantly associated with susceptibility to HCC. A significantly increased susceptibility to HCC was noted in the homozygote comparison (CC versus AA: OR=1.621, 95% CI 1.143-2.300, ${\chi}^2$=7.4095, P=0.0065), recessive model (CC versus AC+AA: OR=1.625, 95% CI 1.167-2.264, ${\chi}^2$=8.3544, P=0.0039) and allele contrast (C versus A: OR=1.185, 95% CI 1.011-1.389, ${\chi}^2$=4.4046, P=0.0358). However, no significant increase was observed in the heterozygote comparison (AC versus AA: OR=0.995, 95% CI 0.794-1.248, ${\chi}^2$=0.0017, P=0.9672) and dominant model (CC+AC versus AA: OR=1.106, 95% CI 0.894-1.369, ${\chi}^2$=0.8560, P=0.3549). Conclusions: These findings suggest that the c.4125A>C polymorphism of the MDR1 gene might contribute to susceptibility to HCC in the Chinese population. Further work will be necessary to clarify the relationship between the c.4125A>C polymorphism and susceptibility to HCC on larger populations of diverse ethnicity.

Effects of supplementation of high pressured red ginseng and ginseng berry on the duration of running time to exhaustion and the body lipid profiles in SD rats (5주간의 초고압 홍삼섭취가 흰쥐의 운동지속시간 및 체내 지질성분에 미치는 영향)

  • Kim, Shinae;Shin, Myungkil;Kim, Jungki;Lee, Myungsook;Park, Hyon
    • Korean Journal of Exercise Nutrition
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    • v.14 no.2
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    • pp.63-68
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    • 2010
  • This study evaluated the effects of high pressured red ginseng(HRG) and ginseng berry(GB) supplementation on lipid profiles and run to exercise time in SD rats. Five weeks-old male rats were randomly assigned into six groups, ie. control group(AC: n = 8), exercise group(AE: n = 7), general extracted red ginseng group(C: n = 8), HRG group(high density D: n = 8, low density E: n = 7), and HRG + GB group(F: n = 7). The AC and AE groups had a supplementation of AIN-93G, and AE group performed 40 min treadmill exercise five times per week for five weeks. E, C, D, and F groups had a supplementation composed of general extracted red ginseng(GRG), HRG(250 mpk and 500 mpk), and HRG(250 mpk) + GB(167 mpk) in the AIN-93G. Main results of the study were as follow 1) the duration of running time to exhaustion was higher in exercise group compared to other groups. HRG had no effect on run to exhaustion time, but, GRG and HRG + GB showed longer run time than control groups. 2) Blood TC, TG, HDL-C and liver TG showed no difference between groups, but, liver TC showed lower level in the HRG groups than other groups. It was concluded that the 5 weeks of supplementation of HRG extract would have positive effects on liver cholesterol, and GRG and HRG + GB have a positive effect on exercise performance tested run to exhaustion time, but, we can not find a positive effect of supplementation of HRG on exercise performance.

Effect of Types of Egg Shell Calcium Salts and Egg Shell Membrane on Calcium Metabolism in Rats (난각 칼슘염의 종류와 난막의 존재유무가 흰쥐의 칼슘대사에 미치는 영향)

  • Noh, Kyung-Hee;Lee, Sang-Hyun;Ma, Jie;Zhou, Yusi;Kim, Jae-Cherl;Kim, Myo-Jeong;Song, Young-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.7
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    • pp.853-859
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    • 2006
  • This study was carried out to investigate the effect of egg shell calcium salt types and egg shell membrane on calcium metabolism in rats. Sprague-Dawley male rats, 4 weeks of age, were fed on free-calcium diets for 2 weeks after adjustment period. Rats weighing approximately $247{\pm}2.3g$ were divided into 6 groups and were fed on the experimental diets containing 0.2% calcium for 4 weeks. Experimental groups were as follows; {ES(M+)} (egg shell powder diet with egg shell membrane), {ES(M-)} (egg shell powder diet without egg shell membrane), {AC(M+)} (egg shell calcium acetate diet with egg shell membrance), {AC(M-)} (egg shell calcium acetate diet without eg shell membrane), {GC(M+)} (egg shell calcium glucuronate diet with egg shell membrane) and {GC(M-)} (egg shell calcium glucuronate diet without egg shell membrane). Bone length of femur was significantly different by the types (p<0.05) of egg shell calcium salts. Bone mineral density of femur showed the highest level in AC(M-) group. Calcium content of femur and calcium absorption rate were higher in egg shell calcium salt groups than in eg shell powder groups. Calcium absorption rate and retention were significantly different (p<0.05) among the types of eg shell calcium salts and were higher in the AC(M-) group than in the other groups. Alkaline phosphatase activity, parathyroid hormone and osteocalcin levels of serum showed no significant difference among the experimental groups. From the above results, it is concluded that bioavailability of calcium is higher in groups of egg shell calcium salts compared to those in egg shell powder, even though egg shell membrane has no effect on calcium metabolism. Thus, these findings suggest the possibility of using egg shell calcium salts as a functional food material related to calcium metabolism.

