• Applied Chemistry for Engineering
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• v.31 no.2
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• pp.226-229
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• 2020

N-phenylmaleimide (PMI), a compound for strengthening the heat resistance of ABS resin, is a yellow crystal. Therefore, copolymers modified with PMI exhibit color, which limits their use. In order to overcome such disadvantage, the demand for N-cyclohexylmaleimide (CHMI), which has similar properties to PMI and also is a white crystal, is increasing. However, CHMI is difficult to industrialize due to the formation of various by-products during synthesis, which requires an additional purification process resulting in a low yield. In this study, composite catalysts were developed to improve these problems and industrially produce CHMI. Finally, CHMI was synthesized with a 85% yield and at least 99.5% purity.

• The Journal of the Korea institute of electronic communication sciences
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• v.9 no.12
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• pp.1415-1420
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• 2014

3D printer is based on an additive manufacturing technology, which helps in creating the three-dimensional object using a 3D drawing. It is used in various fields, because it prints out a variety of three-dimensional products in a short period of time. In this paper, we consider a technique using the FDM(Fused Deposition Modeling) method by dissolving the ABS(Acrylonitrile Butadiene Styrene) resin among a diversity of printing technique and materials. This kind of the 3D printer prints out a product in high temperature and cools down it. In this process, a flection phenomenon is occurred according to the size of the printing product and the surrounding environment. Conventional methods for mitigating this phenomenon maintain the temperature at the optimum level, but they require using additional devices. In order to minimize the flection phenomenon in 3D printing products without additional devices, in this paper, we propose a noble technique, which creates holes on suitable positions when they are designed by 3D drawing tools. Also, we suggest mathematical model for the proposed method, and measure and analyse a printing output using a proposed technique.

• Journal of Environmental Health Sciences
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• v.20 no.3
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• pp.1-12
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• 1994

Wastewaters being treated and final effluents were collected from 3 wastewater treatment plants of petrochemical industries, from August 31 to October 4, 1993 in an interval of 10 days, and further analysed by GC/FID to investigate discharge situation and removal efficiency on polycyclic aromatic hydrocarbons. The results were as follows: 1. The PAHs 294.57 $\mu$g/l were discharged in primary treatment effluent of plant A to manufacture vinyl acetate resin and acryl, and removed 54.51% by aeration and totally 84.71%. 2. The PAHs of the highest concentration were discharged in primary treatment effluent of plant B to manufacture PS resin and ABS resin, but removed 91.65% by activated sludge process and 98.19% by activated carbon to discharge PAHs of the lowest concentration comparing to another treatment operations. 3. The PAHs 99.96 $\mu$g/l of the lowest concentration were discharged in wastewater of plant C to manufacture epoxy resin, and removed 80.48% by activated sludge process. 4. B treatment system including activated carbon showed up the best removal efficiency of PAHs. Activated carbon therefore, seems to be effective as tertiary treatment. 5. Correlation coefficient of components to total PAHs was generally low, and correlation coefficients of phenanthrene, pyrene and acenaphthylene to total PAHs were each 0.98, 0.97 and 0.80, respectively. Correlation coefficient of the sum of phenanthrene, pyrene and acenaphthylene to total PAHs was 0.99, so that the sum of phenanthrene, pyrene and acenaphthylene was available as index to estimated total PAHs. 6. Phenanthrene and Chrysene were very well treated biologically and acenaphthylene and fluoranthene were untreated biologically. 7. Considering EPA standards, it seems that the concentration of phenanthrene, pyrene, fluoranthene, and benzo(k)fluoranthene is high level.

• Journal of Industrial Technology
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• v.21 no.B
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• pp.281-286
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• 2001

In this study, product design and prototype manufacturing of a plastic water-pump pulley has been tried. The designed model is supposed to be made of 33 % glass reinforced resin of which the tensile strength is 180 MPa, and has 24 ribs on each side to increase its structural strength. Structural analysis under a static load of 300 kgf acting on both edges of the belt has been carried out using a commercial finite element code, MARC. The analysis result showed the maximum effective stress near a rib of designed model would be at most 35 MPa (less than 20% of the tensile strength), therefore, the plastic product would be sufficiently safe under that loading condition. On the basis of the structural analysis, a prototype of the designed model has been manufactured by using the fused deposition modelling (FDM) method which is one of the rapid prototyping (RP) methods, using ABS resin and support materials. The CAD data exported to the RP system in STL format was prepared by a commercial solid modeling software, SolidWorks. It has been proved that the plastic pulley can successfully replace the existing flow-formed steel product.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2008.10a
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• pp.110-113
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• 2008

This study was performed to predict the shape of polymer extrusion product and to find the cause of defective products Experiments was performed to extrude the complex profile shape using PC/ABS composite resin with new profile die and cooling die. A finite element analysis for the Polymer Extrusion process considering the heat transfer and thermal deformation was also performed, and the result was compared with the experimental data. It is found that the predicted profile shape in F. E. M was similar to the experimental result and the thickness of extruded product was thin when the velocity of profile die outlet was slow than the velocity of production (2m/min).

• Journal of the Korean Society for Precision Engineering
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• v.12 no.3
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• pp.110-118
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• 1995

The filling phase analysis of the injection molding process for thermoplastics was applied to predict pressure, themperature and shear stress in the test mold, and the results were compared with the experiment using 30% glass fiber added ABS resin. The finite difference method was used in the analysis considering the effects of heat transfer between molten polymer and mold wall, and also frictional heating by shear flow. The analysis results were considered as a method to improve the quality and the productivity of injection molding process. Using the analysis results, the molding factors such as mold-ability of polymers, performance of injection molding machine, positioning of gate and dimendsioning of runner in the injection molding process can be estimated at the design stage of mold for good quality and productivity.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1193-1198
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• 2003

Translucent plastics are commonly used in packaging of mechanical and/or electrical components. Although Rapid Prototyping(RP) provides prototypes of various materials, translucent RP parts are not readily available from most RP processes. ABSi is one of the ABS materials available for Stratasys' FDM process, and the material has potential to be translucent. In this paper, two post-processing techniques were applied in order to increase optical transmissivity of the parts made of FDM's ABSi. First, elevated temperature condition was applied resulting in increased transmissivity while dimensional shrinkage was observed. Second, resin infiltration and surface sanding provided upto 16% transmissivity without shrinkage. These post-processes can be selectively applied to increase transmissivity of ABSi parts. Thus, translucent FDM part can be fabricated from regular FDM process followed by the post-processes developed in this study.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.5
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• pp.659-665
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• 2011

Recently, the plastic resin such as PC, ABS are widely used in IT market. Especially, in most cases the keypads mounted on the mobile phone are the dual-injection-plated type. Environmental regulation is based on the quality of injection-molded products and the minimum process steps are required to avoid the plating defects. Various parameters to produce the injection-molded plastic products make it difficult to obtain the desired stability. However, the past experience and the use of CAE analysis make it possible to predict the problems occurred in injection molding process. Especially, the problems of the weld lines such as runner balancing, bending, deformation and forming defects can be solved systematically and minimized by CAE analysis. Through this study, the non-uniform volumetric shrinkage and the difference in temperature distribution induce the deformation and the high value of stress causes the problems such as crack.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.741-744
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• 2000

In general there occur warpage in one way long part. Warpage is caused by differential shrinkage-Orientation Effect, Volumetric Shrinkage Effect, Differential Cooling Effect -over the part. Deco-Top is located at the top of 29"TV set and it's shape is one way long$(626{\times}130mm)$. Material is used transparency ABS resin. So we can't design ribs in this part. And we use film gate to avoid weld line. In these reasons we must develop no ribs and no warpage product. In this study we use MOLDFLOW's software-MF/FLOW, MF/COOL, MF/WARP. Using MF/FLOW, set the flow balance and gate positioning. And we can set cooling channel layout and the optimum processing condition through MF/COOL and MF/WARP. In result we reduced trials and obtained good product.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.9
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• pp.1524-1530
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• 2003

Translucent plastics are commonly used in packaging of mechanical and/or electrical components. Although Rapid Prototyping(RP) provides prototypes of various materials, translucent RP parts are not readily available from most RP processes. ABSi is one of the ABS materials available for Stratasys' FDM process, and the material had potential to be translucent. In this paper, two post-processing techniques were applied in order to increase optical transmissivity of the parts made of FDM's ABSi. First, elevated temperature condition was applied resulting in increased transmissivity while dimensional shrinkage was observed. Second, resin infiltration and surface sanding provided up tp 16 ％ transmissivity without shrinkage. These post-processes can be selectively applied to increase transmissivity of ABSi parts. Thus, translucent FDM part can be fabricated from regular FDM process followed by the post-processes developed in this study.