A Study on the Determination of Density and Moisture Content of Asphalt Concrete Pavement and Subgrade Using Nuclear Density Meter (방사선측정치를 이용한 아스콘 포장 및 노상의 현장밀도와 함수비 측정에 관한 연구)

  • 진성기;도덕현
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.36 no.4
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    • pp.103-116
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    • 1994
  • The objective of this study was to determine the criteria for density and moisture content measurements made with a nuclear density meter on common materials in the construction field. The study also sought to test a full-type nuclear density meter in controlling the density of overlay layers( 2.5~5.0cm). In order to determine the accuracy and reliablility of nuclear guage measurements made on construction materials, laboratory and field tests were conducted. Wooden blocks( 65 x 45 ${\times}$ 50 cm) and a special steel compactor( 4.7kg) were constructed in order to carry out tests which were conducted on three different materials; coarse gramed soil, fine grained soil, and AC material. Throughout all laboratory and field tests, the nuclear density and moisture content were determined using Humboldt 5OOLP nuclear gauge. The tests on subgrade material entailed obtaining density measurements by means of both the sand replacement method and the nuclear density meter. The results of the sand replacement method were then compared to the readings recorded bu the meter. As in the subgrade material tests, density measurements made during AC pavement tests were also determined using the unclear meter in addition to a second means; through the core method. The meter readings and core densties were compared as was done in the tests on subgrade materials. The correlation between the results of the sand replacement test( also, the core method) and meter readings on subgrade material was then determined. Sirnilarly, the observed results were then analyzed through linear regression. The tests to determine thin-lift density by means of a full-type nuclear density meter also conducted on the overlay layers( about 4. 8cm thickness) above AC pavements at road construction sities in Korea.

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A Study on current sensor (전류 검출기에 대한 연구)

  • Lee, Hwan
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.3
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    • pp.335-340
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    • 1996
  • The item and structure of current detector depends on the current in conductors. The Hall current detector of these detectors is to use the variation of Hall voltage to conductor's current and it is very difficult for the conventional type to detect small current. In this paper we study experimented-method that detect AC current by using the magnetic modulation method the current, 0[mA]~100[mA]. The experiments results in 5 percent against the conventional, 20 percent in linear error, 0.12[.DELTA.mV/.DELTA.mA] to conventional type, 50[.DELTA.mV/.DELTA.mA] in sensitivity. (author). 7 refs., 15 figs.

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Corona Discharge and Ozone Generation Characteristics of a Wire-to-Wire Plasma Reactor with a Ferroelectric Pellet Layer (강유전체층을 갖는 선대선 방편 플라즈마장치의 코로나 방전 및 오존발생 특성)

  • 문재덕;신정민;한상옥
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.7
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    • pp.377-381
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    • 2004
  • A discharge plasma reactor using a ferroelectric pellet packed bed is now used as a removal means of pollutant gases, such as NOx, SOx and VOCs. When an ac voltage is applied to this plasma reactor, then the pellets are polarized, and great electric fields are formed at each top and bottom contact points of the ferroelectric pellets. Thus the points of each pellet become covered with intense corona discharges, where an electrophysicochemical reaction is taking place strongly However these strong discharges also elevate the temperature of the pellets greatly and concurrently decrease the output ozone generation, as a result, the overall removal efficiency of gas becomes decreased greatly A new configuration of discharge plasma reactor using a ferroelectric pellet layer and a wire-to-wire electrode has been proposed and investigated experimentally. It is found that an intensive microdischarge is taking place on the surface of ac corona-charged ferroelectric pellet layer of the proposed reactor, which concurrently enhances the efficiency of plasma generation greatly And, this type of configuration of plasma reactor utilizing a wire-to-wire electrode and a ferroelectric pellet layer could be used as one of effective plasma reactors to remove pollutant gas.

Electroantennogram Responses of Spodoptera frugiperda Males (Lepidoptera: Noctuidae) to Sex Pheromone Compounds (열대거세미나방 성페로몬 성분에 대한 수컷의 촉각 반응)

  • Cho, Jum Rae;Kim, Jeong Hwan;Seo, Bo Yoon;Seo, Meeja;Lee, Gwan Seok
    • Korean journal of applied entomology
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    • v.60 no.4
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    • pp.363-367
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    • 2021
  • This study was conducted to investigate the EAG (electroantennogram) response of Spodoptera frugiperda male to sex pheromone compounds and whether or not S. frugiperda male adults would undergo double mating. The EAG response of S. frugiperda male adult to Z9-14:Ac increased in a dose-dependent as the dose increased. Among the 7 sex pheromone components investigated, male EAG recording was the highest to Z9-14:Ac. The EAG response of S. frugiperda male adult to the mixed sex pheromone component was greater than that to the single component. Male adults of S. frugiperda were capable of double mating under laboratory condition, and the secondary mating rate increased to 72.2% compared to the 58.3% of primary mating rate. The EAG response of mated S. frugiperda male adult was not different from that of unmated S. frugiperda male. In the net house test with sex pheromone lure, mated male adults were not captured during the test period. Also, strangely, unmated male adults were not captured even in a trap equipped with virgin female adults, although the antennae of mated male adult were responded to the sex pheromone component in the laboratory. Probably, it is thought that the mated male adults may not have been caught in the trap be due to flight ability which has been decreased after mating. The field attractiveness of S. frugiperda male adults to sex pheromones remains to be further elucidated.